Even-Parity Self-Trapped Excitons Lead to Magnetic Dipole Radiation in Two-Dimensional Lead Halide Perovskites

DeCrescent, Ryan A.; Du, Xinhong; Kennard, Rhys M.; Venkatesan, Naveen R.; Dahlman, Clayton J.; Chabinyc, Michael L.; Schuller, Jon A.

doi:10.1021/acsnano.0c03783

Title: Even-Parity Self-Trapped Excitons Lead to Magnetic Dipole Radiation in Two-Dimensional Lead Halide Perovskites

Journal Article · Wed Jul 15 00:00:00 EDT 2020 · ACS Nano

DOI:https://doi.org/10.1021/acsnano.0c03783· OSTI ID:1802380

^[1]; Du, Xinhong ^[2]; Kennard, Rhys M. ^[3];

^[3];

^[2]

Department of Physics, University of California Santa Barbara, Santa Barbara, California 93106, United States
Department of Electrical and Computer Engineering, University of California Santa Barbara, Santa Barbara, California 93106, United States
Department of Materials, University of California Santa Barbara, Santa Barbara, California 93106, United States

Not provided.

Cite

Export

Save

Research Organization:: Univ. of California, Santa Barbara, CA (United States); Univ. of California, San Diego, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0012541; SC0019273

OSTI ID:: 1802380

Journal Information:: ACS Nano, Vol. 14, Issue 7; ISSN 1936-0851

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (56)

