skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Separation of short-chain glucan oligomers from molten salt hydrate and hydrolysis to glucose

Journal Article · · Green Chemistry
DOI:https://doi.org/10.1039/D1GC00851J· OSTI ID:1806355
 [1];  [2]; ORCiD logo [3];  [1];  [4]
  1. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, China
  2. Department of Chemical Engineering, University of Massachusetts-Amherst, Amherst, USA
  3. Department of Chemical Engineering, University of Massachusetts-Amherst, Amherst, USA, Catalysis Center for Energy Innovation
  4. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, China, School of Chemical Engineering and Light Industry

Glucan oligomers obtained from cellulose hydrolysis in molten salt hydrate can be separated using anti-solvent precipitation with a high efficiency.

Sponsoring Organization:
USDOE
Grant/Contract Number:
SC0001004
OSTI ID:
1806355
Alternate ID(s):
OSTI ID: 1787430
Journal Information:
Green Chemistry, Journal Name: Green Chemistry Vol. 23 Journal Issue: 11; ISSN 1463-9262
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (46)

Cellulose Hydrolysis in Acidified LiBr Molten Salt Hydrate Media journal May 2015
Solubility of d -Glucose in Water and Ethanol/Water Mixtures journal November 2007
LiCl/HCl ionic solution for efficient conversion of lignocellulose into glucose under mild conditions journal December 2018
A review on the pretreatment of lignocellulose for high-value chemicals journal June 2017
Biocatalysis in ionic liquids – advantages beyond green technology journal August 2003
Monosaccharide separation from ZnCl2 molten salt hydrates by zeolite beta journal February 2017
Soluble Fiber Dextrin and Soluble Corn Fiber Supplementation Modify Indices of Health in Cecum and Colon of Sprague-Dawley Rats journal February 2013
Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering journal September 2006
Long-Chain Glucan Adsorption and Depolymerization in Zeolite-Templated Carbon Catalysts journal September 2015
Pretreatment of corn stover for sugar production using a two-stage dilute acid followed by wet-milling pretreatment process journal July 2016
Hydrolysis of cellulose in SO3H-functionalized ionic liquids journal October 2011
Formation of humins during degradation of carbohydrates and furfural derivatives in various solvents journal April 2019
Hydrolysis of cellulose to glucose by solid acid catalysts journal January 2013
Adsorption-enhanced hydrolysis of glucan oligomers into glucose over sulfonated three-dimensionally ordered mesoporous carbon catalysts journal January 2016
Ionic liquids and deep eutectic solvents for lignocellulosic biomass fractionation journal January 2017
Ionic liquids: Promising green solvents for lignocellulosic biomass utilization journal June 2017
Acidic Deep Eutectic Solvents As Hydrolytic Media for Cellulose Nanocrystal Production journal August 2016
Hydrolysis and Decomposition of Cellulose in Brönsted Acidic Ionic Liquids Under Mild Conditions journal November 2009
Efficient mechano-catalytic depolymerization of crystalline cellulose by formation of branched glucan chains journal January 2015
Mechanistic understanding of humin formation in the conversion of glucose and fructose to 5-hydroxymethylfurfural in [BMIM]Cl ionic liquid journal January 2020
Recent advances in membrane technologies for biorefining and bioenergy production journal July 2012
Glucose Solvation by the Ionic Liquid 1,3-Dimethylimidazolium Chloride:  A Simulation Study journal December 2007
Functional Inks for Printable Energy Storage Applications based on 2 D Materials journal March 2020
New lignocellulose pretreatments using cellulose solvents: a review: New lignocellulose pretreatments using cellulose solvents journal November 2012
Efficient catalytic conversion of cellulose to levulinic acid in the biphasic system of molten salt hydrate and methyl isobutyl ketone journal January 2020
Effect of cellooligosaccharide or synbiotic feeding on growth performance, fecal condition and hormone concentrations in Holstein calves: CELLOBIOSE OR SYNBIOTIC FEEDING IN CALVES journal April 2011
Water-soluble cellulose oligomer production by chemical and enzymatic synthesis: a mini-review: Water-soluble cellulose oligomer production: a mini-review journal June 2017
Cellulose hydrolysis over silica modified with chlorosulphonic acid in one pot synthesis journal April 2014
Natural deep eutectic solvents efficient catalytic conversion of cellulose to total reducing sugars (TRS) journal August 2020
Soluble Cello‐Oligosaccharides Produced by Carbon‐Catalyzed Hydrolysis of Cellulose journal May 2019
Review of Cellulose Non-Derivatizing Solvent Interactions with Emphasis on Activity in Inorganic Molten Salt Hydrates journal May 2013
Production of Monosugars from Lignocellulosic Biomass in Molten Salt Hydrates: Process Design and Techno-Economic Analysis journal June 2017
Separation of Glucose and Bioethanol in Biomass with Current Methods and Sorbents journal April 2013
Understanding Acidity of Molten Salt Hydrate Media for Cellulose Hydrolysis by Combining Kinetic Studies, Electrolyte Solution Modeling, Molecular Dynamics Simulations, and 13 C NMR Experiments journal September 2019
One-pot integrated processing of biopolymers to furfurals in molten salt hydrate: understanding synergy in acidity journal January 2017
Depolymerization of Cellulose Using Solid Catalysts in Ionic Liquids journal October 2008
Efficient Acid-Catalyzed Hydrolysis of Cellulose in Ionic Liquid journal August 2007
A two-stage pretreatment process using dilute hydrochloric acid followed by Fenton oxidation to improve sugar recovery from corn stover journal November 2016
An uncondensed lignin depolymerized in the solid state and isolated from lignocellulosic biomass: a mechanistic study journal January 2018
Performance evaluation and fouling analysis for reverse osmosis and nanofiltration membranes during processing of lignocellulosic biomass hydrolysate journal February 2014
Depolymerization of Cellulose Using Solid Catalysts in Ionic Liquids journal October 2008
High enhancement of the hydrolysis rate of cellulose after pretreatment with inorganic salt hydrates journal January 2020
Mechanical depolymerisation of acidulated cellulose: understanding the solubility of high molecular weight oligomers journal January 2013
Deep eutectic solvents (DESs) for cellulose dissolution: a mini-review journal November 2018
Homogeneous Metal Salt Solutions for Biomass Upgrading and Other Select Organic Reactions journal August 2019
Cellulose-Derived Oligomers Act as Damage-Associated Molecular Patterns and Trigger Defense-Like Responses journal February 2017

Related Subjects