Thermal conversion of unsolvated Mg(B3H8)2 to BH4- in the presence of MgH2

Gigante, Angelina; Leick, Noemi; Lipton, Andrew S.; Tran, Ba L.; Strange, Nicholas A.; Bowden, Mark E.; Martinez, Madison; Moury, Romain; Gennett, Thomas; Hagemann, Hans R.; Autrey, S Thomas

doi:10.1021/acsaem.1c00159

Thermal conversion of unsolvated Mg(B3H8)2 to BH4- in the presence of MgH2

Journal Article · Mon Apr 26 04:00:00 EDT 2021 · ACS Applied Energy Materials

DOI:https://doi.org/10.1021/acsaem.1c00159· OSTI ID:1808279

Gigante, Angelina ^[1]; Leick, Noemi ^[2]; ^[3]; Tran, Ba L. ^[3]; Strange, Nicholas A. ^[2]; Bowden, Mark E. ^[3]; Martinez, Madison ^[2]; Moury, Romain ^[1]; Gennett, Thomas ^[2]; Hagemann, Hans R. ^[4]; ^[3]

University of Geneva
National Renewable Energy Laboratory
BATTELLE (PACIFIC NW LAB)
VISITORS

In the search for energy storage materials, metal octahydrotriborates, M(B3H8)n, n=1,2, are promising candidates but their synthesis suffers from residual solvents which tend to interact and greatly alter their decomposition mechanism. Therefore, we studied the thermal conversion of unsolvated Mg(B3H8)2 to BH4 -: as synthesized, and in the presence of MgH2. The conversion of our unsolvated Mg(B3H8)2 starts at ~100°C and yields ~22 wt% of BH4 - along with the formation of (closo-hydro)borates and volatile boranes. This loss of boron (B) is a sign of poor cyclability of the system. However, the addition of MgH2 to unsolvated Mg(B3H8)2 drastically increases the thermal conversion to 85-88wt% of BH4 - while simultaneously decreasing the amounts of B-losses. Our results strongly indicate that the presence of activated MgH2 substantially decreases the formation of (closohydro) borates and provides the necessary H2 for the B3H8-to-BH4 conversion. This is the first report of a metal octahydrotriborate system to selectively convert to BH4 - under moderate conditions of temperature (200°C) in less than 1h, making the MgB3H8-MgH2 system very promising for energy storage applications.

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1808279

Report Number(s):: PNNL-SA-158858

Journal Information:: ACS Applied Energy Materials, Journal Name: ACS Applied Energy Materials Journal Issue: 4 Vol. 4

Country of Publication:: United States

Language:: English

References (76)