Hybrid Organic-Inorganic Perovskites (HOIPs): Opportunities and Challenges Berry, Joseph; Buonassisi, Tonio; Egger, David A. Advanced Materials, Vol. 27, Issue 35 https://doi.org/10.1002/adma.201502294	journal	July 2015
Metal halide perovskites for energy applications Zhang, Wei; Eperon, Giles E.; Snaith, Henry J. Nature Energy, Vol. 1, Issue 6 https://doi.org/10.1038/nenergy.2016.48	journal	May 2016
Optical properties due to electronic transitions in two-dimensional semiconductors ( $C_{n}$ $H_{2 n + 1}$ ${NH}_{3}$ $)_{2}$ ${PbI}_{4}$ Ishihara, Teruya; Takahashi, Jun; Goto, Takenari Physical Review B, Vol. 42, Issue 17 https://doi.org/10.1103/PhysRevB.42.11099	journal	December 1990
Synthesis, Crystal Structure, and Optical and Thermal Properties of (C₄H₉NH₃)₂MI₄ (M = Ge, Sn, Pb) Mitzi, David B. Chemistry of Materials, Vol. 8, Issue 3, p. 791-800 https://doi.org/10.1021/cm9505097	journal	January 1996
Electronic and Excitonic Structures of Inorganic–Organic Perovskite-Type Quantum-Well Crystal (C ₄ H ₉ NH ₃ ) ₂ PbBr ₄ Tanaka, Kenichiro; Takahashi, Takayuki; Kondo, Takashi Japanese Journal of Applied Physics, Vol. 44, Issue 8 https://doi.org/10.1143/JJAP.44.5923	journal	August 2005
A Layered Hybrid Perovskite Solar-Cell Absorber with Enhanced Moisture Stability Smith, Ian C.; Hoke, Eric T.; Solis-Ibarra, Diego Angewandte Chemie, Vol. 126, Issue 42 https://doi.org/10.1002/ange.201406466	journal	September 2014
High-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells Tsai, Hsinhan; Nie, Wanyi; Blancon, Jean-Christophe Nature, Vol. 536, Issue 7616 https://doi.org/10.1038/nature18306	journal	July 2016
Quantum and Dielectric Confinement Effects in Lower-Dimensional Hybrid Perovskite Semiconductors Katan, Claudine; Mercier, Nicolas; Even, Jacky Chemical Reviews, Vol. 119, Issue 5 https://doi.org/10.1021/acs.chemrev.8b00417	journal	January 2019
Image charge effect on two-dimensional excitons in an inorganic-organic quantum-well crystal Tanaka, Kenichiro; Takahashi, Takayuki; Kondo, Takashi Physical Review B, Vol. 71, Issue 4 https://doi.org/10.1103/PhysRevB.71.045312	journal	January 2005
Strong exciton–photon coupling at room temperature in microcavities containing two-dimensional layered perovskite compounds Lanty, G.; Bréhier, A.; Parashkov, R. New Journal of Physics, Vol. 10, Issue 6 https://doi.org/10.1088/1367-2630/10/6/065007	journal	June 2008
The influence of the Rashba effect Stranks, Samuel D.; Plochocka, Paulina Nature Materials, Vol. 17, Issue 5 https://doi.org/10.1038/s41563-018-0067-8	journal	April 2018
Two-dimensional hybrid perovskites sustaining strong polariton interactions at room temperature Fieramosca, A.; Polimeno, L.; Ardizzone, V. Science Advances, Vol. 5, Issue 5 https://doi.org/10.1126/sciadv.aav9967	journal	May 2019
Bright magnetic dipole radiation from two-dimensional lead-halide perovskites DeCrescent, Ryan A.; Venkatesan, Naveen R.; Dahlman, Clayton J. Science Advances, Vol. 6, Issue 6 https://doi.org/10.1126/sciadv.aay4900	journal	February 2020
Properties and potential optoelectronic applications of lead halide perovskite nanocrystals Kovalenko, Maksym V.; Protesescu, Loredana; Bodnarchuk, Maryna I. Science, Vol. 358, Issue 6364 https://doi.org/10.1126/science.aam7093	journal	November 2017
Exciton Polarons in Two-Dimensional Hybrid Metal-Halide Perovskites Srimath Kandada, Ajay Ram; Silva, Carlos The Journal of Physical Chemistry Letters, Vol. 11, Issue 9 https://doi.org/10.1021/acs.jpclett.9b02342	journal	March 2020
White-Light Emission from Layered Halide Perovskites Smith, Matthew D.; Karunadasa, Hemamala I. Accounts of Chemical Research, Vol. 51, Issue 3 https://doi.org/10.1021/acs.accounts.7b00433	journal	February 2018
Synthesis of Polycrystalline Ruddlesden–Popper Organic Lead Halides and Their Growth Dynamics Moral, Raphael F.; Bonato, Luiz Gustavo; Germino, José Carlos Chemistry of Materials, Vol. 31, Issue 22 https://doi.org/10.1021/acs.chemmater.9b03439	journal	October 2019
Layered Lead Iodide of [Methylhydrazinium] ₂ PbI ₄ with a Reduced Band Gap: Thermochromic Luminescence and Switchable Dielectric Properties Triggered by Structural Phase Transitions Mączka, Mirosław; Ptak, Maciej; Gągor, Anna Chemistry of Materials, Vol. 31, Issue 20 https://doi.org/10.1021/acs.chemmater.9b03775	journal	September 2019
Exciton Self-Trapping in Hybrid Lead Halides: Role of Halogen Gautier, Romain; Paris, Michael; Massuyeau, Florian Journal of the American Chemical Society, Vol. 141, Issue 32 https://doi.org/10.1021/jacs.9b04262	journal	July 2019
