Overcoming geometric limitations in metallic glasses through stretch blow molding

Ojeda Mota, Rodrigo Miguel; Liu, Naijia; Kube, Sebastian Alexander; Chay, John; McClintock, Hayley D.; Schroers, Jan

doi:10.1016/j.apmt.2020.100567

Title: Overcoming geometric limitations in metallic glasses through stretch blow molding

Journal Article · Sat Jan 25 00:00:00 EST 2020 · Applied Materials Today

DOI:https://doi.org/10.1016/j.apmt.2020.100567· OSTI ID:1801610

Ojeda Mota, Rodrigo Miguel ^[1]; Liu, Naijia ^[1]; Kube, Sebastian Alexander ^[1]; Chay, John ^[1]; McClintock, Hayley D. ^[1]; Schroers, Jan ^[1]

Yale Univ., New Haven, CT (United States)

Bulk metallic glasses (BMGs) exhibit remarkable mechanical properties, such as high strength and elasticity, which is often paired with fracture toughness. Their supercooled liquid region gives rise to plastic-like processing and suggests parts and shapes that can otherwise not be obtained for crystalline metals. However, current processing techniques only allow for limited options in terms of geometry, thicknesses uniformity, and shape complexity. Here we introduce a new processing technique, “stretch blow molding,” to expand the range of possible parts and increase the available geometries that can be fabricated with BMGs. Additionally, a model is derived that allows for the quantification and prediction of stretch blow molding and provides insight into its potential use and limitations. We demonstrate that with stretch blow molding overall strains exceeding 2000% are achievable, compared to the previously reported ~150% of blow molding. With the ability to stretch blow mold shapes that were previously unachievable with any other metal fabrication technique in a fast and economical manner, and the superb properties of BMGs, we look forward to a broad commercial adaptation of this technique.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Yale Univ., New Haven, CT (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0004889

OSTI ID:: 1801610

Journal Information:: Applied Materials Today, Vol. 19; ISSN 2352-9407

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (37)

