Feasibility of TEMPO-functionalized imidazolium, ammonium and pyridinium salts as redox-active carriers in ethaline deep eutectic solvent for energy storage

Chen, Brian; Mitchell, Sarah; Sinclair, Nicholas; Wainright, Jesse; Pentzer, Emily; Gurkan, Burcu

doi:10.1039/d0me00038h

Feasibility of TEMPO-functionalized imidazolium, ammonium and pyridinium salts as redox-active carriers in ethaline deep eutectic solvent for energy storage

Journal Article · Tue Jun 23 00:00:00 EDT 2020 · Molecular Systems Design & Engineering

DOI:https://doi.org/10.1039/d0me00038h· OSTI ID:1803807

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Case Western Reserve Univ., Cleveland, OH (United States); OSTI
Texas A & M Univ., College Station, TX (United States)
Case Western Reserve Univ., Cleveland, OH (United States)

The discovery of electrolytes that have low vapor pressures and high solubility towards redox active species with an ability to undergo multiple electron transfer reactions is a challenge to realize in large-scale energy storage. In this work, we investigate the feasibility of (2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO) derived halide salts as redox active species in ethaline (1 : 2 ethylene glycol : choline chloride), a deep eutectic solvent (DES). Hydrogen bonding and electrostatic interactions achieved by the functionalization of TEMPO are shown to improve solubility in ethaline. This is the first study evaluating the physical properties and electrochemical behavior of the newly synthesized TEMPO-salts in ethaline providing insight into the impact of chemical functionality on the utility of these redox active species in DESs.

View Accepted Manuscript (DOE)

Research Organization:: Case Western Reserve Univ., Cleveland, OH (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019409

OSTI ID:: 1803807

Alternate ID(s):: OSTI ID: 1635411

Journal Information:: Molecular Systems Design & Engineering, Journal Name: Molecular Systems Design & Engineering Journal Issue: 6 Vol. 5; ISSN 2058-9689

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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