Mechanism for Broadband White-Light Emission from Two-Dimensional (110) Hybrid Perovskites Hu, Te; Smith, Matthew D.; Dohner, Emma R. The Journal of Physical Chemistry Letters, Vol. 7, Issue 12 https://doi.org/10.1021/acs.jpclett.6b00793	journal	May 2016
Optical spectroscopy of two-dimensional layered (C_6H_5C_2H_4-NH_3)_2-PbI_4 perovskite Gauthron, K.; Lauret, J-S.; Doyennette, L. Optics Express, Vol. 18, Issue 6 https://doi.org/10.1364/OE.18.005912	journal	January 2010
Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors Stoumpos, Constantinos C.; Cao, Duyen H.; Clark, Daniel J. Chemistry of Materials, Vol. 28, Issue 8, p. 2852-2867 https://doi.org/10.1021/acs.chemmater.6b00847	journal	April 2016
Hyperbolic Dispersion Arising from Anisotropic Excitons in Two-Dimensional Perovskites Guo, Peijun; Huang, Wei; Stoumpos, Constantinos C. Physical Review Letters, Vol. 121, Issue 12 https://doi.org/10.1103/PhysRevLett.121.127401	journal	September 2018
Temperature-Dependent Band Gap in Two-Dimensional Perovskites: Thermal Expansion Interaction and Electron–Phonon Interaction Wang, Shuai; Ma, Jiaqi; Li, Wancai The Journal of Physical Chemistry Letters, Vol. 10, Issue 10 https://doi.org/10.1021/acs.jpclett.9b01011	journal	April 2019
Electronic model for self-assembled hybrid organic/perovskite semiconductors: Reverse band edge electronic states ordering and spin-orbit coupling Even, J.; Pedesseau, L.; Dupertuis, M. -A. Physical Review B, Vol. 86, Issue 20 https://doi.org/10.1103/PhysRevB.86.205301	journal	November 2012
Model for Self-Trapping of Excitons with Internal Degrees of Freedom Noba, Ken-ichi; Kayanuma, Yosuke Journal of the Physical Society of Japan, Vol. 67, Issue 10 https://doi.org/10.1143/JPSJ.67.3388	journal	October 1998
In-Plane Propagation of Light in Transition Metal Dichalcogenide Monolayers: Optical Selection Rules Wang, G.; Robert, C.; Glazov, M. M. Physical Review Letters, Vol. 119, Issue 4 https://doi.org/10.1103/PhysRevLett.119.047401	journal	July 2017
Local Polar Fluctuations in Lead Halide Perovskite Crystals Yaffe, Omer; Guo, Yinsheng; Tan, Liang Z. Physical Review Letters, Vol. 118, Issue 13 https://doi.org/10.1103/PhysRevLett.118.136001	journal	March 2017
Dynamic symmetry breaking and spin splitting in metal halide perovskites McKechnie, Scott; Frost, Jarvist M.; Pashov, Dimitar Physical Review B, Vol. 98, Issue 8 https://doi.org/10.1103/PhysRevB.98.085108	journal	August 2018
Structural fluctuations cause spin-split states in tetragonal (CH ₃ NH ₃ )PbI ₃ as evidenced by the circular photogalvanic effect Niesner, Daniel; Hauck, Martin; Shrestha, Shreetu Proceedings of the National Academy of Sciences, Vol. 115, Issue 38 https://doi.org/10.1073/pnas.1805422115	journal	September 2018
Octahedral tilting instabilities in inorganic halide perovskites Bechtel, Jonathon S.; Van der Ven, Anton Physical Review Materials, Vol. 2, Issue 2 https://doi.org/10.1103/PhysRevMaterials.2.025401	journal	February 2018
Control of Crystal Symmetry Breaking with Halogen-Substituted Benzylammonium in Layered Hybrid Metal-Halide Perovskites Schmitt, Tanja; Bourelle, Sean; Tye, Nathaniel Journal of the American Chemical Society, Vol. 142, Issue 11 https://doi.org/10.1021/jacs.9b11809	journal	February 2020
Scaling law for excitons in 2D perovskite quantum wells Blancon, J. -C.; Stier, A. V.; Tsai, H. Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04659-x	journal	June 2018
Excitonic Instabilities of Deformable Lattice - from Self-Trapping to Phase Transition Toyozawa, Y. Acta Physica Polonica A, Vol. 87, Issue 1 https://doi.org/10.12693/APhysPolA.87.47	journal	January 1995
Polaron self-localization in white-light emitting hybrid perovskites Cortecchia, Daniele; Yin, Jun; Bruno, Annalisa Journal of Materials Chemistry C, Vol. 5, Issue 11 https://doi.org/10.1039/C7TC00366H	journal	January 2017
The role of self-trapped excitons in polaronic recombination processes in lithium niobate Messerschmidt, S.; Krampf, A.; Freytag, F. Journal of Physics: Condensed Matter, Vol. 31, Issue 6 https://doi.org/10.1088/1361-648X/aaf4df	journal	December 2018
Atomistic Mechanism of Broadband Emission in Metal Halide Perovskites Wang, Xiaoming; Meng, Weiwei; Liao, Weiqiang The Journal of Physical Chemistry Letters, Vol. 10, Issue 3 https://doi.org/10.1021/acs.jpclett.8b03717	journal	January 2019