Metallic Glass Hemispherical Shell Resonators Kanik, Michael; Bordeenithikasem, Punnathat; Kim, Dennis Journal of Microelectromechanical Systems, Vol. 24, Issue 1 https://doi.org/10.1109/JMEMS.2014.2363581	journal	February 2015
High strain rate thermoplastic demolding of metallic glasses Hasan, Molla; Kumar, Golden Scripta Materialia, Vol. 123 https://doi.org/10.1016/j.scriptamat.2016.06.021	journal	October 2016
Mechanical glass transition revealed by the fracture toughness of metallic glasses Ketkaew, Jittisa; Chen, Wen; Wang, Hui Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-05682-8	journal	August 2018
Effect of strain rate on the formation of nanocrystallites in an Al-based amorphous alloy during nanoindentation Jiang, W. H.; Pinkerton, F. E.; Atzmon, M. Journal of Applied Physics, Vol. 93, Issue 11 https://doi.org/10.1063/1.1571234	journal	June 2003
Critical Crystallization for Embrittlement in Metallic Glasses Ketkaew, Jittisa; Liu, Ze; Chen, Wen Physical Review Letters, Vol. 115, Issue 26 https://doi.org/10.1103/PhysRevLett.115.265502	journal	December 2015
Embrittlement of Zr-based bulk metallic glasses Kumar, G.; Rector, D.; Conner, R. D. Acta Materialia, Vol. 57, Issue 12 https://doi.org/10.1016/j.actamat.2009.04.016	journal	July 2009
Viscosity of the supercooled liquid and relaxation at the glass transition of the Zr46.75Ti8.25Cu7.5Ni10Be27.5 bulk metallic glass forming alloy Busch, R.; Bakke, E.; Johnson, W. L. Acta Materialia, Vol. 46, Issue 13 https://doi.org/10.1016/S1359-6454(98)00122-0	journal	August 1998
Rejuvenation of metallic glasses by non-affine thermal strain Ketov, S. V.; Sun, Y. H.; Nachum, S. Nature, Vol. 524, Issue 7564 https://doi.org/10.1038/nature14674	journal	August 2015
Critical fictive temperature for plasticity in metallic glasses Kumar, Golden; Neibecker, Pascal; Liu, Yan Hui Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2546	journal	February 2013
Influence of cooling rate on the structure and properties of a Cu–Zr–Ti–Ag glassy alloy Louzguine-Luzgin, Dmitri V.; Saito, Takanobu; Saida, Junji Journal of Materials Research, Vol. 23, Issue 2 https://doi.org/10.1557/JMR.2008.0066	journal	February 2008
Deformation behavior of the Zr41.2Ti13.8Cu12.5Ni10Be22.5 bulk metallic glass over a wide range of strain-rates and temperatures Lu, J.; Ravichandran, G.; Johnson, W. L. Acta Materialia, Vol. 51, Issue 12 https://doi.org/10.1016/S1359-6454(03)00164-2	journal	July 2003
Thermoplastic blow molding of metals Schroers, Jan; Hodges, Thomas M.; Kumar, Golden Materials Today, Vol. 14, Issue 1-2 https://doi.org/10.1016/S1369-7021(11)70018-9	journal	January 2011
The effect of thermal cycling on the fracture toughness of metallic glasses Ketkaew, Jittisa; Yamada, Rui; Wang, Hui Acta Materialia, Vol. 184 https://doi.org/10.1016/j.actamat.2019.11.046	journal	February 2020
Fragility and thermal stability of Pt- and Pd-based bulk glass forming liquids and their correlation with deformability Kato, H.; Wada, T.; Hasegawa, M. Scripta Materialia, Vol. 54, Issue 12 https://doi.org/10.1016/j.scriptamat.2006.03.025	journal	June 2006
Thermoplastic extrusion of bulk metallic glass Chiu, Ho Ming; Kumar, Golden; Blawzdziewicz, Jerzy Scripta Materialia, Vol. 61, Issue 1 https://doi.org/10.1016/j.scriptamat.2009.02.052	journal	July 2009
Honeycomb Structures of Bulk Metallic Glasses Sarac, Baran; Ketkaew, Jittisa; Popnoe, Dawn Olivia Advanced Functional Materials, Vol. 22, Issue 15 https://doi.org/10.1002/adfm.201200539	journal	April 2012
Strain Rate Induced Crystallization in Bulk Metallic Glass-Forming Liquid Lohwongwatana, Boonrat; Schroers, Jan; Johnson, William L. Physical Review Letters, Vol. 96, Issue 7 https://doi.org/10.1103/PhysRevLett.96.075503	journal	February 2006
Protocols for multi-step thermoplastic processing of metallic glasses Bordeenithikasem, Punnathat; Sohn, Sungwoo; Liu, Ze Scripta Materialia, Vol. 104 https://doi.org/10.1016/j.scriptamat.2015.03.024	journal	July 2015
Hot rolling of bulk metallic glass in its supercooled liquid region Martinez, Robert; Kumar, Golden; Schroers, Jan Scripta Materialia, Vol. 59, Issue 2 https://doi.org/10.1016/j.scriptamat.2008.03.008	journal	July 2008
Additive manufacturing of metals Herzog, Dirk; Seyda, Vanessa; Wycisk, Eric Acta Materialia, Vol. 117 https://doi.org/10.1016/j.actamat.2016.07.019	journal	September 2016
