Important features of the potential energy surface of the methylamine plus O(1D) reaction

Wolf, Mark E.; Hoobler, Preston R.; Turney, Justin M.; Schaefer, Henry F.

doi:10.1039/c9cp05039f

Important features of the potential energy surface of the methylamine plus O(¹D) reaction

Journal Article · Mon Oct 21 00:00:00 EDT 2019 · Physical Chemistry Chemical Physics. PCCP

DOI:https://doi.org/10.1039/c9cp05039f· OSTI ID:1803411

^[1]; ^[2]; ^[2]; ^[2]

Univ. of Georgia, Athens, GA (United States). Center for Computational Quantum Chemistry; OSTI
Univ. of Georgia, Athens, GA (United States). Center for Computational Quantum Chemistry

This research presents an ab initio characterization of the potential energy surface for the methylamine plus 1D oxygen atom reaction, which may be relevant to interstellar chemistry. Geometries and harmonic vibrational frequencies were determined for all stationary points at the CCSD(T)/aug-cc-pVTZ level of theory. The focal point method along with several additive corrections was used to obtain reliable CCSDT(Q)/CBS potential energy surface features. Extensive conformational analysis and intrinsic reaction coordinate computations were performed to ensure accurate chemical connectivity of the stationary points. Additionally, five minima were determined to be possible products of this reaction and three novel transition states were found that were previously unreported or mislabeled in the literature. The pathways we present can be used to guide further searches for NH₂ containing species in the interstellar medium.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Georgia, Athens, GA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0018412

OSTI ID:: 1803411

Alternate ID(s):: OSTI ID: 1572206

Journal Information:: Physical Chemistry Chemical Physics. PCCP, Journal Name: Physical Chemistry Chemical Physics. PCCP Journal Issue: 43 Vol. 21; ISSN 1463-9076

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (88)