Luminescence of Free and Self-Trapped Excitons in α- and β-Perylene Crystals Nishimura, Hitoshi; Yamaoka, Tohru; Mizuno, Ken-ichi Journal of the Physical Society of Japan, Vol. 53, Issue 11 https://doi.org/10.1143/JPSJ.53.3999	journal	November 1984
Off-center self-trapped excitons and creation of lattice defects in alkali halide crystals Williams, R. T.; Song, K. S.; Faust, W. L. Physical Review B, Vol. 33, Issue 10 https://doi.org/10.1103/PhysRevB.33.7232	journal	May 1986
Selective non-radiative transitions at excited states of the self-trapped exciton in alkali halides Tanimura, Katsumi; Itoh, Noriaki Journal of Physics and Chemistry of Solids, Vol. 45, Issue 3 https://doi.org/10.1016/0022-3697(84)90038-6	journal	January 1984
Structural origins of broadband emission from layered Pb–Br hybrid perovskites Smith, Matthew D.; Jaffe, Adam; Dohner, Emma R. Chemical Science, Vol. 8, Issue 6 https://doi.org/10.1039/C7SC01590A	journal	January 2017
Dynamical Aspects of Self-Trapping of 1 s Excitons in RbI and KI Unuma, Yutaka; Masumoto, Yasuaki; Shionoya, Shigeo Journal of the Physical Society of Japan, Vol. 52, Issue 12 https://doi.org/10.1143/JPSJ.52.4277	journal	December 1983
Fast growth of monocrystalline thin films of 2D layered hybrid perovskite Lédée, Ferdinand; Trippé-Allard, Gaëlle; Diab, Hiba CrystEngComm, Vol. 19, Issue 19 https://doi.org/10.1039/C7CE00240H	journal	January 2017
Synthesis, characterization and phase transitions in the inorganic–organic layered perovskite-type hybrids [(C _n H _{2 n + 1} NH ₃ ) ₂ PbI ₄ ], n = 4, 5 and 6 Billing, David G.; Lemmerer, Andreas Acta Crystallographica Section B Structural Science, Vol. 63, Issue 5 https://doi.org/10.1107/S0108768107031758	journal	September 2007
Temperature-dependent exciton linewidths in semiconductors Rudin, S.; Reinecke, T. L.; Segall, B. Physical Review B, Vol. 42, Issue 17 https://doi.org/10.1103/PhysRevB.42.11218	journal	December 1990
Electron–phonon coupling in hybrid lead halide perovskites Wright, Adam D.; Verdi, Carla; Milot, Rebecca L. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11755	journal	May 2016
Temperature-dependent time-resolved photoluminescence of (C6H5C2H4NH3)2PbX4 (X=Br and I) Kitazawa, Nobuaki; Aono, Masami; Watanabe, Yoshihisa Materials Chemistry and Physics, Vol. 134, Issue 2-3 https://doi.org/10.1016/j.matchemphys.2012.03.083	journal	June 2012
Elastic constants of LiCl and RbCl from 300°K to 4.2°K Marshall, B. J.; Pederson, D. O.; Dorris, G. G. Journal of Physics and Chemistry of Solids, Vol. 28, Issue 6 https://doi.org/10.1016/0022-3697(67)90223-5	journal	June 1967
Temperature Dependence of Mechanical Properties in Molecular Crystals Mohamed, Reda M.; Mishra, Manish Kumar; AL-Harbi, Laila M. Crystal Growth & Design, Vol. 15, Issue 5 https://doi.org/10.1021/acs.cgd.5b00245	journal	March 2015
Manipulating efficient light emission in two-dimensional perovskite crystals by pressure-induced anisotropic deformation Liu, Sheng; Sun, Shishuai; Gan, Chee Kwan Science Advances, Vol. 5, Issue 7 https://doi.org/10.1126/sciadv.aav9445	journal	July 2019
Femtosecond Dynamics of the Exciton Self-Trapping Process in a Quasi-One-Dimensional Halogen-Bridged Platinum Complex Tomimoto, S.; Nansei, H.; Saito, S. Physical Review Letters, Vol. 81, Issue 2 https://doi.org/10.1103/PhysRevLett.81.417	journal	July 1998
Integrated all-photonic non-volatile multi-level memory Ríos, Carlos; Stegmaier, Matthias; Hosseini, Peiman Nature Photonics, Vol. 9, Issue 11 https://doi.org/10.1038/nphoton.2015.182	journal	September 2015
Extremely Low Operating Current Resistive Memory Based on Exfoliated 2D Perovskite Single Crystals for Neuromorphic Computing Tian, He; Zhao, Lianfeng; Wang, Xuefeng ACS Nano, Vol. 11, Issue 12 https://doi.org/10.1021/acsnano.7b05726	journal	October 2016
Large polarons in lead halide perovskites Miyata, Kiyoshi; Meggiolaro, Daniele; Trinh, M. Tuan Science Advances, Vol. 3, Issue 8 https://doi.org/10.1126/sciadv.1701217	journal	August 2017
Excitonic Properties of Chemically Synthesized 2D Organic-Inorganic Hybrid Perovskite Nanosheets Zhang, Qi; Chu, Leiqiang; Zhou, Feng Advanced Materials, Vol. 30, Issue 18 https://doi.org/10.1002/adma.201704055	journal	March 2018
Exciton-polaron spectral structures in two-dimensional hybrid lead-halide perovskites Neutzner, Stefanie; Thouin, Félix; Cortecchia, Daniele Physical Review Materials, Vol. 2, Issue 6 https://doi.org/10.1103/PhysRevMaterials.2.064605	journal	June 2018

