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Defect-free-induced Na+ disordering in electrode materials

Journal Article · · Energy & Environmental Science
DOI:https://doi.org/10.1039/d1ee00087j· OSTI ID:1809968
 [1];  [2];  [2];  [2];  [3];  [4];  [5];  [5];  [6];  [7];  [2];  [2];  [8];  [2];  [2];  [4];  [4];  [2];  [2];  [9] more »;  [10];  [11];  [2] « less
  1. Huazhong Univ. of Science and Technology, Wuhan (China). School of Materials Science and Engineering, State Key Laboratory of Material Processing and Die & Mould Technology; Univ. of Wollongong, NSW (Australia). Australian Institute for Innovative Materials, Institute for Superconducting and Electronic Materials
  2. Huazhong Univ. of Science and Technology, Wuhan (China). School of Materials Science and Engineering, State Key Laboratory of Material Processing and Die & Mould Technology
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Neutron Science Division
  4. Huazhong Univ. of Science and Technology, Wuhan (China). School of Optical and Electronic Information
  5. Hubei Engineering Univ., Xiaogan (China). College of Chemistry and Materials Science
  6. Chinese Academy of Sciences (CAS), Shanghai (China). Institute of Applied Physics, Shanghai Synchrotron Radiation Facility
  7. Universidad Nacional de San Luis (UNSL) (Argentina). Instituto de Investigaciones en Tecnología Química (INTEQUI); Universidad Nacional de San Luis (UNSL) (Argentina). CONICET; Universidad Nacional de San Luis (UNSL) (Argentina) Facultad de Quím. Bioquím. y Farm.
  8. Wuhan Univ. (China). Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education, School of Physics
  9. Inst. Laue-Langevin (ILL), Grenoble (France)
  10. Dept. of Energy and Environment, Consejo Superior de Investigaciones Cientificas (CSIC), Madrid (Spain). Inst. de Ciencia de Materiales de Madrid Cantoblanco
  11. Univ. of Wollongong, NSW (Australia). Australian Institute for Innovative Materials, Institute for Superconducting and Electronic Materials
+ Show Author Affiliations
For reaching high-performance of electrode materials, it is generally believed that understanding the structure evolution and heterogeneous alignment effect is the key. Presently, a very simple and universally applicable self-healing method is investigated to prepare defect-free Prussian blue analogs (PBAs) that reach their theoretical capacity as cathode materials for sodium-ion batteries (SIBs). For direct imaging of the local structure and the dynamic process at the atomic scale, we deliver a fast ion-conductive nickel-based PBA that enables rapid Na+ extraction/insertion within 3 minutes and a capacity retention of nearly 100% over 4000 cycles. This guest-ion disordered and quasi-zero-strain nonequilibrium solid–solution reaction mechanism provides an effective guarantee for realizing long-cycle life and high-rate capability electrode materials that operate via reversible two-phase transition reaction. Unconventional materials and mechanisms that enable reversible insertion/extraction of ions in low-cost metal–organic frameworks (MOFs) within minutes have implications for fast-charging devices, grid-scale energy storage applications, material discovery, and tailored modification.
Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
National Key R&D Program of China; National Natural Science Foundation of China; USDOE
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1809968
Journal Information:
Energy & Environmental Science, Journal Name: Energy & Environmental Science Journal Issue: 5 Vol. 14; ISSN 1754-5692
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English

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