3D printing of thermoset polymers and composites

Moore, Jeffrey S.; White, Scott R.; Robertson, Ian D.; Sottos, Nancy R.; Aw, Jia En

Title: 3D printing of thermoset polymers and composites

Patent · Tue Feb 16 00:00:00 EST 2021

OSTI ID:1805507

Moore, Jeffrey S.; White, Scott R.; Robertson, Ian D.; Sottos, Nancy R.; Aw, Jia En

The present disclosure provides a novel method of 3D printing using frontal polymerization chemistry. This method enables the printing of tough, high quality thermosets in a short time with the option of adding fiber reinforcement. As such, it facilitates fabrication of mechanically robust 3D-printed devices and structures.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-06CH11357

Assignee:: The Board of Trustees of the University of Illinois (Urbana, IL)

Patent Number(s):: 10,920,002

Application Number:: 15/979,029

OSTI ID:: 1805507

Resource Relation:: Patent File Date: 05/14/2018

Country of Publication:: United States

Language:: English

References (10)

Apopinene as a Biorenewable Monomer for Ring-Opening Metathesis Polymerization Thomson, Regan J.; Strick, Benjamin F.; Geiger, Franz M. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20170101488 US Patent Application 15/289686; 20170101488	patent-application	April 2017
Polymerizing Composition Method of Manufacture Thereof and Articles Comprising the Same Lesser, Alan James; Lampe, Matthew https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20190202953 US Patent Application 16/327541; 20190202953	patent-application	July 2019
Reaction Resin Mortar Curable by Frontal Polymerization and Method for Fixing Anchor Rods Buergel, Thomas; Pfeil, Armin https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160236983 US Patent Application 15/023317; 20160236983	patent-application	August 2016
Method Of Making A Self-Healing Composite System PAtrick, Jason F.; Hart, Kevin R.; Krull, Brett P. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150328848 US Patent Application 14/607759; 20150328848	patent-application	November 2015
Digitally-Controlled Three-Dimensional Printing Using Ring-Opening Metathesis Polymerization Matzner, Eynat; Yudovin-Farber, Ira; Vidavsky, Yuval https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20190039321 US Patent Application 16/075159; 20190039321	patent-application	February 2019
Fused Filament Fabrication Extruder Gordon, Mark Christopher https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160354977 US Patent Application 14/732761; 20160354977	patent-application	December 2016
Selective ring-opening cross-metathesis of cycloolefins Morgan, John P.; Morrill, Christie; Grubbs, Robert H. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6803429 US Patent Document 6,803,429	patent	October 2004
Wax particles for protection of activators, and multifunctional autonomically healing composite materials Moore, Jeffrey S.; Rule, Joseph D.; White, Scott R. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050250878 US Patent Application 10/840937; 20050250878	patent-application	November 2005
Light-Curing Slips for the Stereolithographic Preparation of Dental Ceramics Moszner, Norbert; Wachter, Wolfgang; Appert, Christoph https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100029801 US Patent Application 12/394452; 20100029801	patent-application	February 2010
Catalysts and Methods for Ring Opening Metathesis Polymerization Schrock, Richard Royce; Autenrieth, Benjamin https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20170240694 US Patent Application 15/452505; 20170240694	patent-application	August 2017

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