A novel generalized metal dissolution approach for the synthesis of mixed valent mesoporous metal oxides

Thalgaspitiya, Wimalika R.K.; Kapuge, Tharindu Kankanam; Rathnayake, Dinithi; He, Junkai; Willis, William S.; Suib, Steven L.

doi:10.1016/j.mattod.2019.10.024

A novel generalized metal dissolution approach for the synthesis of mixed valent mesoporous metal oxides

Journal Article · Mon Nov 25 00:00:00 UTC 2019 · Materials Today

DOI:https://doi.org/10.1016/j.mattod.2019.10.024· OSTI ID:1800618

Thalgaspitiya, Wimalika R.K. ^[1]; Kapuge, Tharindu Kankanam ^[2]; Rathnayake, Dinithi ^[2]; He, Junkai ^[2]; Willis, William S. ^[2]; ^[2]

University of Connecticut, Storrs, CT (United States); OSTI
University of Connecticut, Storrs, CT (United States)

A novel approach is introduced to synthesize multivalent, mesoporous metal oxides with high surface area using zero oxidation state precursors. In this paper, the synthesis and comprehensive characterization of the metal oxides of s block, p block, transition metal, and lanthanide series elements are reported. Some of the synthesized metal oxides showed mixed phases at relatively low temperatures which is advantageous over single-phase materials. The initial metal dissolution process allows this method to be extended to any metal in the periodic table and metal alloys. A green and highly efficient catalytic sp²-sp² C–C coupling reaction is carried out using high surface area MoO3 (142 m²/g) where complete conversion is observed within one hour.

View Accepted Manuscript (DOE)

Research Organization:: University of Connecticut, Storrs, CT (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: FG02-86ER13622

OSTI ID:: 1800618

Alternate ID(s):: OSTI ID: 1631350

Journal Information:: Materials Today, Journal Name: Materials Today Journal Issue: C Vol. 35; ISSN 1369-7021

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Thermal Behavior of a New Type Molybdenum Oxide Obtained by Oxidation of Molybdenum Powder or Molydenum Trioxide with Hydrogen Peroxide Kurusu, Yasuhiko Bulletin of the Chemical Society of Japan, Vol. 54, Issue 1 https://doi.org/10.1246/bcsj.54.293	journal	January 1981
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Chemical Synthesis of Vanadium Oxide (V2O5) Nanoparticles Prepared by Sodium Metavanadate Farahmandjou, Majid Journal of Nanomedicine Research, Vol. 5, Issue 1 https://doi.org/10.15406/jnmr.2017.05.00103	journal	January 2017
Design of Transition Metal Oxide and Hybrid Mesoporous Materials Sanchez, Clément; Crepaldi, Eduardo L.; Bouchara, Anne MRS Proceedings, Vol. 728 https://doi.org/10.1557/PROC-728-S1.2	journal	January 2002
A Novel Green Synthesis of Nickel Oxide Nanoparticles Using Arabic Gum Fardood, Saeid Taghavi; Ramazani, Ali; Moradi, Sajjad Chemistry Journal of Moldova, Vol. 12, Issue 1 https://doi.org/10.19261/cjm.2017.383	journal	May 2017
Physical & Electrochemical Properties of Green Synthesized Bunsenite NiO Nanoparticles via Callistemon Viminalis’ Extracts T. Sone, B. International Journal of Electrochemical Science https://doi.org/10.20964/2016.10.17	journal	October 2016
Mesoporous Transition Metal Oxides for Supercapacitors Wang, Yan; Guo, Jin; Wang, Tingfeng Nanomaterials, Vol. 5, Issue 4 https://doi.org/10.3390/nano5041667	journal	October 2015
Band Gap Energies of Magnesium Oxide Nanomaterials Synthesized by the Sol-Gel Method Badar, Nurhanna; Chayed, Nor Fadilah; Roshidah, Rusdi Advanced Materials Research, Vol. 545 https://doi.org/10.4028/www.scientific.net/AMR.545.157	journal	July 2012
Electrodeposited Cobalt-Iron Alloy Thin-Film for Potentiometric Hydrogen Phosphate-Ion Sensor Kidosaki, Toru; Takase, Satoko; Shimizu, Youichi Journal of Sensor Technology, Vol. 02, Issue 03 https://doi.org/10.4236/jst.2012.23014	journal	January 2012

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