Synthesis of Prebiotic Glycerol in Interstellar Ices Kaiser, Ralf I.; Maity, Surajit; Jones, Brant M. Angewandte Chemie International Edition, Vol. 54, Issue 1 https://doi.org/10.1002/anie.201408729	journal	October 2014
Definitive Ab Initio Studies of Model SN2 Reactions CH3X+F (X=F, Cl, CN, OH, SH, NH2, PH2) Gonzales, Jason M.; Pak, Chaeho; Cox, R. Sidney Chemistry - A European Journal, Vol. 9, Issue 10 https://doi.org/10.1002/chem.200204408	journal	May 2003
NBO 6.0 : Natural bond orbital analysis program Glendening, Eric D.; Landis, Clark R.; Weinhold, Frank Journal of Computational Chemistry, Vol. 34, Issue 16 https://doi.org/10.1002/jcc.23266	journal	March 2013
Theoretical study of possible ion-molecule reactions leading to precursors of glycine in the interstellar medium Largo, Antonio; Redondo, Pilar; Barrientos, Carmen International Journal of Quantum Chemistry, Vol. 98, Issue 4 https://doi.org/10.1002/qua.20070	journal	January 2004
Recursive intermediate factorization and complete computational linearization of the coupled-cluster single, double, triple, and quadruple excitation equations Kucharski, Stanislaw A.; Bartlett, Rodney J. Theoretica Chimica Acta, Vol. 80, Issue 4-5 https://doi.org/10.1007/BF01117419	journal	January 1991
Prebiotic Chemical Evolution in the Astrophysical Context Ziurys, L. M.; Adande, G. R.; Edwards, J. L. Origins of Life and Evolution of Biospheres, Vol. 45, Issue 1-2 https://doi.org/10.1007/s11084-015-9431-8	journal	April 2015
The adiabatic correction to molecular potential surfaces in the SCF approximation Sellers, Harrell; Pulay, Peter Chemical Physics Letters, Vol. 103, Issue 6 https://doi.org/10.1016/0009-2614(84)85277-X	journal	January 1984
A new implementation of the full CCSDT model for molecular electronic structure Scuseria, Gustavo E.; Schaefer, Henry F. Chemical Physics Letters, Vol. 152, Issue 4-5 https://doi.org/10.1016/0009-2614(88)80110-6	journal	November 1988
Non-iterative fifth-order triple and quadruple excitation energy corrections in correlated methods Bartlett, Rodney J.; Watts, J. D.; Kucharski, S. A. Chemical Physics Letters, Vol. 165, Issue 6 https://doi.org/10.1016/0009-2614(90)87031-L	journal	February 1990
Amino acids in meteorites Cronin, J. R.; Pizzarello, S. Advances in Space Research, Vol. 3, Issue 9 https://doi.org/10.1016/0273-1177(83)90036-4	journal	January 1983
A matrix-isolation infrared spectroscopic study of the reactions of methane and methanol with ozone Lugez, C.; Schriver, A.; Levant, R. Chemical Physics, Vol. 181, Issue 1-2 https://doi.org/10.1016/0301-0104(94)85021-6	journal	March 1994
A fifth-order perturbation comparison of electron correlation theories Raghavachari, Krishnan; Trucks, Gary W.; Pople, John A. Chemical Physics Letters, Vol. 157, Issue 6 https://doi.org/10.1016/S0009-2614(89)87395-6	journal	May 1989
Why CCSD(T) works: a different perspective Stanton, John F. Chemical Physics Letters, Vol. 281, Issue 1-3 https://doi.org/10.1016/S0009-2614(97)01144-5	journal	December 1997
One possible origin of ethanol in interstellar medium: Photochemistry of mixed CO2–C2H6 films at 11K. A FTIR study Schriver, A.; Schriver-Mazzuoli, L.; Ehrenfreund, P. Chemical Physics, Vol. 334, Issue 1-3 https://doi.org/10.1016/j.chemphys.2007.02.018	journal	April 2007
Ab initio study of the C+HNC, N+C2H, H+C2N and H+CNC reactions Loison, J. C.; Hickson, K. M. Chemical Physics Letters, Vol. 635 https://doi.org/10.1016/j.cplett.2015.05.060	journal	August 2015
