skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Technical and economic feasibility of an integrated ethanol and anthocyanin coproduction process using purple corn stover

Journal Article · · Biofuels, Bioproducts & Biorefining
DOI:https://doi.org/10.1002/bbb.2212· OSTI ID:1807577
 [1]; ORCiD logo [2]; ORCiD logo [3]
  1. Univ. of Illinois at Urbana-Champaign, IL (United States)
  2. State Univ. of New York (SUNY), Syracuse, NY (United States)
  3. Univ. of Illinois at Urbana-Champaign, IL (United States); Center for Advanced Bioenergy and Bioproducts Innovation (CABBI), Urbana, IL (United States)

Abstract The coproduction of high‐value anthocyanin extract in the cellulosic ethanol process would diversify the co‐product market, increase revenue, and potentially improve the economics of the process. The high anthocyanin concentration in the cob and structural carbohydrates in residual stover make purple corn stover an attractive source for anthocyanin and ethanol coproduction. This study aimed to develop simulation models for processes integrating ethanol production and anthocyanin extraction using purple corn stover, to evaluate their techno‐economic feasibility, and to compare their performance with the conventional ethanol production process using corn stover. The annual ethanol production for plants processing 2000 MT dry feedstock / day was 148.6 million L/year for the integrated processes compared with 222.6 million L/year for the conventional process. Anthocyanin production in the modified processes using dilute acid‐based and water‐based anthocyanin extraction processes was 1779 and 1099 MT/year, respectively. Capital investments for the integrated processes ($448.1 to $443.8 million) were higher than the conventional process ($371.9 million). Due to high revenue from anthocyanin extract, the ethanol production cost for the integrated process using acid‐based anthocyanin extraction ($0.36/L) was 34.5% lower than conventional ethanol production ($0.55/L). The ethanol production cost for the integrated process using water‐based anthocyanin extraction ($0.68/L) was higher than conventional ethanol production due to low ethanol and anthocyanin yields. The minimum ethanol selling price for the integrated process using acid‐based anthocyanin extraction ($0.65/L) was also lower than the conventional process ($0.72/L), indicating an improvement in economic performance. © 2021 Society of Chemical Industry and John Wiley & Sons, Ltd

Research Organization:
Center for Advanced Bioenergy and Bioproducts Innovation (CABBI), Urbana, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Biological and Environmental Research (BER)
Grant/Contract Number:
SC0018420
OSTI ID:
1807577
Alternate ID(s):
OSTI ID: 1997879
Journal Information:
Biofuels, Bioproducts & Biorefining, Vol. 15, Issue 3; ISSN 1932-104X
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English

References (40)

Impact of disk milling on corn stover pretreated at commercial scale journal May 2017
Antioxidant and Prooxidant Activities of Elderberry ( Sambucus nigra ) Extract in Low-Density Lipoprotein Oxidation journal October 1998
Improvement of sugar yields from corn stover using sequential hot water pretreatment and disk milling journal September 2016
Variation in corn stover composition and energy content with crop maturity journal April 2005
Effects of Extraction Conditions on Improving the Yield and Quality of an Anthocyanin-Rich Purple Corn (Zea mays L.) Color Extract journal September 2007
Comparative techno-economic analysis of steam explosion, dilute sulfuric acid, ammonia fiber explosion and biological pretreatments of corn stover journal May 2017
Protective Effects of Anthocyanins from Blackberry in a Rat Model of Acute Lung Inflammation journal January 2003
Development of Sustainable Corn Stover Harvest Strategies for Cellulosic Ethanol Production journal February 2014
Process Design and Economics for Biochemical Conversion of Lignocellulosic Biomass to Ethanol: Dilute-Acid Pretreatment and Enzymatic Hydrolysis of Corn Stover report March 2011
Techno-economic comparison of process technologies for biochemical ethanol production from corn stover journal November 2010
Techno-Economic Analysis of Cellulosic Butanol Production from Corn Stover through Acetone–Butanol–Ethanol Fermentation journal June 2016
Modeling the process and costs of fuel ethanol production by the corn dry-grind process journal May 2006
Extraction of purple corn ( Zea mays L.) cob pigments and phenolic compounds using food-friendly solvents journal March 2018
Techno-economic analysis and life-cycle assessment of cellulosic isobutanol and comparison with cellulosic ethanol and n-butanol journal October 2013
Techno-economic analysis of co-located corn grain and corn stover ethanol plants journal February 2014
Corn Cob Characteristics in Irrigated Central Great Plains Studies journal March 2009
Economic Analysis of Cellulosic Ethanol Production from Sugarcane Bagasse Using a Sequential Deacetylation, Hot Water and Disk-Refining Pretreatment journal September 2019
The effect of pigment matrix, temperature and amount of carrier on the yield and final color properties of spray dried purple corn (Zea mays L.) cob anthocyanin powders journal July 2017
Effects of Commercial Anthocyanin-Rich Extracts on Colonic Cancer and Nontumorigenic Colonic Cell Growth journal October 2004
Identification and antioxidant activity of anthocyanins extracted from the seed and cob of purple corn (Zea mays L.) journal January 2010
Improving Nutritive Value of Purple Field Corn Residue and Rice Straw by Culturing with White-Rot Fungi journal May 2020
Structure−Function Relationships of Anthocyanins from Various Anthocyanin-Rich Extracts on the Inhibition of Colon Cancer Cell Growth journal October 2008
Impact of pretreatment and downstream processing technologies on economics and energy in cellulosic ethanol production journal January 2011
Improving technical and economic feasibility of water based anthocyanin recovery from purple corn using staged extraction approach journal December 2020
Oxidative stress and gene regulation journal February 2000
Coproduction of ethanol and power from switchgrass journal March 2009
Techno-economic feasibility analysis of blue and purple corn processing for anthocyanin extraction and ethanol production using modified dry grind process journal May 2018
Bio-waste corn-cob cellulose supported poly(hydroxamic acid) copper complex for Huisgen reaction: Waste to wealth approach journal January 2017
Characterization of Anthocyanin-Rich Waste from Purple Corncobs ( Zea mays L.) and Its Application to Color Milk journal November 2005
Optimization of microwave-assisted extraction of anthocyanins from purple corn (Zea mays L.) cob and identification with HPLC–MS journal July 2010
Partial flow of compressed-hot water through corn stover to enhance hemicellulose sugar recovery and enzymatic digestibility of cellulose journal December 2005
Pleurotus Ostreatus and Volvariella Volvacea Can Enhance the Quality of Purple Field Corn Stover and Modulate Ruminal Fermentation and Feed Utilization in Tropical Beef Cattle journal December 2019
Process design and techno-economic analysis of an integrated mango processing waste biorefinery journal June 2018
Biorefinery for combined production of jet fuel and ethanol from lipid-producing sugarcane: a techno-economic evaluation journal September 2017
Combined sugar yields for dilute sulfuric acid pretreatment of corn stover followed by enzymatic hydrolysis of the remaining solids journal December 2005
Comparative techno-economic analysis and reviews of n-butanol production from corn grain and corn stover journal December 2013
Anthocyanins: Natural Colorants with Health-Promoting Properties journal April 2010
Techno-economic analysis of biodiesel and ethanol co-production from lipid-producing sugarcane: Biodiesel and Ethanol Co-Production from Lipid-Producing Sugarcane journal March 2016
Comparative sugar recovery data from laboratory scale application of leading pretreatment technologies to corn stover journal December 2005
Engineering aspects of collecting corn stover for bioenergy journal November 2002