Surprisingly big linker-dependence of activity and selectivity in CO 2 reduction by an iridium( i ) pincer complex

Hu, Gongfang; Jiang, Jianbing “Jimmy”; Kelly, H. Ray; Matula, Adam J.; Wu, Yueshen; Romano, Neyen; Mercado, Brandon Q.; Wang, Hailiang; Batista, Victor S.; Crabtree, Robert H.; Brudvig, Gary W.

doi:10.1039/d0cc03207g

Title: Surprisingly big linker-dependence of activity and selectivity in CO ₂ reduction by an iridium( i ) pincer complex

Journal Article · Wed Jan 01 00:00:00 EST 2020 · ChemComm

DOI:https://doi.org/10.1039/d0cc03207g· OSTI ID:1800437

^[1]; Jiang, Jianbing “Jimmy” ^[2]; Kelly, H. Ray ^[1]; Matula, Adam J. ^[1]; Wu, Yueshen ^[1]; Romano, Neyen ^[1]; Mercado, Brandon Q. ^[3];

^[1]; Batista, Victor S. ^[1];

^[1];

^[1]

Department of Chemistry; Yale University; New Haven; USA; Energy Sciences Institute
Department of Chemistry; University of Cincinnati; Cincinnati; USA
Department of Chemistry; Yale University; New Haven; USA

Here, we report the quantitative electroreduction of CO₂to CO by a PNP-pincer iridium(i) complex bearing amino linkers in DMF/water. The activity and selectivity of the reduction greatly depend on the choice of linker within the ligand.

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Research Organization:: Yale Univ., New Haven, CT (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

DOE Contract Number:: FG02-07ER15909

OSTI ID:: 1800437

Journal Information:: ChemComm, Vol. 56, Issue 64; ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

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Title: Surprisingly big linker-dependence of activity and selectivity in CO 2 reduction by an iridium( i ) pincer complex

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Title: Surprisingly big linker-dependence of activity and selectivity in CO ₂ reduction by an iridium( i ) pincer complex