Laboratory millimeter wave spectrum of N-methylhydroxylamine Kolesniková, L.; Alonso, E. R.; Mata, S. Journal of Molecular Spectroscopy, Vol. 335 https://doi.org/10.1016/j.jms.2017.03.006	journal	May 2017
First-principles study of the formation of glycine-producing radicals from common interstellar species Sato, Akimasa; Kitazawa, Yuya; Ochi, Toshiro Molecular Astrophysics, Vol. 10 https://doi.org/10.1016/j.molap.2018.01.002	journal	March 2018
Many – Body Methods in Chemistry and Physics Shavitt, Isaiah; Bartlett, Rodney J. https://doi.org/10.1017/CBO9780511596834	book	January 2009
The Molecular Universe Tielens, A. G. G. M. Proceedings of the International Astronomical Union, Vol. 7, Issue S280 https://doi.org/10.1017/s1743921311024823	journal	June 2011
Psi4 1.1: An Open-Source Electronic Structure Program Emphasizing Automation, Advanced Libraries, and Interoperability Parrish, Robert M.; Burns, Lori A.; Smith, Daniel G. A. Journal of Chemical Theory and Computation, Vol. 13, Issue 7 https://doi.org/10.1021/acs.jctc.7b00174	journal	June 2017
Pathways to Meteoritic Glycine and Methylamine Aponte, José C.; Elsila, Jamie E.; Glavin, Daniel P. ACS Earth and Space Chemistry, Vol. 1, Issue 1 https://doi.org/10.1021/acsearthspacechem.6b00014	journal	February 2017
Convergent Partially Augmented Basis Sets for Post-Hartree−Fock Calculations of Molecular Properties and Reaction Barrier Heights Papajak, Ewa; Truhlar, Donald G. Journal of Chemical Theory and Computation, Vol. 7, Issue 1 https://doi.org/10.1021/ct1005533	journal	December 2010
A Correlation of Reaction Rates Hammond, George S. Journal of the American Chemical Society, Vol. 77, Issue 2 https://doi.org/10.1021/ja01607a027	journal	January 1955
Formation of Amino Acid Precursors in the Interstellar Medium. A DFT Study of Some Gas-Phase Reactions Starting with Methylenimine Basiuk, Vladimir A. The Journal of Physical Chemistry A, Vol. 105, Issue 17 https://doi.org/10.1021/jp004116t	journal	May 2001
Combined Crossed Beam and Theoretical Studies of the N( ² D) + C ₂ H ₄ Reaction and Implications for Atmospheric Models of Titan Balucani, Nadia; Skouteris, Dimitrios; Leonori, Francesca The Journal of Physical Chemistry A, Vol. 116, Issue 43 https://doi.org/10.1021/jp3072316	journal	October 2012
Theoretical Examination of O( ¹ D) Insertion Reactions to Form Methanediol, Methoxymethanol, and Aminomethanol Hays, Brian M.; Widicus Weaver, Susanna L. The Journal of Physical Chemistry A, Vol. 117, Issue 32 https://doi.org/10.1021/jp400753r	journal	May 2013
Comets and the Formation of Biochemical Compounds on the Primitive Earth OrÓ, J. Nature, Vol. 190, Issue 4774 https://doi.org/10.1038/190389a0	journal	April 1961
Racemic amino acids from the ultraviolet photolysis of interstellar ice analogues Bernstein, Max P.; Dworkin, Jason P.; Sandford, Scott A. Nature, Vol. 416, Issue 6879 https://doi.org/10.1038/416401a	journal	March 2002
Amino acids from ultraviolet irradiation of interstellar ice analogues Muñoz Caro, G. M.; Meierhenrich, U. J.; Schutte, W. A. Nature, Vol. 416, Issue 6879 https://doi.org/10.1038/416403a	journal	March 2002
Collisional excitation of interstellar PO(X ² Π) by He: new ab initio potential energy surfaces and scattering calculations Lique, François; Jiménez-Serra, Izaskun; Viti, Serena Physical Chemistry Chemical Physics, Vol. 20, Issue 8 https://doi.org/10.1039/C7CP05605B	journal	January 2018