3D printing metals like thermoplastics: Fused filament fabrication of metallic glasses Gibson, Michael A.; Mykulowycz, Nicholas M.; Shim, Joseph Materials Today, Vol. 21, Issue 7 https://doi.org/10.1016/j.mattod.2018.07.001	journal	September 2018
Criticality in Bulk Metallic Glass Constituent Elements Mota, Rodrigo Miguel Ojeda; Graedel, T. E.; Pekarskaya, Evgenia JOM, Vol. 69, Issue 11 https://doi.org/10.1007/s11837-017-2415-6	journal	July 2017
Shear bands and cracking of metallic glass plates in bending Conner, R. D.; Johnson, W. L.; Paton, N. E. Journal of Applied Physics, Vol. 94, Issue 2 https://doi.org/10.1063/1.1582555	journal	July 2003
Superplasticity in advanced materials Chokshi, A.; Mukherjee, A.; Langdon, T. Materials Science and Engineering: R: Reports, Vol. 10, Issue 6 https://doi.org/10.1016/0927-796X(93)90009-R	journal	September 1993
Effect of ion irradiation on tensile ductility, strength and fictive temperature in metallic glass nanowires Magagnosc, D. J.; Kumar, G.; Schroers, J. Acta Materialia, Vol. 74 https://doi.org/10.1016/j.actamat.2014.04.002	journal	August 2014
Three-Dimensional Shell Fabrication Using Blow Molding of Bulk Metallic Glass Sarac, Baran; Kumar, Golden; Hodges, Thomas Journal of Microelectromechanical Systems, Vol. 20, Issue 1 https://doi.org/10.1109/JMEMS.2010.2090495	journal	February 2011
Processing metallic glasses by selective laser melting Pauly, Simon; Löber, Lukas; Petters, Romy Materials Today, Vol. 16, Issue 1-2 https://doi.org/10.1016/j.mattod.2013.01.018	journal	January 2013
Processing of Bulk Metallic Glass Schroers, Jan Advanced Materials, Vol. 22, Issue 14 https://doi.org/10.1002/adma.200902776	journal	December 2009
Shear-accelerated crystallization in a supercooled atomic liquid Shao, Zhen; Singer, Jonathan P.; Liu, Yanhui Physical Review E, Vol. 91, Issue 2 https://doi.org/10.1103/PhysRevE.91.020301	journal	February 2015
Thermodynamics and Kinetics of Bulk Metallic Glass Busch, R.; Schroers, J.; Wang, W. H. MRS Bulletin, Vol. 32, Issue 8 https://doi.org/10.1557/mrs2007.122	journal	August 2007
Transformation superplasticity of zirconium Zwigl, Peter; Dunand, David C. Metallurgical and Materials Transactions A, Vol. 29, Issue 10 https://doi.org/10.1007/s11661-998-0229-4	journal	October 1998
Blow molding of bulk metallic glass Schroers, Jan; Pham, Quoc; Peker, Atakan Scripta Materialia, Vol. 57, Issue 4 https://doi.org/10.1016/j.scriptamat.2007.04.033	journal	August 2007
Joining of bulk metallic glasses in air Chen, Wen; Liu, Ze; Schroers, Jan Acta Materialia, Vol. 62 https://doi.org/10.1016/j.actamat.2013.08.053	journal	January 2014
On the formability of bulk metallic glass in its supercooled liquid state Schroers, Jan Acta Materialia, Vol. 56, Issue 3 https://doi.org/10.1016/j.actamat.2007.10.008	journal	February 2008
Laser powder bed fusion additive manufacturing of metals; physics, computational, and materials challenges King, W. E.; Anderson, A. T.; Ferencz, R. M. Applied Physics Reviews, Vol. 2, Issue 4 https://doi.org/10.1063/1.4937809	journal	December 2015
Timescales of crystallization and viscous flow of the bulk glass-forming Zr-Ti-Ni-Cu-Be alloys Waniuk, Theodore; Schroers, Jan; Johnson, William L. Physical Review B, Vol. 67, Issue 18 https://doi.org/10.1103/PhysRevB.67.184203	journal	May 2003
New Methods for Developing and Manufacturing Compliant Mechanisms Utilizing Bulk Metallic Glass: New Methods for Developing and Manufacturing Compliant Mechanisms Homer, Eric R.; Harris, Matthew B.; Zirbel, Shannon A. Advanced Engineering Materials, Vol. 16, Issue 7 https://doi.org/10.1002/adem.201300566	journal	March 2014

Similar Records

Simulation of the Two Stages Stretch-Blow Molding Process: Infrared Heating and Blowing Modeling

Journal Article · Thu May 17 00:00:00 EDT 2007 · AIP Conference Proceedings · OSTI ID:1801610

Bordival, M; Schmidt, F M; Le Maoult, Y; +1 more

Simulative design and process optimization of the two-stage stretch-blow molding process

Journal Article · Fri May 22 00:00:00 EDT 2015 · AIP Conference Proceedings · OSTI ID:1801610

Hopmann, Ch.; Rasche, S.; Windeck, C.

Thermo-mechanical simulation of liquid-supported stretch blow molding

Journal Article · Fri May 22 00:00:00 EDT 2015 · AIP Conference Proceedings · OSTI ID:1801610

Zimmer, J.; Stommel, M.

Related Subjects

36 MATERIALS SCIENCE
bulk metallic glass
thermoplastic forming
stretch blow molding
superplastic forming

Title: Overcoming geometric limitations in metallic glasses through stretch blow molding

Citation Formats

References (37)

Similar Records

Related Subjects