Status and prospects of hydroborate electrolytes for all-solid-state batteries Duchêne, Léo; Remhof, Arndt; Hagemann, Hans Energy Storage Materials, Vol. 25 https://doi.org/10.1016/j.ensm.2019.08.032	journal	March 2020
Boron Hydrogen Compounds for Hydrogen Storage and as Solid Ionic Conductors Hagemann, Hans CHIMIA International Journal for Chemistry, Vol. 73, Issue 11 https://doi.org/10.2533/chimia.2019.868	journal	November 2019
Breaking the passivation—the road to a solvent free borohydride synthesis Friedrichs, O.; Remhof, A.; Borgschulte, A. Physical Chemistry Chemical Physics, Vol. 12, Issue 36 https://doi.org/10.1039/c0cp00022a	journal	January 2010
A New Class of CVD Precursors to Metal Borides: Cr(B ₃ H ₈ ) ₂ and Related Octahydrotriborate Complexes Goedde, Dean M.; Girolami, Gregory S. Journal of the American Chemical Society, Vol. 126, Issue 39 https://doi.org/10.1021/ja046906c	journal	October 2004
Facile Synthesis of Unsolvated Alkali Metal Octahydrotriborate Salts MB ₃ H ₈ (M=K, Rb, and Cs), Mechanisms of Formation, and the Crystal Structure of KB ₃ H ₈ Chen, Xi‐Meng; Ma, Nana; Liu, Xin‐Ran Angewandte Chemie International Edition, Vol. 58, Issue 9 https://doi.org/10.1002/anie.201812795	journal	February 2019
Local Structure of Amorphous (PbO) _x [(B ₂ O ₃ ) ₁ _- _z (Al ₂ O ₃ ) _z ] _y (SiO ₂ ) _y Dielectric Materials by Multinuclear Solid State NMR Sawvel, April M.; Chinn, Sarah C.; Bourcier, William L. Chemistry of Materials, Vol. 17, Issue 6 https://doi.org/10.1021/cm035261x	journal	February 2005
A theoretical study of the spectroscopic properties of B2H6 and of a series of B H y z − species (x = 1−12, y = 3−14, z = 0−2): From BH3 to B12 H 12 2 − Sethio, Daniel; Lawson Daku, Latévi Max; Hagemann, Hans International Journal of Hydrogen Energy, Vol. 41, Issue 16 https://doi.org/10.1016/j.ijhydene.2016.02.121	journal	May 2016
Reduction of borane THF by alkali metal (potassium, rubidium, cesium) and ytterbium mercury amalgams to form salts of octahydrotriborate(1-); a simple procedure for the synthesis of tetraborane(10) Hill, Tara G.; Godfroid, Robert A.; White, James P. Inorganic Chemistry, Vol. 30, Issue 14 https://doi.org/10.1021/ic00014a024	journal	July 1991
Thermolysis and solid state NMR studies of NaB ₃ H ₈ , NH ₃ B ₃ H ₇ , and NH ₄ B ₃ H ₈ Huang, Zhenguo; Eagles, Mitch; Porter, Spencer Dalton Trans., Vol. 42, Issue 3 https://doi.org/10.1039/C2DT31365K	journal	January 2013
The Sodium-Diborane Reaction ¹ Hough, William V.; Edwards, Lawrence J.; McElroy, Albert D. Journal of the American Chemical Society, Vol. 80, Issue 8 https://doi.org/10.1021/ja01541a015	journal	April 1958
How to Design Hydrogen Storage Materials? Fundamentals, Synthesis, and Storage Tanks Lai, Qiwen; Sun, Yahui; Wang, Ting Advanced Sustainable Systems, Vol. 3, Issue 9 https://doi.org/10.1002/adsu.201900043	journal	June 2019
Ionic Transport in Potential Coating Materials for Mg Batteries Chen, Tina; Sai Gautam, Gopalakrishnan; Canepa, Pieremanuele Chemistry of Materials, Vol. 31, Issue 19 https://doi.org/10.1021/acs.chemmater.9b02692	journal	September 2019
Li(NH ₃ )B ₃ H ₈ : a new ionic liquid octahydrotriborate Zheng, Xiongfei; Yang, Yanjing; Li, Mengxuan Chemical Communications, Vol. 55, Issue 3 https://doi.org/10.1039/C8CC08300B	journal	January 2019
Halide-Stabilized LiBH ₄ , a Room-Temperature Lithium Fast-Ion Conductor Maekawa, Hideki; Matsuo, Motoaki; Takamura, Hitoshi Journal of the American Chemical Society, Vol. 131, Issue 3 https://doi.org/10.1021/ja807392k	journal	January 2009
Reversible Storage of Hydrogen in Destabilized LiBH ₄ Vajo, John J.; Skeith, Sky L.; Mertens, Florian The Journal of Physical Chemistry B, Vol. 109, Issue 9 https://doi.org/10.1021/jp040769o	journal	March 2005