Extraterrestrial prebiotic molecules: photochemistry vs. radiation chemistry of interstellar ices Arumainayagam, Chris R.; Garrod, Robin T.; Boyer, Michael C. Chemical Society Reviews, Vol. 48, Issue 8 https://doi.org/10.1039/C7CS00443E	journal	January 2019
Low temperature reaction dynamics for CH ₃ OH + OH collisions on a new full dimensional potential energy surface Roncero, Octavio; Zanchet, Alexandre; Aguado, Alfredo Physical Chemistry Chemical Physics, Vol. 20, Issue 40 https://doi.org/10.1039/C8CP04970J	journal	January 2018
Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy Weigend, Florian; Ahlrichs, Reinhart Physical Chemistry Chemical Physics, Vol. 7, Issue 18, p. 3297-3305 https://doi.org/10.1039/b508541a	journal	January 2005
Formation of nitriles and imines in the atmosphere of Titan: combined crossed-beam and theoretical studies on the reaction dynamics of excited nitrogen atoms N(2D) with ethane Balucani, Nadia; Leonori, Francesca; Petrucci, Raffaele Faraday Discussions, Vol. 147 https://doi.org/10.1039/c004748a	journal	January 2010
Hydrogenation of solid hydrogen cyanide HCN and methanimine CH ₂ NH at low temperature Theule, P.; Borget, F.; Mispelaer, F. Astronomy & Astrophysics, Vol. 534 https://doi.org/10.1051/0004-6361/201117494	journal	October 2011
Is the reaction between formic acid and protonated aminomethanol a possible source of glycine precursors in the interstellar medium? Redondo, Pilar; Largo, Antonio; Barrientos, Carmen Astronomy & Astrophysics, Vol. 579 https://doi.org/10.1051/0004-6361/201526548	journal	July 2015
A rigorous detection of interstellar CH ₃ NCO: An important missing species in astrochemical networks Cernicharo, J.; Kisiel, Z.; Tercero, B. Astronomy & Astrophysics, Vol. 587 https://doi.org/10.1051/0004-6361/201527531	journal	February 2016
Submillimeter spectra of 2-hydroxyacetonitrile (glycolonitrile; HOCH ₂ CN) and its searches in GBT PRIMOS observations of Sgr B2(N) Margulès, L.; McGuire, B. A.; Senent, M. L. Astronomy & Astrophysics, Vol. 601 https://doi.org/10.1051/0004-6361/201628551	journal	April 2017
Rotational spectrum of methoxyamine up to 480 GHz: a laboratory study and astronomical search Kolesniková, L.; Tercero, B.; Alonso, E. R. Astronomy & Astrophysics, Vol. 609 https://doi.org/10.1051/0004-6361/201730744	journal	December 2017
Prebiotic molecules formation through the gas-phase reaction between HNO and CH ₂ CHOH ₂ ⁺ Redondo, Pilar; Martínez, Henar; Largo, Antonio Astronomy & Astrophysics, Vol. 603 https://doi.org/10.1051/0004-6361/201731186	journal	July 2017
Millimeter wave spectra of ethyl isocyanate and searches for it in Orion KL and Sagittarius B2 Kolesniková, L.; Alonso, E. R.; Tercero, B. Astronomy & Astrophysics, Vol. 616 https://doi.org/10.1051/0004-6361/201833223	journal	August 2018
The UMIST database for astrochemistry 2006 Woodall, J.; Agúndez, M.; Markwick-Kemper, A. J. Astronomy & Astrophysics, Vol. 466, Issue 3 https://doi.org/10.1051/0004-6361:20064981	journal	April 2007
Formation of methyl formate and other organic species in the warm-up phase of hot molecular cores Garrod, R. T.; Herbst, E. Astronomy & Astrophysics, Vol. 457, Issue 3 https://doi.org/10.1051/0004-6361:20065560	journal	September 2006
Toward subchemical accuracy in computational thermochemistry: Focal point analysis of the heat of formation of NCO and [H,N,C,O] isomers Schuurman, Michael S.; Muir, Steven R.; Allen, Wesley D. The Journal of Chemical Physics, Vol. 120, Issue 24 https://doi.org/10.1063/1.1707013	journal	June 2004
