First-row transition metal polypyridine complexes that catalyze proton to hydrogen reduction

Tong, Lianpeng; Duan, Lele; Zhou, Aiju; Thummel, Randolph P.

doi:10.1016/j.ccr.2019.213079

First-row transition metal polypyridine complexes that catalyze proton to hydrogen reduction

Journal Article · Wed Oct 16 00:00:00 EDT 2019 · Coordination Chemistry Reviews

DOI:https://doi.org/10.1016/j.ccr.2019.213079· OSTI ID:1800416

Tong, Lianpeng ^[1]; Duan, Lele ^[2]; Zhou, Aiju ^[3]; Thummel, Randolph P. ^[4]

Guangzhou Univ. (China); OSTI
Southern Univ. of Science and Technology, Shenzhen (China)
Guangzhou Univ. (China)
Univ. of Houston, TX (United States)

Proton reduction is a critical reaction for the efficient utilization of solar fuels and the development of a hydrogen economy. Molecular proton reduction catalysts help us to understand how hydrogenases function in nature, on one hand, and inspire us to design new practical materials on the other. This manuscript introduces the concept of electrocatalytic and photocatalytic proton (hydrogen evolution) in a homogeneous system, and then reviews recent studies on molecular proton reduction catalysts that contain 3d transition metal centers (Mn, Fe, Co, and Ni) surrounded by polypyridine ligands. The discussion focuses on the design, structure, and catalytic behavior of these metal polypyridine catalysts. Catalytic pathways, and how they are affected by complex structure, are addressed in order to offer rational suggestions for the future preparation of promising hydrogen evolution catalysts.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Houston, TX (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-07ER15888

OSTI ID:: 1800416

Alternate ID(s):: OSTI ID: 1570543

Journal Information:: Coordination Chemistry Reviews, Journal Name: Coordination Chemistry Reviews Vol. 402; ISSN 0010-8545

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (238)