A dynamic calibration technique for temperature programmed desorption spectroscopy Hurst, K. E.; Heben, M. J.; Blackburn, J. L. Review of Scientific Instruments, Vol. 84, Issue 2 https://doi.org/10.1063/1.4770115	journal	February 2013
Boron-11 NMR spectra of boranes, main-group heteroboranes, and substituted derivatives. Factors influencing chemical shifts of skeletal atoms Hermanek, Stanislav Chemical Reviews, Vol. 92, Issue 2 https://doi.org/10.1021/cr00010a007	journal	March 1992
Pressure and Temperature Influence on the Desorption Pathway of the LiBH ₄ −MgH ₂ Composite System Bösenberg, Ulrike; Ravnsbæk, Dorthe B.; Hagemann, Hans The Journal of Physical Chemistry C, Vol. 114, Issue 35 https://doi.org/10.1021/jp104814u	journal	August 2010
Chemistry of Boranes. XX. Syntheses of Polyhedral Boranes Miller, H. C.; Miller, N. E.; Muetterties, E. L. Inorganic Chemistry, Vol. 3, Issue 10 https://doi.org/10.1021/ic50020a026	journal	October 1964
A Tracer Study of the Reaction between Tetraborane and Sodium Tetradeuterioborate(III) Parry, R. W.; Rudolph, R. W.; Shriver, D. F. Inorganic Chemistry, Vol. 3, Issue 11 https://doi.org/10.1021/ic50021a002	journal	November 1964
An alternative approach to the synthesis of NaB3H8 and Na2B12H12 for solid electrolyte applications Moury, R.; Gigante, A.; Hagemann, H. International Journal of Hydrogen Energy, Vol. 42, Issue 35 https://doi.org/10.1016/j.ijhydene.2017.02.044	journal	August 2017
Low-Temperature Synthesis of LiBH ₄ by Gas-Solid Reaction Friedrichs, Oliver; Borgschulte, Andreas; Kato, Shunsuke Chemistry - A European Journal, Vol. 15, Issue 22 https://doi.org/10.1002/chem.200900471	journal	May 2009
Ionic Conduction Mechanism in the Na ₂ (B ₁₂ H ₁₂ ) _0.5 (B ₁₀ H ₁₀ ) _0.5 closo -Borate Solid-State Electrolyte: Interplay of Disorder and Ion–Ion Interactions Duchêne, Léo; Lunghammer, Sarah; Burankova, Tatsiana Chemistry of Materials, Vol. 31, Issue 9 https://doi.org/10.1021/acs.chemmater.9b00610	journal	April 2019
Direct Solution‐Based Synthesis of Na ₄ (B ₁₂ H ₁₂ )(B ₁₀ H ₁₀ ) Solid Electrolyte Gigante, Angelina; Duchêne, Léo; Moury, Romain ChemSusChem, Vol. 12, Issue 21 https://doi.org/10.1002/cssc.201902152	journal	October 2019
The NIST Chemistry WebBook: A Chemical Data Resource on the Internet ^† Linstrom, Peter J.; Mallard, William G. Journal of Chemical & Engineering Data, Vol. 46, Issue 5 https://doi.org/10.1021/je000236i	journal	September 2001
Nido -Borate/ Closo -Borate Mixed-Anion Electrolytes for All-Solid-State Batteries Payandeh, SeyedHosein; Asakura, Ryo; Avramidou, Petroula Chemistry of Materials, Vol. 32, Issue 3 https://doi.org/10.1021/acs.chemmater.9b03933	journal	January 2020
Preparation of sodium borohydride by the reaction of MgH2 with dehydrated borax through ball milling at room temperature Li, Z. P.; Morigazaki, N.; Liu, B. H. Journal of Alloys and Compounds, Vol. 349, Issue 1-2 https://doi.org/10.1016/S0925-8388(02)00872-1	journal	February 2003
Quantitative Assessment of B−B−B, B−H _b −B, and B−H _t Bonds: From BH ₃ to B ₁₂ H ₁₂ ²⁻ Sethio, Daniel; Daku, Latévi Max Lawson; Hagemann, Hans ChemPhysChem, Vol. 20, Issue 15 https://doi.org/10.1002/cphc.201900364	journal	July 2019
The Preparation and Structure of the Diammoniate of Tetraborane ¹ Kodama, G.; Parry, R. W. Journal of the American Chemical Society, Vol. 82, Issue 24 https://doi.org/10.1021/ja01509a012	journal	December 1960
Facile preparation and dehydrogenation of unsolvated KB ₃ H ₈ Zheng, Xiongfei; Yang, Yanjing; Zhao, Fengqi Chem. Commun., Vol. 53, Issue 80 https://doi.org/10.1039/C7CC06414D	journal	January 2017
