Tuning the excited-state deactivation pathways of dinuclear ruthenium( ii ) 2,2'-bipyridine complexes through bridging ligand design

Cerfontaine, Simon; Troian-Gautier, Ludovic; Wehlin, Sara A.  M.; Loiseau, Frédérique; Cauët, Emilie; Elias, Benjamin

doi:10.1039/d0dt01216e

Title: Tuning the excited-state deactivation pathways of dinuclear ruthenium( ii ) 2,2'-bipyridine complexes through bridging ligand design

Journal Article · Wed Jan 01 00:00:00 EST 2020 · Dalton Transactions

DOI:https://doi.org/10.1039/d0dt01216e· OSTI ID:1801394

^[1];

^[2]; Wehlin, Sara A. M. ^[3]; Loiseau, Frédérique ^[4]; Cauët, Emilie ^[5];

^[1]

Université catholique de Louvain (UCLouvain); Institut de la Matière Condensée et des Nanosciences (IMCN); Molecular Chemistry; Materials and Catalysis (MOST); 1348 Louvain-la-Neuve
Laboratoire de Chimie Organique; Université libre de Bruxelles (ULB); 1050 Brussels; Belgium; Department of Chemistry
Department of Chemistry; University of North Carolina at Chapel Hill; Chapel Hill; USA
Département de Chimie Moléculaire; Univ. Grenoble-Alpes (UGA); 38058 Grenoble; France
Spectroscopy; Quantum Chemistry and Atmospheric Remote Sensing (CP 160/09); Université libre de Bruxelles; B-1050 Brussels; Belgium

A detailed photophysical study of binuclear complexes was performed using steady-state and time-resolved photoluminescence measurements at variable temperature. The results were compared with the prototypical [Ru(bpy)₃]²⁺.

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Research Organization:: University of North Carolina, Chapel Hill, NC (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0001011

OSTI ID:: 1801394

Journal Information:: Dalton Transactions, Vol. 49, Issue 24; ISSN 1477-9226

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

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