Hydrogenases: Hydrogen-Activating Enzymes Frey, Michel ChemBioChem, Vol. 3, Issue 2-3 https://doi.org/10.1002/1439-7633(20020301)3:2/3<153::AID-CBIC153>3.0.CO;2-B	journal	March 2002
Single-Atom Catalysts: Emerging Multifunctional Materials in Heterogeneous Catalysis Zhang, Huabin; Liu, Guigao; Shi, Li Advanced Energy Materials, Vol. 8, Issue 1 https://doi.org/10.1002/aenm.201701343	journal	September 2017
Splitting Water with Cobalt Artero, Vincent; Chavarot-Kerlidou, Murielle; Fontecave, Marc Angewandte Chemie International Edition, Vol. 50, Issue 32 https://doi.org/10.1002/anie.201007987	journal	July 2011
A Nickel Thiolate Catalyst for the Long-Lived Photocatalytic Production of Hydrogen in a Noble-Metal-Free System Han, Zhiji; McNamara, William R.; Eum, Min-Sik Angewandte Chemie International Edition, Vol. 51, Issue 7 https://doi.org/10.1002/anie.201107329	journal	January 2012
Electrocatalytic and Photocatalytic Hydrogen Production in Aqueous Solution by a Molecular Cobalt Complex Singh, Wangkheimayum Marjit; Baine, Teera; Kudo, Shotaro Angewandte Chemie International Edition, Vol. 51, Issue 24 https://doi.org/10.1002/anie.201200082	journal	April 2012
Photocatalytic Water Reduction with Copper-Based Photosensitizers: A Noble-Metal-Free System Luo, Shu-Ping; Mejía, Esteban; Friedrich, Aleksej Angewandte Chemie International Edition, Vol. 52, Issue 1 https://doi.org/10.1002/anie.201205915	journal	October 2012
Molybdenum Boride and Carbide Catalyze Hydrogen Evolution in both Acidic and Basic Solutions Vrubel, Heron; Hu, Xile Angewandte Chemie International Edition, Vol. 51, Issue 51 https://doi.org/10.1002/anie.201207111	journal	November 2012
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles Popczun, Eric J.; Read, Carlos G.; Roske, Christopher W. Angewandte Chemie International Edition, Vol. 53, Issue 21 https://doi.org/10.1002/anie.201402646	journal	April 2014
A Molecular Copper Catalyst for Electrochemical Water Reduction with a Large Hydrogen-Generation Rate Constant in Aqueous Solution Zhang, Peili; Wang, Mei; Yang, Yong Angewandte Chemie International Edition, Vol. 53, Issue 50 https://doi.org/10.1002/anie.201408266	journal	October 2014
Ligand Transformations and Efficient Proton/Water Reduction with Cobalt Catalysts Based on Pentadentate Pyridine-Rich Environments Basu, Debashis; Mazumder, Shivnath; Shi, Xuetao Angewandte Chemie International Edition, Vol. 54, Issue 7 https://doi.org/10.1002/anie.201409813	journal	December 2014
Singly versus Doubly Reduced Nickel Porphyrins for Proton Reduction: Experimental and Theoretical Evidence for a Homolytic Hydrogen-Evolution Reaction Han, Yongzhen; Fang, Huayi; Jing, Huize Angewandte Chemie International Edition, Vol. 55, Issue 18 https://doi.org/10.1002/anie.201510001	journal	March 2016
Single-Site Active Cobalt-Based Photocatalyst with a Long Carrier Lifetime for Spontaneous Overall Water Splitting Liu, Wei; Cao, Linlin; Cheng, Weiren Angewandte Chemie International Edition, Vol. 56, Issue 32 https://doi.org/10.1002/anie.201704358	journal	June 2017
Antimony Complexes for Electrocatalysis: Activity of a Main‐Group Element in Proton Reduction Jiang, Jianbing; Materna, Kelly L.; Hedström, Svante Angewandte Chemie International Edition, Vol. 56, Issue 31 https://doi.org/10.1002/anie.201704700	journal	July 2017
Atomic-Level Insight into Optimizing the Hydrogen Evolution Pathway over a Co ₁ -N ₄ Single-Site Photocatalyst Cao, Yuanjie; Chen, Si; Luo, Qiquan Angewandte Chemie International Edition, Vol. 56, Issue 40 https://doi.org/10.1002/anie.201706467	journal	August 2017
Visible-Light Photocatalysis: Does It Make a Difference in Organic Synthesis? Marzo, Leyre; Pagire, Santosh K.; Reiser, Oliver Angewandte Chemie International Edition, Vol. 57, Issue 32 https://doi.org/10.1002/anie.201709766	journal	June 2018
Carbon Nanotubes with Cobalt Corroles for Hydrogen and Oxygen Evolution in pH 0-14 Solutions Li, Xialiang; Lei, Haitao; Liu, Jieyu Angewandte Chemie International Edition, Vol. 57, Issue 46 https://doi.org/10.1002/anie.201807996	journal	October 2018
Hydrogen Evolution from Aqueous Solutions Mediated by a Heterogenized [NiFe]-Hydrogenase Model: Low pH Enables Catalysis through an Enzyme-Relevant Mechanism Ahmed, Md Estak; Chattopadhyay, Samir; Wang, Lianke Angewandte Chemie International Edition, Vol. 57, Issue 49 https://doi.org/10.1002/anie.201808215	journal	November 2018
Mechanistic Studies in Photocatalysis Buzzetti, Luca; Crisenza, Giacomo E. M.; Melchiorre, Paolo Angewandte Chemie International Edition, Vol. 58, Issue 12 https://doi.org/10.1002/anie.201809984	journal	March 2019
Multielectron, Multistep Molecular Catalysis of Electrochemical Reactions: Benchmarking of Homogeneous Catalysts Costentin, Cyrille; Savéant, Jean-Michel ChemElectroChem, Vol. 1, Issue 7 https://doi.org/10.1002/celc.201300263	journal	June 2014
Dinuclear Cobalt Complexes with a Decadentate Ligand Scaffold: Hydrogen Evolution and Oxygen Reduction Catalysis Di Giovanni, Carlo; Gimbert-Suriñach, Carolina; Nippe, Michael Chemistry - A European Journal, Vol. 22, Issue 1 https://doi.org/10.1002/chem.201503567	journal	November 2015
Heptacoordinate Co ^II Complex: A New Architecture for Photochemical Hydrogen Production Lucarini, Fiorella; Pastore, Mariachiara; Vasylevskyi, Serhii Chemistry - A European Journal, Vol. 23, Issue 28 https://doi.org/10.1002/chem.201701427	journal	May 2017
Bimetallic Cooperativity in Proton Reduction with an Amido-Bridged Cobalt Catalyst Kpogo, Kenneth K.; Mazumder, Shivnath; Wang, Denan Chemistry - A European Journal, Vol. 23, Issue 39 https://doi.org/10.1002/chem.201701982	journal	June 2017
Structure-Activity and Stability Relationships for Cobalt Polypyridyl-Based Hydrogen-Evolving Catalysts in Water Schnidrig, Stephan; Bachmann, Cyril; Müller, Peter ChemSusChem, Vol. 10, Issue 22 https://doi.org/10.1002/cssc.201701511	journal	November 2017
Photochemistry and Photophysics of Coordination Compounds: Iridium Flamigni, Lucia; Barbieri, Andrea; Sabatini, Cristiana Photochemistry and Photophysics of Coordination Compounds II https://doi.org/10.1007/128_2007_131	book	January 2007
Photochemistry and Photophysics of Coordination Compounds: Ruthenium Campagna, Sebastiano; Puntoriero, Fausto; Nastasi, Francesco Photochemistry and Photophysics of Coordination Compounds I https://doi.org/10.1007/128_2007_133	book	January 2007
The exchange activities of [Fe] hydrogenase (iron–sulfur-cluster-free hydrogenase) from methanogenic archaea in comparison with the exchange activities of [FeFe] and [NiFe] hydrogenases Vogt, Sonja; Lyon, Erica J.; Shima, Seigo JBIC Journal of Biological Inorganic Chemistry, Vol. 13, Issue 1 https://doi.org/10.1007/s00775-007-0302-2	journal	October 2007
Photogeneration and reactions of cobalt(I) complexes Creutz, Carol; Sutin, Norman Coordination Chemistry Reviews, Vol. 64 https://doi.org/10.1016/0010-8545(85)80058-8	journal	May 1985
Ru(II) polypyridine complexes: photophysics, photochemistry, eletrochemistry, and chemiluminescence Juris, A.; Balzani, V.; Barigelletti, F. Coordination Chemistry Reviews, Vol. 84 https://doi.org/10.1016/0010-8545(88)80032-8	journal	March 1988
Potential-sweep chronoamperometry: Kinetic currents for first-order chemical reaction parallel to electron-transfer process (catalytic currents) Saveant, J. M.; Vianello, E. Electrochimica Acta, Vol. 10, Issue 9 https://doi.org/10.1016/0013-4686(65)80003-2	journal	September 1965
Homogeneous redox catalysis of electrochemical reaction Savéant, J. M.; