skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Recombination and Resistive Losses of Transferred Foil Contacts for Silicon Heterojunction Solar Cells

Journal Article · · Physica Status Solidi. Rapid Research Letters
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1];  [2];  [2]; ORCiD logo [3]
  1. Department of Materials Science and Engineering University of Central Florida Orlando FL 32816 USA, Resilient Intelligent Sustainable Energy Systems Faculty Cluster University of Central Florida Orlando FL 32816 USA
  2. School of Electrical, Computing and Energy Engineering Arizona State University Tempe AZ 85287-5706 USA
  3. Department of Materials Science and Engineering University of Central Florida Orlando FL 32816 USA, Resilient Intelligent Sustainable Energy Systems Faculty Cluster University of Central Florida Orlando FL 32816 USA, CREOL, The College of Optics and Photonics University of Central Florida Orlando FL 32816 USA, Florida Solar Energy Center University of Central Florida Cocoa FL 32922 USA

Silicon heterojunction (SHJ) solar cells have been studied extensively due to their potential to reach high energy conversion efficiencies. However, one of the limiting factors for this technology is the metallization, which uses low‐curing‐temperature silver pastes that result in fingers with higher bulk resistivity. Herein, a simple approach to fabricate the SHJ solar cell contacts is demonstrated with commercially available low‐cost silver (Ag) electrically conductive adhesive (ECA) pastes and aluminium (Al) foils. This technique can result in a transparent conductive oxide (TCO)‐free cell structure and has the potential to combine cell metallization and interconnection. Recombination and resistive loss analyses are performed on the fabricated test samples. A dark saturation current density at the contact ( J 0c ) of 3.05 fA cm −2 for test samples before annealing is reported. The analysis of the experimental and simulated photoluminescence (PL) images shows negligible added recombination. The contact resistivity ( ρ c ) value is 49.3 mΩ cm 2 after annealing which can be optimized by specialized ECA pastes.

Sponsoring Organization:
USDOE
Grant/Contract Number:
EE-0008155
OSTI ID:
1804829
Journal Information:
Physica Status Solidi. Rapid Research Letters, Journal Name: Physica Status Solidi. Rapid Research Letters Vol. 14 Journal Issue: 11; ISSN 1862-6254
Publisher:
Wiley Blackwell (John Wiley & Sons)Copyright Statement
Country of Publication:
Germany
Language:
English

References (24)

Low-temperature processes for passivation and metallization of high-efficiency crystalline silicon solar cells journal November 2018
Crystalline Silicon Device Loss Analysis Through Spatially Resolved Quantum Efficiency Measurements journal July 2017
Low Surface Recombination in Silicon-Heterojunction Solar Cells With Rear Laser-Fired Contacts From Aluminum Foils journal May 2015
Luminescence Image Analysis Using Finite-Element Models: Finished Solar Cell Analysis journal January 2020
Measurement of low resistive ohmic contacts on semiconductors journal January 1986
A Comprehensive Methodology to Evaluate Losses and Process Variations in Silicon Solar Cell Manufacturing journal September 2019
Bifacial silicon heterojunction solar cells with advanced Ag-free multi-wire metallization attached to ITO layers using new transparent conductive PAEK copolymers journal November 2019
High-efficiency Silicon Heterojunction Solar Cells: A Review journal January 2012
Silicon heterojunction solar cell with interdigitated back contacts for a photoconversion efficiency over 26% journal March 2017
Solar cell efficiency tables (Version 55)
  • Green, Martin A.; Dunlop, Ewan D.; Hohl‐Ebinger, Jochen
  • Progress in Photovoltaics: Research and Applications, Vol. 28, Issue 1 https://doi.org/10.1002/pip.3228
journal December 2019
Current Losses at the Front of Silicon Heterojunction Solar Cells journal January 2012
Solar cell contact resistance—A review journal May 1984
Detailed investigation of TLM contact resistance measurements on crystalline silicon solar cells journal July 2017
A cost roadmap for silicon heterojunction solar cells journal April 2016
A Comprehensive Evaluation of Contact Recombination and Contact Resistivity Losses in Industrial Silicon Solar Cells journal September 2020
Laser-fired rear contacts for crystalline silicon solar cells: LASER-FIRED CONTACTS journal January 2002
Silicon Heterojunction Solar Cells With Copper-Plated Grid Electrodes: Status and Comparison With Silver Thick-Film Techniques journal July 2014
Industrial Silicon Wafer Solar Cells – Status and Trends journal January 2012
Approaching the Schottky–Mott limit in van der Waals metal–semiconductor junctions journal May 2018
Silicon heterojunction solar cells: Recent technological development and practical aspects - from lab to industry journal December 2018
Determination of Metallization-Induced Recombination Losses of Screen-Printed Silicon Solar Cell Contacts and Their Dependence on the Doping Profile journal November 2018
Damage at hydrogenated amorphous/crystalline silicon interfaces by indium tin oxide overlayer sputtering journal October 2012
Investigation of the Internal Back Reflectance of Rear-Side Dielectric Stacks for c-Si Solar Cells journal April 2013
High-efficiency crystalline silicon solar cells: status and perspectives journal January 2016

Similar Records

Amorphous silicon enhanced metal-insulator-semiconductor contacts for silicon solar cells
Journal Article · Tue Oct 28 00:00:00 EDT 2014 · Journal of Applied Physics · OSTI ID:1804829

A Comprehensive Evaluation of Contact Recombination and Contact Resistivity Losses in Industrial Silicon Solar Cells
Journal Article · Mon Jul 06 00:00:00 EDT 2020 · IEEE Journal of Photovoltaics · OSTI ID:1804829

Molybdenum oxide MoO{sub x}: A versatile hole contact for silicon solar cells
Journal Article · Mon Dec 08 00:00:00 EST 2014 · Applied Physics Letters · OSTI ID:1804829

Related Subjects