Theoretical Prediction of Metastable Intermediates in the Decomposition of Mg(BH ₄ ) ₂ Zhang, Yongsheng; Majzoub, Eric; Ozoliņš, Vidvuds The Journal of Physical Chemistry C, Vol. 116, Issue 19 https://doi.org/10.1021/jp302303z	journal	May 2012
An Improved Broadband Decoupling Sequence for Liquid Crystals and Solids Fung, B. M.; Khitrin, A. K.; Ermolaev, Konstantin Journal of Magnetic Resonance, Vol. 142, Issue 1 https://doi.org/10.1006/jmre.1999.1896	journal	January 2000
Morphology‐Dependent Stability of Complex Metal Hydrides and Their Intermediates Using First‐Principles Calculations Kang, ShinYoung; Heo, Tae Wook; Allendorf, Mark D. ChemPhysChem, Vol. 20, Issue 10 https://doi.org/10.1002/cphc.201801132	journal	March 2019
Interplay between the Reorientational Dynamics of the B ₃ H ₈ ^– Anion and the Structure in KB ₃ H ₈ Andersson, M. S.; Grinderslev, J. B.; Chen, X. -M. The Journal of Physical Chemistry C, Vol. 125, Issue 7 https://doi.org/10.1021/acs.jpcc.0c10186	journal	February 2021
Estimation of Thermodynamic Properties of Metal Hydroborates Hagemann, Hans ChemistrySelect, Vol. 4, Issue 31 https://doi.org/10.1002/slct.201901776	journal	August 2019
Temperature Dependence of 207 Pb MAS Spectra of Solid Lead Nitrate. An Accurate, Sensitive Thermometer for Variable-Temperature MAS Bielecki, Anthony; Burum, Douglas P. Journal of Magnetic Resonance, Series A, Vol. 116, Issue 2 https://doi.org/10.1006/jmra.1995.0010	journal	October 1995
Boron–nitrogen–hydrogen (BNH) compounds: recent developments in hydrogen storage, applications in hydrogenation and catalysis, and new syntheses Huang, Zhenguo; Autrey, Tom Energy & Environmental Science, Vol. 5, Issue 11 https://doi.org/10.1039/c2ee23039a	journal	January 2012
The Reaction of Lewis Acids of Boron with Sodium Hydride and Borohydride ^1, Brown, Herbert C.; Tierney, Paul A. Journal of the American Chemical Society, Vol. 80, Issue 7 https://doi.org/10.1021/ja01540a011	journal	April 1958
A simplified preparation of B3H8− salts Dewkett, William J.; Grace, Michael; Beall, Herbert Journal of Inorganic and Nuclear Chemistry, Vol. 33, Issue 5 https://doi.org/10.1016/0022-1902(71)80420-7	journal	May 1971
Low temperature and paramagnetic ion effects on the proton and boron-11 nuclear magnetic resonance spectra of the triborohydride in (B ₃ H ₈ ^– ) Marynick, Dennis; Onak, Thomas J. Chem. Soc. A, Vol. 0, Issue 0 https://doi.org/10.1039/J19700001160	journal	January 1970
Processing of NaBH4 from NaBO2 with MgH2 by ball milling and usage as hydrogen carrier Çakanyıldırım, Çetin; Gürü, Metin Renewable Energy, Vol. 35, Issue 9 https://doi.org/10.1016/j.renene.2010.01.001	journal	September 2010
Three-Coordinated Boron-11 Chemical Shifts in Borates Kroeker, Scott; Stebbins, Jonathan F. Inorganic Chemistry, Vol. 40, Issue 24 https://doi.org/10.1021/ic010305u	journal	November 2001
Heterostructures Built in Metal Hydrides for Advanced Hydrogen Storage Reversibility Wang, Yanran; Chen, Xiaowei; Zhang, Hongyu Advanced Materials, Vol. 32, Issue 31 https://doi.org/10.1002/adma.202002647	journal	June 2020
Temperature dependence of the proton nuclear magnetic resonance spectra of copper(I) borane complexes, B3H8- salts, and icosahedral carboranes. Quadrupole-induced spin decoupling. Fluxional behavior Bushweller, C. Hackett; Beall, Herbert; Grace, Michael Journal of the American Chemical Society, Vol. 93, Issue 9 https://doi.org/10.1021/ja00738a009	journal	May 1971
Operando MAS NMR Reaction Studies at High Temperatures and Pressures Walter, Eric D.; Qi, Long; Chamas, Ali The Journal of Physical Chemistry C, Vol. 122, Issue 15 https://doi.org/10.1021/acs.jpcc.7b11442	journal	January 2018
