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Unveiling the Stable Nature of the Solid Electrolyte Interphase between Lithium Metal and LiPON via Cryogenic Electron Microscopy

Journal Article · · Joule

Not Available

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI ID:
1831321
Alternate ID(s):
OSTI ID: 1706485
OSTI ID: 1809853
Journal Information:
Joule, Journal Name: Joule Journal Issue: 11 Vol. 4; ISSN 2542-4351
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (56)

Promises, Challenges, and Recent Progress of Inorganic Solid-State Electrolytes for All-Solid-State Lithium Batteries journal February 2018
Strategies Based on Nitride Materials Chemistry to Stabilize Li Metal Anode journal March 2017
Solid Electrolyte: the Key for High-Voltage Lithium Batteries journal October 2014
Stack Pressure Considerations for Room‐Temperature All‐Solid‐State Lithium Metal Batteries journal November 2019
Kinetics‐Controlled Degradation Reactions at Crystalline LiPON/Li x CoO 2 and Crystalline LiPON/Li‐Metal Interfaces journal March 2018
The sei model—application to lithium-polymer electrolyte batteries journal October 1995
Ionic conductivity of pure and doped Li3N journal October 1983
Electrical properties of amorphous lithium electrolyte thin films journal July 1992
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set journal July 1996
Review of selected electrode–solution interactions which determine the performance of Li and Li ion batteries journal August 2000
Intergranular Li metal propagation through polycrystalline Li6.25Al0.25La3Zr2O12 ceramic electrolyte journal January 2017
Correlating Structure and Function of Battery Interphases at Atomic Resolution Using Cryoelectron Microscopy journal October 2018
Unraveling the Nanoscale Heterogeneity of Solid Electrolyte Interphase Using Tip-Enhanced Raman Spectroscopy journal August 2019
High-Efficiency Lithium-Metal Anode Enabled by Liquefied Gas Electrolytes journal August 2019
Electrochemical behaviors of a Li3N modified Li metal electrode in secondary lithium batteries journal October 2011
Effects of cathode electrolyte interfacial (CEI) layer on long term cycling of all-solid-state thin-film batteries journal August 2016
Interfacial instability of amorphous LiPON against lithium: A combined Density Functional Theory and spectroscopic study journal June 2017
Characterization of Li2S?P2S5 glass-ceramics as a solid electrolyte for lithium secondary batteries journal November 2004
Interface reactions between LiPON and lithium studied by in-situ X-ray photoemission journal May 2015
Analysis of the structural evolution of the SEI layer in FeF2 thin-film lithium-ion batteries upon cycling using HRTEM and EELS journal May 2017
Interface Stability in Solid-State Batteries journal December 2015
Direct Observation of the Interfacial Instability of the Fast Ionic Conductor Li 10 GeP 2 S 12 at the Lithium Metal Anode journal March 2016
In Situ STEM-EELS Observation of Nanoscale Interfacial Phenomena in All-Solid-State Batteries journal May 2016
Interfacial Stability of Li Metal–Solid Electrolyte Elucidated via in Situ Electron Microscopy journal October 2016
New Insights on the Structure of Electrochemically Deposited Lithium Metal and Its Solid Electrolyte Interphases via Cryogenic TEM journal November 2017
Origin of Outstanding Stability in the Lithium Solid Electrolyte Materials: Insights from Thermodynamic Analyses Based on First-Principles Calculations journal October 2015
Unraveling the Formation Mechanism of Solid–Liquid Electrolyte Interphases on LiPON Thin Films journal February 2019
Resolving Nanoscopic and Mesoscopic Heterogeneity of Fluorinated Species in Battery Solid-Electrolyte Interphases by Cryogenic Electron Microscopy journal March 2020
Cryogenic Focused Ion Beam Characterization of Lithium Metal Anodes journal January 2019
Visualizing Chemomechanical Degradation of a Solid-State Battery Electrolyte journal May 2019
Resolving the Amorphous Structure of Lithium Phosphorus Oxynitride (Lipon) journal July 2018
Interface Limited Lithium Transport in Solid-State Batteries journal December 2013
Reviving the lithium metal anode for high-energy batteries journal March 2017
Operando X-ray photoelectron spectroscopy of solid electrolyte interphase formation and evolution in Li2S-P2S5 solid-state electrolytes journal June 2018
Review on modeling of the anode solid electrolyte interphase (SEI) for lithium-ion batteries journal March 2018
Monolithic solid–electrolyte interphases formed in fluorinated orthoformate-based electrolytes minimize Li depletion and pulverization journal September 2019
Cryo-STEM mapping of solid–liquid interfaces and dendrites in lithium-metal batteries journal August 2018
Quantifying inactive lithium in lithium metal batteries journal August 2019
3D visualization of inhomogeneous multi-layered structure and Young's modulus of the solid electrolyte interphase (SEI) on silicon anodes for lithium ion batteries journal January 2014
First principles study on electrochemical and chemical stability of solid electrolyte–electrode interfaces in all-solid-state Li-ion batteries journal January 2016
The pursuit of solid-state electrolytes for lithium batteries: from comprehensive insight to emerging horizons journal January 2016
Parameter-free calculations of X-ray spectra with FEFF9 journal January 2010
A novel all-solid electrolyte based on a co-polymer of poly-(methoxy/hexadecal-poly(ethylene glycol) methacrylate) for lithium-ion cell journal January 2012
A climbing image nudged elastic band method for finding saddle points and minimum energy paths journal December 2000
Commentary: The Materials Project: A materials genome approach to accelerating materials innovation journal July 2013
Perspective: Highly stable vapor-deposited glasses journal December 2017
Bookworms and party animals: an artificial labour market with human and social capital accumulation journal August 2012
Accurate and simple density functional for the electronic exchange energy: Generalized gradient approximation journal June 1986
Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium journal May 1994
From ultrasoft pseudopotentials to the projector augmented-wave method journal January 1999
Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy journal October 2017
A Stable Thin-Film Lithium Electrolyte: Lithium Phosphorus Oxynitride journal January 1997
The Surface Chemistry of Lithium Electrodes in Alkyl Carbonate Solutions journal January 1994
The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems—The Solid Electrolyte Interphase Model journal January 1979
Perspective—Fluorinating Interphases journal December 2018
In situ and operando probing of solid–solid interfaces in electrochemical devices journal October 2018

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