A metastable Ru III azido complex with metallo-Staudinger reactivity

Park, Sungho V.; Fry, Charles G.; Bill, Eckhard; Berry, John F.

doi:10.1039/d0cc04426a

A metastable Ru ^III azido complex with metallo-Staudinger reactivity

Journal Article · Tue Dec 31 23:00:00 EST 2019 · ChemComm

DOI:https://doi.org/10.1039/d0cc04426a· OSTI ID:1802992

^[1]; Fry, Charles G. ^[2]; Bill, Eckhard ^[3]; ^[2]

Department of Chemistry; University of Wisconsin – Madison; Madison; USA; OSTI
Department of Chemistry; University of Wisconsin – Madison; Madison; USA
Max-Planck-Institut für Chemische Energiekonversion; D-45470 Mülheim an der Ruhr; Germany

One-electron oxidation of [(Py₅Me₂)Ru^II(N₃)]⁺to [(Py₅Me₂)Ru^III(N₃)]²⁺switches on metallo-Staudinger reactivity towards PPh₃, forming [(Py₅Me₂)Ru^II(N(H)PPh₃)]²⁺through a putative [Ru–N=N=N–PPh₃] intermediate.

Research Organization:: Univ. of Wisconsin, Madison, WI (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0016442

OSTI ID:: 1802992

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 73 Vol. 56; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

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