Similar Records

Bright magnetic dipole radiation from two-dimensional lead-halide perovskites

Journal Article · Fri Feb 07 00:00:00 EST 2020 · Science Advances · OSTI ID:1802380

DeCrescent, Ryan A.; Venkatesan, Naveen R.; Dahlman, Clayton J.; +7 more

Screening of Excitons by Organic Cations in Quasi-Two-Dimensional Organic–Inorganic Lead-Halide Perovskites

Journal Article · Thu Jun 09 00:00:00 EDT 2022 · Nano Letters · OSTI ID:1802380

Filip, Marina R.; Qiu, Diana Y.; Del Ben, Mauro; +1 more

Phase Stability and Diffusion in Lateral Heterostructures of Methyl Ammonium Lead Halide Perovskites

Journal Article · Wed Jul 03 00:00:00 EDT 2019 · ACS Applied Materials and Interfaces · OSTI ID:1802380

Kennard, Rhys M.; Dahlman, Clayton J.; Nakayama, Hidenori; +5 more

Related Subjects

Chemistry
Science & Technology - Other Topics
Materials Science

Title: Even-Parity Self-Trapped Excitons Lead to Magnetic Dipole Radiation in Two-Dimensional Lead Halide Perovskites

Citation Formats

References (56)

Similar Records

Related Subjects