Collisional Deactivation of the Excited Singlet Oxygen Atoms and Their Insertion into the CH Bonds of Propane Yamazaki, Hideo; Cvetanović, R. J. The Journal of Chemical Physics, Vol. 41, Issue 12 https://doi.org/10.1063/1.1725802	journal	December 1964
Aminomethanol water elimination: Theoretical examination Feldmann, Michael T.; Widicus, Susanna L.; Blake, Geoffrey A. The Journal of Chemical Physics, Vol. 123, Issue 3 https://doi.org/10.1063/1.1935510	journal	July 2005
Coupled-cluster methods including noniterative corrections for quadruple excitations Bomble, Yannick J.; Stanton, John F.; Kállay, Mihály The Journal of Chemical Physics, Vol. 123, Issue 5 https://doi.org/10.1063/1.1950567	journal	August 2005
Sources of error in electronic structure calculations on small chemical systems Feller, David; Peterson, Kirk A.; Crawford, T. Daniel The Journal of Chemical Physics, Vol. 124, Issue 5 https://doi.org/10.1063/1.2137323	journal	February 2006
Approximate treatment of higher excitations in coupled-cluster theory. II. Extension to general single-determinant reference functions and improved approaches for the canonical Hartree–Fock case Kállay, Mihály; Gauss, Jürgen The Journal of Chemical Physics, Vol. 129, Issue 14 https://doi.org/10.1063/1.2988052	journal	October 2008
Relativistic corrections to electrical first-order properties using direct perturbation theory Stopkowicz, Stella; Gauss, Jürgen The Journal of Chemical Physics, Vol. 129, Issue 16 https://doi.org/10.1063/1.2998300	journal	October 2008
The diagonal correction to the Born–Oppenheimer approximation: Its effect on the singlet–triplet splitting of CH ₂ and other molecular effects Handy, Nicholas C.; Yamaguchi, Yukio; Schaefer, Henry F. The Journal of Chemical Physics, Vol. 84, Issue 8 https://doi.org/10.1063/1.450020	journal	April 1986
The full CCSDT model for molecular electronic structure Noga, Jozef; Bartlett, Rodney J. The Journal of Chemical Physics, Vol. 86, Issue 12 https://doi.org/10.1063/1.452353	journal	June 1987
Gaussian basis sets for use in correlated molecular calculations. I. The atoms boron through neon and hydrogen Dunning, Thom H. The Journal of Chemical Physics, Vol. 90, Issue 2 https://doi.org/10.1063/1.456153	journal	January 1989
Coupled‐cluster method truncated at quadruples Oliphant, Nevin; Adamowicz, Ludwik The Journal of Chemical Physics, Vol. 95, Issue 9 https://doi.org/10.1063/1.461534	journal	November 1991
The coupled‐cluster single, double, triple, and quadruple excitation method Kucharski, Stanislaw A.; Bartlett, Rodney J. The Journal of Chemical Physics, Vol. 97, Issue 6 https://doi.org/10.1063/1.463930	journal	September 1992
Density‐functional thermochemistry. III. The role of exact exchange Becke, Axel D. The Journal of Chemical Physics, Vol. 98, Issue 7, p. 5648-5652 https://doi.org/10.1063/1.464913	journal	April 1993
The heat of formation of NCO East, Allan L. L.; Allen, Wesley D. The Journal of Chemical Physics, Vol. 99, Issue 6 https://doi.org/10.1063/1.466062	journal	September 1993
Basis-set convergence of correlated calculations on water Helgaker, Trygve; Klopper, Wim; Koch, Henrik The Journal of Chemical Physics, Vol. 106, Issue 23 https://doi.org/10.1063/1.473863	journal	June 1997
Dynamics of the reactions of O( ¹ D) with CD ₃ OH and CH ₃ OD studied with time-resolved Fourier-transform IR spectroscopy Huang, Chong-Kai; Xu, Zhen-Feng; Nakajima, Masakazu The Journal of Chemical Physics, Vol. 137, Issue 16 https://doi.org/10.1063/1.4759619	journal	October 2012
