Mg2+ ion-catalyzed polymerization of 1,3-dioxolane in battery electrolytes

Sahadeo, Emily; Wang, Yang; Lin, Chuan-Fu; Li, Yue; Rubloff, Gary; Lee, Sang Bok

doi:10.1039/d0cc01769h

Mg²⁺ ion-catalyzed polymerization of 1,3-dioxolane in battery electrolytes

Journal Article · Mon Mar 16 00:00:00 EDT 2020 · ChemComm

DOI:https://doi.org/10.1039/d0cc01769h· OSTI ID:1801463

^[1]; Wang, Yang ^[2]; Lin, Chuan-Fu ^[3]; ^[2]; Rubloff, Gary ^[4]; ^[2]

Univ. of Maryland, College Park, MD (United States). Dept. of Chemistry and Biochemistry; OSTI
Univ. of Maryland, College Park, MD (United States). Dept. of Chemistry and Biochemistry
The Catholic Univ. of America, Washington, DC (United States). Dept. of Mechanical Engineering
Univ. of Maryland, College Park, MD (United States). Dept. of Materials Science and Engineering. Inst. for Systems Research

Electrolyte salts with Mg²⁺ and Al³⁺ Lewis acidic cations demonstrate polymerization of 1,3-dioxolane. The speed and extent of the reaction depends on coordination of the anion with the Mg²⁺ cation catalyst. Weakly coordinating anions such as TFSI^- aid faster polymerization while strongly coordinating anions such as ClO₄^- hinder the polymerization.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Maryland, College Park, MD (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001160

OSTI ID:: 1801463

Alternate ID(s):: OSTI ID: 1606062

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 33 Vol. 56; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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