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Energy efficient supercritical water desalination using a high-temperature heat pump: A zero liquid discharge desalination

Journal Article · · Desalination

Supercritical water desalination (SCWD) is zero liquid discharge technology that can potentially control the solubility of different electrolytes. However, SCWD is an energy-intensive process and requires high-quality thermal heat (> 450 °C). This study proposes the integration of a high-temperature heat pump to reduce the SCWD energy requirement. The integrated system energy consumption improves by 36% for 3.5% feed concentration and 14% for 20% feed, and the distillate cost reduces by 15% and 10%. Another benefit of the proposed integration is the system can be operated using only electricity as a heat source, as is the case with commonly used high-recovery thermal desalination technology. The integrated SCWD-heat pump system shows superior performance compared to the commercially used brine concentrator and crystallizer system. It is approximately 20% more energy-efficient for 25% feed concentration and 8% cheaper. Hence, the integrated SCWD-heat pump has the potential to outperform the pre-existing high-recovery desalination technology.

Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Grant/Contract Number:
AC36-08GO28308
OSTI ID:
1782805
Alternate ID(s):
OSTI ID: 1804366
OSTI ID: 1815272
Report Number(s):
NREL/JA-5700-79944; MainId:39162; UUID:1f2f8f04-845b-44a6-878c-9268d6ff60b8; MainAdminID:22446
Journal Information:
Desalination, Journal Name: Desalination Vol. 506; ISSN 0011-9164
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (36)

Synthesis of heat exchanger networks: I. Systematic generation of energy optimal networks journal July 1978
Supercritical Water as a Solvent journal April 2005
Thermodynamic Analysis of High‐Temperature Carnot Battery Concepts journal October 2019
Optimal Temperature Selection for Energy Integrated Multiple-Effect Evaporator System journal July 2017
Thermal performance and exergy analysis of a thermal vapor compression desalination system journal April 1996
CGAM problem: Definition and conventional solution journal March 1994
Parametric studies and optimisation of pumped thermal electricity storage journal January 2015
Thermal desalination via supercritical CO2 Brayton cycle: Optimal system design and techno-economic analysis without reduction in cycle efficiency journal April 2019
Multi-objective optimization of RO desalination plants journal March 2008
Electrodialysis, a mature technology with a multitude of new applications journal December 2010
A case study for treating a reverse osmosis brine using Eutectic Freeze Crystallization—Approaching a zero waste process journal January 2011
Pilot demonstration of the NH3/CO2 forward osmosis desalination process on high salinity brines journal March 2013
An operational and economic study of a reverse osmosis desalination system for potable water and land irrigation journal November 2016
Brine management methods: Recent innovations and current status journal April 2017
Desalination of hypersaline brines with joule-heating and chemical pre-treatment: Conceptual design and economics journal August 2017
Desalination of hypersaline brines via Joule-heating: Experimental investigations and comparison of results to existing models journal December 2017
Design and results of a first generation pilot plant for supercritical water desalination (SCWD) journal August 2018
Cogeneration using multi-effect distillation and a solar-powered supercritical carbon dioxide Brayton cycle journal June 2019
Experimental evaluation of using various renewable energy sources for heating a greenhouse journal October 2013
Levelised Cost of Storage for Pumped Heat Energy Storage in comparison with other energy storage technologies journal November 2017
Techno-economic analysis of hydraulic fracking flowback and produced water treatment in supercritical water reactor journal August 2017
Performance and cost evaluation of an innovative Pumped Thermal Electricity Storage power system journal November 2017
The system H2O–NaCl. Part I: Correlation formulae for phase relations in temperature–pressure–composition space from 0 to 1000°C, 0 to 5000bar, and 0 to 1 XNaCl journal October 2007
The system H2O–NaCl. Part II: Correlations for molar volume, enthalpy, and isobaric heat capacity from 0 to 1000°C, 1 to 5000bar, and 0 to 1 XNaCl journal October 2007
Solar assisted multiple-effect evaporator journal January 2017
Optimal feed flow sequence for multi-effect distillation system integrated with supercritical carbon dioxide Brayton cycle for seawater desalination journal September 2018
The Global Rise of Zero Liquid Discharge for Wastewater Management: Drivers, Technologies, and Future Directions journal June 2016
Design of a Process for Supercritical Water Desalination with Zero Liquid Discharge journal May 2015
Energy Integration of Multiple Effect Evaporators with Background Process and Appropriate Temperature Selection journal February 2016
Pumped thermal grid storage with heat exchange journal July 2017
Dielectric constant of water at very high temperature and pressure journal July 1983
A pumped thermal energy storage cycle with capacity for concentrated solar power integration conference July 2019
A Tool for Thermoeconomic Analysis and Optimization of Gas, Steam, and Combined Plants journal October 1997
Using Concentrating Solar Power to Create a Geological Thermal Energy Reservoir for Seasonal Storage and Flexible Power Plant Operation journal August 2020
Measurement of Averaged Heat Transfer Coefficients in High-Pressure Vessel during Charging with Hydrogen, Nitrogen or Argon Gas journal January 2007
Cost-Effective ZLD Technology for Desalination Concentrate Management: Cost-Effective ZLD Technology for Desalination Concentrate Management journal January 2018

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