Study of the NaBH 4 –NaBr system and the behaviour of its low temperature phase transition Paterakis, Christos; Guo, Sheng; Heere, Michael International Journal of Hydrogen Energy, Vol. 42, Issue 35 https://doi.org/10.1016/j.ijhydene.2017.03.045	journal	August 2017
Chemical activation of MgH2; a new route to superior hydrogen storage materials Johnson, Simon R.; Anderson, Paul A.; Edwards, Peter P. Chemical Communications, Issue 22 https://doi.org/10.1039/B503085D	journal	January 2005
Selective Reversible Hydrogenation of Mg(B ₃ H ₈ ) ₂ /MgH ₂ to Mg(BH ₄ ) ₂ : Pathway to Reversible Borane-Based Hydrogen Storage? Chong, Marina; Matsuo, Motoaki; Orimo, Shin-ichi Inorganic Chemistry, Vol. 54, Issue 8 https://doi.org/10.1021/acs.inorgchem.5b00373	journal	March 2015
Structure and hindered motion of B3H8 anions in solids: An NMR study Paine, R. T.; Fukushima, Eiichi; Roeder, S. B. W. Chemical Physics Letters, Vol. 32, Issue 3 https://doi.org/10.1016/0009-2614(75)85241-9	journal	May 1975
High-capacity hydrogen release through hydrolysis of NaB3H8 Huang, Zhenguo; Chen, Xuenian; Yisgedu, Teshome International Journal of Hydrogen Energy, Vol. 36, Issue 12 https://doi.org/10.1016/j.ijhydene.2011.03.033	journal	June 2011
Experimental investigation of Mg(B ₃ H ₈ ) ₂ dimensionality, materials for energy storage applications Moury, Romain; Gigante, Angelina; Remhof, Arndt Dalton Transactions, Vol. 49, Issue 35 https://doi.org/10.1039/D0DT02170A	journal	January 2020
Boron: Its Role in Energy‐Related Processes and Applications Huang, Zhenguo; Wang, Suning; Dewhurst, Rian D. Angewandte Chemie International Edition, Vol. 59, Issue 23 https://doi.org/10.1002/anie.201911108	journal	April 2020
Volatile Magnesium Octahydrotriborate Complexes as Potential CVD Precursors to MgB ₂ . Synthesis and Characterization of Mg(B ₃ H ₈ ) ₂ and Its Etherates Kim, Do Young; Yang, Yu; Abelson, John R. Inorganic Chemistry, Vol. 46, Issue 22 https://doi.org/10.1021/ic701037t	journal	October 2007
THE HEATS OF DECOMPOSITION OF SOME HIGHER BORON HYDRIDES ¹ Gunn, Stuart R.; Green, LeRoy G. The Journal of Physical Chemistry, Vol. 65, Issue 12 https://doi.org/10.1021/j100829a015	journal	December 1961
Preparation of magnesium borohydride and diborane Batha, H. D.; Whitney, E. D.; Heying, T. L. Journal of Applied Chemistry, Vol. 12, Issue 11 https://doi.org/10.1002/jctb.5010121102	journal	November 1962
NaBH 4 regeneration from NaBO 2 by high-energy ball milling and its plausible mechanism Lang, Chengguang; Jia, Yi; Liu, Jiangwen International Journal of Hydrogen Energy, Vol. 42, Issue 18 https://doi.org/10.1016/j.ijhydene.2017.04.014	journal	May 2017
Dimagnesium iron(II) hydride, Mg2FeH6, containing octahedral FeH64- anions Didisheim, J. J.; Zolliker, P.; Yvon, K. Inorganic Chemistry, Vol. 23, Issue 13 https://doi.org/10.1021/ic00181a032	journal	June 1984
Efficient Synthesis of Sodium Borohydride: Balancing Reducing Agents with Intrinsic Hydrogen Source in Hydrated Borax Zhu, Yongyang; Ouyang, Liuzhang; Zhong, Hao ACS Sustainable Chemistry & Engineering, Vol. 8, Issue 35 https://doi.org/10.1021/acssuschemeng.0c04354	journal	August 2020
Nanostructured Metal Hydrides for Hydrogen Storage Schneemann, Andreas; White, James L.; Kang, ShinYoung Chemical Reviews, Vol. 118, Issue 22 https://doi.org/10.1021/acs.chemrev.8b00313	journal	October 2018
A stable 3 V all-solid-state sodium–ion battery based on a closo -borate electrolyte Duchêne, L.; Kühnel, R. -S.; Stilp, E. Energy & Environmental Science, Vol. 10, Issue 12 https://doi.org/10.1039/C7EE02420G	journal	January 2017
Elucidation of the Formation Mechanisms of the Octahydrotriborate Anion (B ₃ H ₈ ^– ) through the Nucleophilicity of the B–H Bond Chen, Xi-Meng; Ma, Nana; Zhang, Qian-Fan Journal of the American Chemical Society, Vol. 140, Issue 21 https://doi.org/10.1021/jacs.8b03785	journal	May 2018
