Coinage metal tris(dialkylamido)imidophosphorane complexes as transmetallation reagents for cerium complexes

Aguirre Quintana, Luis M.; Jiang, Ningxin; Bacsa, John; La Pierre, Henry S.

doi:10.1039/d0dt00842g

Coinage metal tris(dialkylamido)imidophosphorane complexes as transmetallation reagents for cerium complexes

Journal Article · Wed Apr 01 00:00:00 EDT 2020 · Dalton Transactions

DOI:https://doi.org/10.1039/d0dt00842g· OSTI ID:1803769

^[1]; Jiang, Ningxin ^[2]; Bacsa, John ^[2]; ^[3]

Georgia Institute of Technology, Atlanta, GA (United States). Dept. of Chemistry and Biochemistry; OSTI
Georgia Institute of Technology, Atlanta, GA (United States). Dept. of Chemistry and Biochemistry
Georgia Institute of Technology, Atlanta, GA (United States). Dept. of Chemistry and Biochemistry. Nuclear and Radiological Engineering Program

We report the synthesis of tetrameric Cu(I) and Ag(I) homoleptic complexes supported by the tris(piperidinyl)imidophosphorane [NP(pip)₃]^1- and [NP(1,2-bis-^tBu-diamidoethane)(NEt₂)]^1- ligands. These complexes demonstrate the redox stability of the imidophosphorane ligands to oxidizing salts, and the silver complexes can, in turn, serve as oxidative transmetallation reagents for the isolation of tetravalent cerium complexes from cerium metal or trivalent cerium precursors.

View Accepted Manuscript (DOE)

Research Organization:: Georgia Institute of Technology, Atlanta, GA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019385

OSTI ID:: 1803769

Alternate ID(s):: OSTI ID: 1608730

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 17 Vol. 49; ISSN 1477-9226

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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CCDC 1986759: Experimental Crystal Structure Determination Aguirre, Quintana, Luis M.; Ningxin, Jiang,; John, Bacsa, https://doi.org/10.5517/ccdc.csd.cc24pd08 The current record is supplemented by this dataset	dataset	January 2020
CCDC 1986792: Experimental Crystal Structure Determination Aguirre, Quintana, Luis M.; Ningxin, Jiang,; John, Bacsa, https://doi.org/10.5517/ccdc.csd.cc24pf2c The current record is supplemented by this dataset	dataset	January 2020
CCDC 1986797: Experimental Crystal Structure Determination Aguirre, Quintana, Luis M.; Ningxin, Jiang,; John, Bacsa, https://doi.org/10.5517/ccdc.csd.cc24pf7j The current record is supplemented by this dataset	dataset	January 2020
CCDC 1986799: Experimental Crystal Structure Determination Aguirre, Quintana, Luis M.; Ningxin, Jiang,; John, Bacsa, https://doi.org/10.5517/ccdc.csd.cc24pf9l The current record is supplemented by this dataset	dataset	January 2020

Coinage metal tris(dialkylamido)imidophosphorane complexes as transmetallation reagents for cerium complexes

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