Complementing Nanoscale Galvanic Exchange with Redox Manipulation toward Architectural Control of Multimetallic Hollow Nanostructures

Li, Guangfang Grace; Wang, Zixin; Wang, Hui

doi:10.1002/cnma.202000139

Complementing Nanoscale Galvanic Exchange with Redox Manipulation toward Architectural Control of Multimetallic Hollow Nanostructures

Journal Article · Fri Mar 27 00:00:00 EDT 2020 · ChemNanoMat

DOI:https://doi.org/10.1002/cnma.202000139· OSTI ID:1803053

Li, Guangfang Grace ^[1]; Wang, Zixin ^[2]; ^[2]

Univ. of South Carolina, Columbia, SC (United States); OSTI
Univ. of South Carolina, Columbia, SC (United States)

Galvanic exchange occurring within the confinement by nanoparticulate templates provides a unique pathway to controllably transform solid metallic nanoparticles into architecturally more sophisticated multimetallic hollow nanostructures under facile reaction conditions. As such, in this Minireview, we elaborately discuss how the nanoparticle-templated galvanic exchange can be deliberately coupled with redox manipulation to synthesize a large library of complex multimetallic hollow nanostructures exhibiting precisely tailored architectures and compositions, with a particular emphasis on important mechanistic insights concerning the dynamic interplay among multiple structure-remodeling processes that synergistically dictate the versatile nanoparticle transforming behaviors during kinetically and regioselectively modulated galvanic exchange reactions.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of South Carolina, Columbia, SC (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE Office of Science (SC)

Grant/Contract Number:: SC0016574

OSTI ID:: 1803053

Alternate ID(s):: OSTI ID: 1632774

Journal Information:: ChemNanoMat, Journal Name: ChemNanoMat Journal Issue: 7 Vol. 6; ISSN 2199-692X

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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