In pursuit of the ab initio limit for conformational energy prototypes Császár, Attila G.; Allen, Wesley D.; Schaefer, Henry F. The Journal of Chemical Physics, Vol. 108, Issue 23 https://doi.org/10.1063/1.476449	journal	June 1998
Combined crossed beam and theoretical studies of the C( ¹ D) + CH ₄ reaction Leonori, Francesca; Skouteris, Dimitrios; Petrucci, Raffaele The Journal of Chemical Physics, Vol. 138, Issue 2 https://doi.org/10.1063/1.4773579	journal	January 2013
A search for the lowest-energy conformer of interstellar glycine Hollis, J. M.; Snyder, L. E.; Suenram, R. D. The Astrophysical Journal, Vol. 241 https://doi.org/10.1086/158413	journal	November 1980
Detection of Interstellar Methylamine Kaifu, N.; Morimoto, M.; Nagane, K. The Astrophysical Journal, Vol. 191 https://doi.org/10.1086/181569	journal	July 1974
Detection of Interstellar Methylamine by its 2_{02}->1_{10} A_{a^{-}} State Transition Fourikis, N.; Takagi, K.; Morimoto, M. The Astrophysical Journal, Vol. 191 https://doi.org/10.1086/181570	journal	July 1974
Excitation of interstellar methylamine Kaifu, N.; Takagi, K.; Kojima, T. The Astrophysical Journal, Vol. 198 https://doi.org/10.1086/181818	journal	June 1975
The Photostability of Amino Acids in Space Ehrenfreund, P.; Bernstein, M. P.; Dworkin, J. P. The Astrophysical Journal, Vol. 550, Issue 1 https://doi.org/10.1086/319491	journal	March 2001
Kinematics of the Sagittarius B2(N-LMH) Molecular Core Hollis, J. M.; Pedelty, J. A.; Boboltz, D. A. The Astrophysical Journal, Vol. 596, Issue 2 https://doi.org/10.1086/379315	journal	September 2003
The Gas‐Phase Formation of Methyl Formate in Hot Molecular Cores Horn, Anne; Mollendal, Harald; Sekiguchi, Osamu The Astrophysical Journal, Vol. 611, Issue 1 https://doi.org/10.1086/422137	journal	August 2004
A Rigorous Attempt to Verify Interstellar Glycine Snyder, L. E.; Lovas, F. J.; Hollis, J. M. The Astrophysical Journal, Vol. 619, Issue 2 https://doi.org/10.1086/426677	journal	February 2005
A Combined Experimental and Theoretical Study on the Formation of the Amino Acid Glycine (NH ₂ CH ₂ COOH) and Its Isomer (CH ₃ NHCOOH) in Extraterrestrial Ices Holtom, Philip D.; Bennett, Chris J.; Osamura, Yoshihiro The Astrophysical Journal, Vol. 626, Issue 2 https://doi.org/10.1086/430106	journal	June 2005
Complex Chemistry in Star‐forming Regions: An Expanded Gas‐Grain Warm‐up Chemical Model Garrod, Robin T.; Weaver, Susanna L. Widicus; Herbst, Eric The Astrophysical Journal, Vol. 682, Issue 1 https://doi.org/10.1086/588035	journal	July 2008
A SEARCH FOR HYDROXYLAMINE (NH ₂ OH) TOWARD SELECT ASTRONOMICAL SOURCES Pulliam, Robin L.; McGuire, Brett A.; Remijan, Anthony J. The Astrophysical Journal, Vol. 751, Issue 1 https://doi.org/10.1088/0004-637X/751/1/1	journal	April 2012
A Three-Phase Chemical Model of hot Cores: the Formation of Glycine Garrod, Robin T. The Astrophysical Journal, Vol. 765, Issue 1 https://doi.org/10.1088/0004-637X/765/1/60	journal	February 2013
INSIGHTS INTO SURFACE HYDROGENATION IN THE INTERSTELLAR MEDIUM: OBSERVATIONS OF METHANIMINE AND METHYL AMINE IN Sgr B2(N) Halfen, D. T.; Ilyushin, V. V.; Ziurys, L. M. The Astrophysical Journal, Vol. 767, Issue 1 https://doi.org/10.1088/0004-637X/767/1/66	journal	March 2013
A search for interstellar glycine Brown, R. D.; Godfrey, P. D.; Storey, J. W. V. Monthly Notices of the Royal Astronomical Society, Vol. 186, Issue 1 https://doi.org/10.1093/mnras/186.1.5P	journal	January 1979
