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Thermal decarboxylation for the generation of hierarchical porosity in isostructural metal–organic frameworks containing open metal sites

Journal Article · · Materials Advances
DOI:https://doi.org/10.1039/D1MA00163A· OSTI ID:1812240
 [1];  [2];  [1];  [3];  [2];  [2];  [2];  [2];  [2];  [3];  [4];  [5]
  1. Neutron Scattering Division, Oak Ridge National Laboratory, Oak Ridge, USA, Department of Chemistry
  2. Department of Chemistry, Texas A&M University, College Station, USA
  3. Department of Biochemistry and Biophysics, Texas A&M University, College Station, USA
  4. Neutron Scattering Division, Oak Ridge National Laboratory, Oak Ridge, USA
  5. Department of Chemistry, Texas A&M University, College Station, USA, Department of Materials Science
+ Show Author Affiliations

The effect of metal-cluster redox identity on the thermal decarboxylation of a series of isostructural metal–organic frameworks (MOFs) with tetracarboxylate-based ligands and trinuclear μ 3 -oxo clusters was investigated.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-06CH11357; AC05-00OR22725; SC0001015; SC0014664
OSTI ID:
1812240
Alternate ID(s):
OSTI ID: 1811335
OSTI ID: 1812241
OSTI ID: 1818960
Journal Information:
Materials Advances, Journal Name: Materials Advances; ISSN MAADC9; ISSN 2633-5409
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

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