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Title: Suppression of axionic charge density wave and onset of superconductivity in the chiral Weyl semimetal Ta 2 Se 8 I

Journal Article · · Physical Review Materials

A Weyl semimetal with strong electron-phonon interaction can show axionic coupling in its insulator state at low temperatures, owing to the formation of a charge density wave (CDW). Such a CDW emerges in the linear-chain-compound Weyl semimetal Ta2Se8I below 263 K, resulting in the appearance of the dynamical condensed-matter axion quasiparticle. In this paper, we demonstrate that the interchain coupling in Ta2Se8I can be varied to suppress the CDW formation with pressure, while retaining the Weyl semimetal phase at high temperatures. Above 17 GPa, the Weyl semimetal phase does not survive, and we induce superconductivity, due to the amorphization of the iodine sublattice. Structurally, the quasi-one-dimensional Ta-Se chains remain intact and provide a channel for superconductivity. We highlight that our results show a near-complete suppression of the gap induced by the axionic charge density wave at pressures inaccessible to previous studies. Including this CDW phase, our experiments and theoretical predictions and analysis reveal the complete phase diagram of Ta2Se8I and its relationship to the nearby superconducting state. The results demonstrate Ta2Se8I to be a distinctively versatile platform for exploring correlated topological states.

Research Organization:
Stanford Univ., CA (United States); Univ. of California, Oakland, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC); European Research Council (ERC); National Key Research and Development Program of China; National Natural Science Foundation of China (NSFC); Gordon and Betty Moore Foundation; Max Planck Society
Grant/Contract Number:
SC0019140; AC02-05CH11231; 742068; 2018YFA0704300; U1932217; 11974246; GBMF8048
OSTI ID:
1812425
Alternate ID(s):
OSTI ID: 1852884
Journal Information:
Physical Review Materials, Journal Name: Physical Review Materials Vol. 5 Journal Issue: 8; ISSN 2475-9953
Publisher:
American Physical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

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