Cyclohexene epoxidation with H2O2 in the vapor and liquid phases over a vanadium-based metal–organic framework

Yoon, Tae-Ung; Ahn, Sol; Kim, Ah-Reum; Notestein, Justin M.; Farha, Omar K.; Bae, Youn-Sang

doi:10.1039/d0cy00833h

Cyclohexene epoxidation with H₂O₂ in the vapor and liquid phases over a vanadium-based metal–organic framework

Journal Article · Wed Jun 17 00:00:00 EDT 2020 · Catalysis Science and Technology

DOI:https://doi.org/10.1039/d0cy00833h· OSTI ID:1802469

Yoon, Tae-Ung ^[1]; Ahn, Sol ^[2]; Kim, Ah-Reum ^[3]; ^[2]; ^[2]; ^[3]

Yonsei Univ., Seoul (Korea, Republic of); OSTI
Northwestern Univ., Evanston, IL (United States)
Yonsei Univ., Seoul (Korea, Republic of)

A metal–organic framework, MIL-47(V) containing coordinatively saturated V^+IV sites linked together by terephthalic linkers, was prepared by a solvothermal method and evaluated as a catalyst in the epoxidation of cyclohexene. We have compared the catalytic activity in the condensed and gas phase oxidation of cyclohexene to discuss the effect of temperature and reaction phase in cyclohexene epoxidation over MIL-47(V). The catalysts were examined for the epoxidation of cyclohexene with H₂O₂ at 50, 65, 120, and 150 °C. Finally, we observed significant differences in product selectivity between liquid-phase and gas-phase operations and confirmed that the active sites are tightly incorporated into the MOF as node channels and thus resistant to leaching.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Minnesota, Minneapolis, MN (United States)

Sponsoring Organization:: National Research Foundation of Korea; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012702

OSTI ID:: 1802469

Alternate ID(s):: OSTI ID: 1634870

Journal Information:: Catalysis Science and Technology, Journal Name: Catalysis Science and Technology Journal Issue: 14 Vol. 10; ISSN 2044-4753

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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