Monitoring structural variation on Gd ratio of La modified bismuth ferrite ceramics with enhanced magnetization

Bozgeyik, Mehmet S.; Kirkgecit, Nurvet; Katiyar, Rajesh K.; Katiyar, Ram S.

doi:10.1016/j.jallcom.2019.153050

Monitoring structural variation on Gd ratio of La modified bismuth ferrite ceramics with enhanced magnetization

Journal Article · Mon Nov 18 00:00:00 EST 2019 · Journal of Alloys and Compounds

DOI:https://doi.org/10.1016/j.jallcom.2019.153050· OSTI ID:1800581

^[1]; Kirkgecit, Nurvet ^[2]; Katiyar, Rajesh K. ^[3]; Katiyar, Ram S. ^[3]

Univ. of Puerto Rico, San Juan, PR (United States); Kahramanmaras Sutcu Imam Univ., Kahramanmaras (Turkey); OSTI
Kahramanmaras Sutcu Imam Univ., Kahramanmaras (Turkey)
Univ. of Puerto Rico, San Juan, PR (United States)

Critical structural variation and dielectric properties were investigated in Lanthanum and Gadolinium co-substituted bismuth ferrite (Bi_0.9La_0.1Fe_1-xGd_xO₃ (x = 0.01, 0.03, 0.05, 0.07, 0.1, and 0.15). Conventional solid state reaction technique was used to synthesize ceramic samples. To investigate the influence of co-substitution on the phase formation and crystal structure, X-ray diffraction method (XRD), Scanning electron microscopy (SEM) and Raman spectroscopy were utilized. Probing the structural properties by changing Gd ratio was carried out to ensure single phase of rhombohedral R3c structure. Hence, the exploration of dielectric properties of single phase modified BiFeO₃ (BFO) ceramic was executed by room temperature capacitance and loss tangent measurements. It was found that by substitution of 10 mol% La for Bi and up to 5 mol% Gd for Bi, perovskite structure of rhombohedral symmetry and R3c space group were formed. This possessed enhanced magnetization and reduced dielectric loss compared to pure BFO.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Puerto Rico, San Juan, PR (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-08ER46526

OSTI ID:: 1800581

Alternate ID(s):: OSTI ID: 1702831

Journal Information:: Journal of Alloys and Compounds, Journal Name: Journal of Alloys and Compounds Vol. 819; ISSN 0925-8388

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Monitoring structural variation on Gd ratio of La modified bismuth ferrite ceramics with enhanced magnetization

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