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Title: Reversible Symmetry-Breaking Charge Separation in a Series of Perylenediimide Cyclophanes

Journal Article · · Journal of Physical Chemistry. C

Not provided.

Research Organization:
Northwestern Univ., Evanston, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
FG02-99ER14999
OSTI ID:
1800958
Journal Information:
Journal of Physical Chemistry. C, Vol. 124, Issue 19; ISSN 1932-7447
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

References (52)

Photo-induced electron and energy transfer in non-covalently bonded supramolecular assemblies journal January 1997
Powering the future of molecular artificial photosynthesis with light-harvesting metallosupramolecular dye assemblies journal January 2013
Solar Fuels via Artificial Photosynthesis journal December 2009
Photoinduced electron transfer in supramolecular systems for artificial photosynthesis journal May 1992
Molecular Aggregate Photophysics beyond the Kasha Model: Novel Design Principles for Organic Materials journal January 2017
Perylene Diimide-Based Hj- and hJ-Aggregates: The Prospect of Exciton Band Shape Engineering in Organic Materials journal August 2019
Energy of Excimer Luminescence. II. Configuration Interaction between Molecular Exciton States and Charge Resonance States journal December 1964
Mixed Excimer Fluorescence; The Importance of Charge‐Transfer Interaction journal October 1967
Excimers journal May 1969
Photoinduced Symmetry-Breaking Charge Separation journal March 2012
Photoinduced Symmetry-Breaking Charge Separation: The Direction of the Charge Transfer journal July 2011
Direct Observation of Excimer-Mediated Intramolecular Electron Transfer in a Cofacially-Stacked Perylene Bisimide Pair journal July 2016
Symmetry-Breaking Charge Separation in a Nanoscale Terrylenediimide Guanine-Quadruplex Assembly journal October 2019
Symmetry Breaking in the Relaxed S 1 Excited State of Bianthryl Derivatives in Weakly Polar Solvents journal June 2001
Ultrafast Photoinduced Symmetry-Breaking Charge Separation and Electron Sharing in Perylenediimide Molecular Triangles journal October 2015
Guest and solvent modulated photo-driven charge separation and triplet generation in a perylene bisimide cyclophane journal January 2016
Ultrafast Spectroscopy of the Solvent Dependence of Electron Transfer in a Perylenebisimide Dimer journal September 2005
Excited-State Symmetry Breaking in Cofacial and Linear Dimers of a Green Perylenediimide Chlorophyll Analogue Leading to Ultrafast Charge Separation journal July 2002
Singlet Exciton Fission in Polycrystalline Thin Films of a Slip-Stacked Perylenediimide journal September 2013
Perylene Bisimide Dye Assemblies as Archetype Functional Supramolecular Materials journal August 2015
The Rylene Colorant Family-Tailored Nanoemitters for Photonics Research and Applications journal October 2010
Combining Light-Harvesting and Charge Separation in a Self-Assembled Artificial Photosynthetic System Based on Perylenediimide Chromophores journal October 2004
Ring-Fusion of Perylene Diimide Acceptor Enabling Efficient Nonfullerene Organic Solar Cells with a Small Voltage Loss journal November 2017
On the Theory of Oxidation‐Reduction Reactions Involving Electron Transfer. I journal May 1956
On the Theory of Electron‐Transfer Reactions. VI. Unified Treatment for Homogeneous and Electrode Reactions journal July 1965
Symmetry-Breaking Charge Transfer in a Zinc Chlorodipyrrin Acceptor for High Open Circuit Voltage Organic Photovoltaics journal April 2015
Steric Interactions Impact Vibronic and Vibrational Coherences in Perylenediimide Cyclophanes journal November 2019
The Delicate Balance of Preorganisation and Adaptability in Multiply Bonded Host-Guest Complexes journal January 2017
Ultrafast Conformational Dynamics of Electron Transfer in ExBox 4+ ⊂Perylene journal November 2013
Near-transform-limited visible and near-IR femtosecond pulses from optical parametric amplification using Type II β-barium borate journal January 1995
Singlet Fission in Covalent Terrylenediimide Dimers: Probing the Nature of the Multiexciton State Using Femtosecond Mid-Infrared Spectroscopy journal June 2018
Characterization of Excimer Relaxation via Femtosecond Shortwave- and Mid-Infrared Spectroscopy journal October 2016
Direct Observation of the Photoreduction Products of Mn(NDI-bpy)(CO) 3 X CO 2 Reduction Catalysts Using Femtosecond Transient IR Spectroscopy journal February 2019
Advances in molecular quantum chemistry contained in the Q-Chem 4 program package journal September 2014
Avogadro: an advanced semantic chemical editor, visualization, and analysis platform journal August 2012
The exciton model in molecular spectroscopy journal January 1965
Photoinduced Electron Transfer in Solution: Exciplex and Radical Ion Pair Formation Free Enthalpies and their Solvent Dependence journal January 1982
Direct Visualization of Excited-State Symmetry Breaking Using Ultrafast Time-Resolved Infrared Spectroscopy journal March 2016
Probing Distance Dependent Charge-Transfer Character in Excimers of Extended Viologen Cyclophanes Using Femtosecond Vibrational Spectroscopy journal September 2017
Direct Observation of Ultrafast Excimer Formation in Covalent Perylenediimide Dimers Using Near-Infrared Transient Absorption Spectroscopy journal July 2014
Triplet State Formation in Photoexcited Slip-Stacked Perylene-3,4:9,10-bis(dicarboximide) Dimers on a Xanthene Scaffold journal September 2013
Energy Flow Dynamics within Cofacial and Slip-Stacked Perylene-3,4-dicarboximide Dimer Models of π-Aggregates journal October 2014
Through-Bond and Through-Space Coupling in Photoinduced Electron and Energy Transfer:  An ab Initio and Semiempirical Study journal January 1996
Electronic Coupling in C-Clamp-Shaped Molecules:  Solvent-Mediated Superexchange Pathways journal January 1996
Use of U-shaped Donor-Bridge-Acceptor Molecules To Study Electron Tunneling through Nonbonded Contacts journal August 2002
Solvent Mediated Superexchange in a C-Clamp Shaped Donor-Bridge-Acceptor Molecule:  The Correlation between Solvent Electron Affinity and Electronic Coupling journal April 2002
Solvent-Mediated Electronic Coupling:  The Role of Solvent Placement journal December 1999
Solvent-Mediated Electron Transfer:  Correlation between Coupling Magnitude and Solvent Vertical Electron Affinity journal August 1998
Dynamic Nature of the Intramolecular Electronic Coupling Mediated by a Solvent Molecule:  A Computational Study journal January 2004
Solute–Solvent Interactions and Excited-State Symmetry Breaking: Beyond the Dipole–Dipole and the Hydrogen-Bond Interactions journal August 2017
Thermal electron transfer reactions in polar solvents journal October 1974
Dipole Solvation in Nondipolar Solvents:  Experimental Studies of Reorganization Energies and Solvation Dynamics journal January 1996

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