The molecular universe Tielens, A. G. G. M. Reviews of Modern Physics, Vol. 85, Issue 3 https://doi.org/10.1103/RevModPhys.85.1021	journal	July 2013
A Search for biomolecules in Sagittarius B2 (LMH) with the Australia Telescope Compact Array Jones, P. A.; Cunningham, M. R.; Godfrey, P. D. Monthly Notices of the Royal Astronomical Society, Vol. 374, Issue 2 https://doi.org/10.1111/j.1365-2966.2006.11175.x	journal	January 2007
A search for propylene oxide and glycine in Sagittarius B2 (LMH) and Orion Cunningham, M. R.; Jones, P. A.; Godfrey, P. D. Monthly Notices of the Royal Astronomical Society, Vol. 376, Issue 3 https://doi.org/10.1111/j.1365-2966.2007.11504.x	journal	April 2007
Ribose and related sugars from ultraviolet irradiation of interstellar ice analogs Meinert, C.; Myrgorodska, I.; de Marcellus, P. Science, Vol. 352, Issue 6282 https://doi.org/10.1126/science.aad8137	journal	April 2016
Discovery of the interstellar chiral molecule propylene oxide (CH3CHCH2O) McGuire, B. A.; Carroll, P. B.; Loomis, R. A. Science, Vol. 352, Issue 6292 https://doi.org/10.1126/science.aae0328	journal	June 2016
Chemical Simulations of Prebiotic Molecules: Interstellar Ethanimine Isomers Quan, Donghui; Herbst, Eric; Corby, Joanna F. The Astrophysical Journal, Vol. 824, Issue 2 https://doi.org/10.3847/0004-637X/824/2/129	journal	June 2016
Methanol Formation via Oxygen Insertion Chemistry in Ices Bergner, Jennifer B.; Öberg, Karin I.; Rajappan, Mahesh The Astrophysical Journal, Vol. 845, Issue 1 https://doi.org/10.3847/1538-4357/aa7d09	journal	August 2017
Rotational and Infrared Spectroscopy of Ethanimine: A Route toward Its Astrophysical and Planetary Detection Melli, Alessio; Melosso, Mattia; Tasinato, Nicola The Astrophysical Journal, Vol. 855, Issue 2 https://doi.org/10.3847/1538-4357/aaa899	journal	March 2018
A Search for Hydroxylamine (NH2OH) toward Select Astronomical Sources Pulliam, Robin L.; McGuire, Brett A.; Remijan, Anthony J. arXiv https://doi.org/10.48550/arxiv.1202.1200	text	January 2012
A three-phase chemical model of hot cores: the formation of glycine Garrod, Robin T. arXiv https://doi.org/10.48550/arxiv.1302.0688	text	January 2013
Discovery of the Interstellar Chiral Molecule Propylene Oxide (CH$_3$CHCH$_2$O) McGuire, Brett A.; Carroll, P. Brandon; Loomis, Ryan A. arXiv https://doi.org/10.48550/arxiv.1606.07483	text	January 2016
Methanol formation via oxygen insertion chemistry in ice Bergner, Jennifer B.; Oberg, Karin I.; Rajappan, Mahesh arXiv https://doi.org/10.48550/arxiv.1707.01120	text	January 2017
A Search for Propylene Oxide and Glycine in Sagittarius B2 (LMH) and Orion Cunningham, M. R.; Jones, P. A.; Godfrey, P. D. arXiv https://doi.org/10.48550/arxiv.astro-ph/0701866	text	January 2007

Similar Records

The atmospheric importance of methylamine additions to Criegee intermediates

Journal Article · Wed Sep 23 20:00:00 EDT 2020 · Physical Chemistry Chemical Physics. PCCP · OSTI ID:1852657

Exploring the Tl 2H 2 potential energy surface: A comparative analysis with group 13 systems and experiment

Journal Article · Tue Jan 09 23:00:00 EST 2024 · Journal of Computational Chemistry · OSTI ID:2575901

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Chemistry
Physics

Important features of the potential energy surface of the methylamine plus O(1D) reaction

Citation Formats

References (88)

Similar Records

Related Subjects

Important features of the potential energy surface of the methylamine plus O(¹D) reaction