Electrode material–ionic liquid coupling for electrochemical energy storage

Wang, Xuehang; Salari, Maryam; Jiang, De-en; Chapman Varela, Jennifer; Anasori, Babak; Wesolowski, David J.; Dai, Sheng; Grinstaff, Mark W.; Gogotsi, Yury

doi:10.1038/s41578-020-0218-9

Electrode material–ionic liquid coupling for electrochemical energy storage

Journal Article · Thu Jul 23 00:00:00 EDT 2020 · Nature Reviews. Materials

DOI:https://doi.org/10.1038/s41578-020-0218-9· OSTI ID:1809986

^[1]; ^[2]; Jiang, De-en ^[3]; ^[2]; ^[1]; ^[4]; ^[4]; ^[2]; ^[1]

Drexel Univ., Philadelphia, PA (United States)
Boston Univ., MA (United States)
Univ. of California, Riverside, CA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division

The development of new electrolyte and electrode designs and compositions has led to advances in electrochemical energy-storage (EES) devices over the past decade. However, focusing on either the electrode or electrolyte separately is insufficient for developing safer and more efficient EES devices in various working environments, as the energy-storage ability is determined by the ion arrangement and charge and/or electron transfer at the electrode–electrolyte interface. Here, we assess the fundamental physicochemical and electrochemical properties at the electrode–electrolyte interfaces in Li-ion batteries and supercapacitors using safe and electrochemically stable ionic-liquid electrolytes. Key reactions and interactions at the electrode–electrolyte interface, as well as geometric constraints and temperature effects, are highlighted. Building on the fundamental understanding of interfacial processes, we suggest potential strategies for designing stable and efficient ionic-liquid-based EES devices with emerging electrode materials.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport (FIRST) Center

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1809986

Journal Information:: Nature Reviews. Materials, Journal Name: Nature Reviews. Materials Journal Issue: 11 Vol. 5; ISSN 2058-8437

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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