The polyborane, carborane, carbocation continuum: architectural patterns Williams, Robert E. Chemical Reviews, Vol. 92, Issue 2 https://doi.org/10.1021/cr00010a001	journal	March 1992
Kinetics of Pyrolysis of Diborane ¹ Bragg, John K.; McCarty, Lewis V.; Norton, F. J. Journal of the American Chemical Society, Vol. 73, Issue 5 https://doi.org/10.1021/ja01149a066	journal	May 1951
A new synthesis of B3H8− ion Nainan, K. C.; Ryschkewitsch, G. E. Inorganic and Nuclear Chemistry Letters, Vol. 6, Issue 9 https://doi.org/10.1016/0020-1650(70)80095-2	journal	September 1970
Role of Cations in CO ₂ Adsorption, Dynamics, and Hydration in Smectite Clays under in Situ Supercritical CO ₂ Conditions Bowers, Geoffrey M.; Schaef, H. Todd; Loring, John S. The Journal of Physical Chemistry C, Vol. 121, Issue 1 https://doi.org/10.1021/acs.jpcc.6b11542	journal	December 2016
Magnesium borohydride as a hydrogen storage material: Properties and dehydrogenation pathway of unsolvated Mg(BH₄)₂ Soloveichik, G.; Gao, Y.; Rijssenbeek, J. International Journal of Hydrogen Energy, Vol. 34, Issue 2, p. 916-928 https://doi.org/10.1016/j.ijhydene.2008.11.016	journal	January 2009
Short and Medium Range Order in Sodium Aluminoborate Glasses. 2. Site Connectivities and Cation Distributions Studied by Rotational Echo Double Resonance NMR Spectroscopy Bertmer, Marko; Züchner, Lars; Chan, Jerry C. C. The Journal of Physical Chemistry B, Vol. 104, Issue 28 https://doi.org/10.1021/jp9941918	journal	July 2000
Pyrolysis of Diborane. Formation of Decaborane in Continuous Flow Reactor Polak, R. J.; Obenland, Clayton I&EC Product Research and Development, Vol. 3, Issue 3 https://doi.org/10.1021/i360011a015	journal	September 1964
Synthesis of lithium octahydrotriborate and investigation on its thermal decomposition Fu, He; Wang, Xiaojuan; Shao, Yunqi International Journal of Hydrogen Energy, Vol. 41, Issue 1 https://doi.org/10.1016/j.ijhydene.2015.10.081	journal	January 2016
Guanidinium octahydrotriborate: an ionic liquid with high hydrogen storage capacity Chen, Weidong; Huang, Zhenguo; Wu, Guotao Journal of Materials Chemistry A, Vol. 3, Issue 21 https://doi.org/10.1039/C5TA01158B	journal	January 2015
Reversible dehydrogenation of magnesium borohydride to magnesium triborane in the solid state under moderate conditions Chong, Marina; Karkamkar, Abhi; Autrey, Tom Chem. Commun., Vol. 47, Issue 4 https://doi.org/10.1039/C0CC03461D	journal	January 2011
Synthesis of a Bimetallic Dodecaborate LiNaB ₁₂ H ₁₂ with Outstanding Superionic Conductivity He, Liqing; Li, Hai-Wen; Nakajima, Hironori Chemistry of Materials, Vol. 27, Issue 16 https://doi.org/10.1021/acs.chemmater.5b01568	journal	August 2015
Potassium octahydridotriborate: diverse polymorphism in a potential hydrogen storage material and potassium ion conductor Grinderslev, Jakob B.; Møller, Kasper T.; Yan, Yigang Dalton Transactions, Vol. 48, Issue 24 https://doi.org/10.1039/C9DT00742C	journal	January 2019
Metal boranes: Progress and applications Hansen, Bjarne R. S.; Paskevicius, Mark; Li, Hai-Wen Coordination Chemistry Reviews, Vol. 323 https://doi.org/10.1016/j.ccr.2015.12.003	journal	September 2016
Convenient Preparations of Solutions Containing the Triborohydride Ion Gaines, Donald F.; Schaeffer, Riley; Tebbe, Fred Inorganic Chemistry, Vol. 2, Issue 3 https://doi.org/10.1021/ic50007a025	journal	June 1963
Hydrogen Storage in Magnesium Clusters: Quantum Chemical Study Wagemans, Rudy W. P.; van Lenthe, Joop H.; de Jongh, Petra E. Journal of the American Chemical Society, Vol. 127, Issue 47 https://doi.org/10.1021/ja054569h	journal	November 2005

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