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Mechanistic Study of Diaryl Ether Bond Cleavage during Palladium-Catalyzed Lignin Hydrogenolysis

Journal Article · · ChemSusChem
 [1];  [2];  [3];  [2];  [4];  [3];  [5];  [6]
  1. Department of Biological Systems Engineering University of Wisconsin-Madison Madison WI 53706 USA; DOE Great Lakes Bioenergy Research Center Madison WI 53726 USA; Department of Chemical Engineering Massachusetts Institute of Technology Cambridge MA 02142 USA; OSTI
  2. DOE Great Lakes Bioenergy Research Center Madison WI 53726 USA; Department of Biochemistry University of Wisconsin-Madison Madison WI 53706 USA
  3. DOE Great Lakes Bioenergy Research Center Madison WI 53726 USA; Department of Chemical and Biological Engineering University of Wisconsin-Madison Madison WI 53706 USA
  4. Institute of Chemical Sciences and Engineering École Polytechnique Fédérale de Lausanne Route Cantonale 1015 Lausanne Switzerland
  5. DOE Great Lakes Bioenergy Research Center Madison WI 53726 USA; Department of Chemistry University of Wisconsin-Madison Madison WI 53706 USA
  6. Department of Biological Systems Engineering University of Wisconsin-Madison Madison WI 53706 USA; DOE Great Lakes Bioenergy Research Center Madison WI 53726 USA; Department of Biochemistry University of Wisconsin-Madison Madison WI 53706 USA

Not provided.

Research Organization:
Univ. of Wisconsin, Madison, WI (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0018409
OSTI ID:
1803391
Journal Information:
ChemSusChem, Journal Name: ChemSusChem Journal Issue: 17 Vol. 13; ISSN 1864-5631
Publisher:
ChemPubSoc Europe
Country of Publication:
United States
Language:
English

References (43)

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Lignin Biosynthesis journal June 2003
Ni-Catalyzed Cleavage of Aryl Ethers in the Aqueous Phase journal December 2012
Formic-acid-induced depolymerization of oxidized lignin to aromatics journal November 2014
Reductive fractionation of woody biomass into lignin monomers and cellulose by tandem metal triflate and Pd/C catalysis journal January 2017
Ru-Catalyzed Hydrogenolysis of Lignin: Base-Dependent Tunability of Monomeric Phenols and Mechanistic Study journal March 2019
Catalytic lignocellulose biorefining in n -butanol/water: a one-pot approach toward phenolics, polyols, and cellulose journal January 2018
β-O-4 Bond Cleavage Mechanism for Lignin Model Compounds over Pd Catalysts Identified by Combination of First-Principles Calculations and Experiments journal July 2016
NMR Assignment for Diaryl Ether Structures (4–O–5 Structures) in Pine Wood Lignin journal April 2016
Bright Side of Lignin Depolymerization: Toward New Platform Chemicals journal January 2018
Formal Cross-Coupling of Diaryl Ethers with Ammonia by Dual C(Ar)–O Bond Cleavages journal August 2018
Protection Group Effects During α,γ-Diol Lignin Stabilization Promote High-Selectivity Monomer Production journal January 2018
Tuning the lignin oil OH-content with Ru and Pd catalysts during lignin hydrogenolysis on birch wood journal January 2015
Lignin depolymerization (LDP) in alcohol over nickel-based catalysts via a fragmentation–hydrogenolysis process journal January 2013
Catalytic hydrodeoxygenation journal June 2000
Dissociative hydrogen adsorption on palladium requires aggregates of three or more vacancies journal April 2003
Mechanistic investigation of the Zn/Pd/C catalyzed cleavage and hydrodeoxygenation of lignin journal January 2016
Synthesis of Guaiacylglycerol-β-guaiacyl Ether journal January 1975
Palladium-Catalyzed Formal Cross-Coupling of Diaryl Ethers with Amines: Slicing the 4- O -5 Linkage in Lignin Models journal March 2018
Lignin structure and its engineering journal April 2019
Selective Route to 2-Propenyl Aryls Directly from Wood by a Tandem Organosolv and Palladium-Catalysed Transfer Hydrogenolysis journal June 2014
Flowthrough Reductive Catalytic Fractionation of Biomass journal November 2017
Palladium-Catalyzed Reductive Insertion of Alcohols into Aryl Ether Bonds journal March 2018
Palladium-Catalyzed Reductive Insertion of Alcohols into Aryl Ether Bonds journal March 2018
Palladium-Catalyzed Formal Cross-Coupling of Diaryl Ethers with Amines: Slicing the 4- O -5 Linkage in Lignin Models journal March 2018
An “ideal lignin” facilitates full biomass utilization journal September 2018
Wege zur Verwertung von Lignin: Fortschritte in der Biotechnik, der Bioraffination und der Katalyse journal June 2016
Lignin-Derived Thioacidolysis Dimers: Reevaluation, New Products, Authentication, and Quantification journal February 2017
Reductive catalytic fractionation: state of the art of the lignin-first biorefinery journal April 2019
Reductive lignocellulose fractionation into soluble lignin-derived phenolic monomers and dimers and processable carbohydrate pulps journal January 2015
Identification of 4–O–5-Units in Softwood Lignins via Definitive Lignin Models and NMR journal May 2016
Kinetic and mechanistic insights into hydrogenolysis of lignin to monomers in a continuous flow reactor journal January 2019
Kinetic Studies of Lignin Solvolysis and Reduction by Reductive Catalytic Fractionation Decoupled in Flow-Through Reactors journal April 2018
Protection Group Effects During α,γ-Diol Lignin Stabilization Promote High-Selectivity Monomer Production journal January 2018
Weitere Oxydationsprodukte des Fichtenlignins journal November 1967
Palladium-Catalyzed Hydrolytic Cleavage of Aromatic C−O Bonds journal January 2017

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