Few‐Unit‐Cell MFI Zeolite Synthesized using a Simple Di‐quaternary Ammonium Structure‐Directing Agent
- Department of Chemical and Biomolecular Engineering &,, Institute for NanoBioTechnology Johns Hopkins University 3400 N. Charles Street Baltimore MD 21218 USA
- Department of Chemical Engineering and Materials Science University of Minnesota 421 Washington Avenue SE Minneapolis MN 55455 USA
- Catalysis Center for Energy Innovation University of Delaware Newark DE 19716 USA, Center for Functional Nanomaterials Brookhaven National Laboratory Upton NY 11973 USA
- Department of Chemistry Faculty of Science King Abdulaziz University Jeddah 21589 Saudi Arabia
- National Synchrotron Light Source II Brookhaven National Laboratory Upton NY 11973 USA
- Catalysis Center for Energy Innovation University of Delaware Newark DE 19716 USA, Center for Functional Nanomaterials Brookhaven National Laboratory Upton NY 11973 USA, Department of Materials Science and Chemical Engineering State University of New York at Stony Brook 100 Nicolls Rd Stony Brook NY 11794 USA
- Chemical Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720 USA, Department of Chemical and Biomolecular Engineering University of California Berkeley CA 94720 USA
- Department of Chemical and Biomolecular Engineering University of Houston Houston TX 77204 USA
- Department of Chemical and Biomolecular Engineering &,, Institute for NanoBioTechnology Johns Hopkins University 3400 N. Charles Street Baltimore MD 21218 USA, Applied Physics Laboratory Johns Hopkins University 11100 Johns Hopkins Road Laurel MD 20723 USA
Synthesis of a pentasil‐type zeolite with ultra‐small few‐unit‐cell crystalline domains, which we call FDP (few‐unit‐cell crystalline domain pentasil), is reported. FDP is made using bis‐1,5(tributyl ammonium) pentamethylene cations as structure directing agent (SDA). This di‐quaternary ammonium SDA combines butyl ammonium, in place of the one commonly used for MFI synthesis, propyl ammonium, and a five‐carbon nitrogen‐connecting chain, in place of the six‐carbon connecting chain SDAs that are known to fit well within the MFI pores. X‐ray diffraction analysis and electron microscopy imaging of FDP indicate ca. 10 nm crystalline domains organized in hierarchical micro‐/meso‐porous aggregates exhibiting mesoscopic order with an aggregate particle size up to ca. 5 μm. Al and Sn can be incorporated into the FDP zeolite framework to produce active and selective methanol‐to‐hydrocarbon and glucose isomerization catalysts, respectively.
- Sponsoring Organization:
- USDOE
- Grant/Contract Number:
- SC0014468
- OSTI ID:
- 1811567
- Alternate ID(s):
- OSTI ID: 1813636
- Journal Information:
- Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 35 Vol. 133; ISSN 0044-8249
- Publisher:
- Wiley Blackwell (John Wiley & Sons)Copyright Statement
- Country of Publication:
- Germany
- Language:
- English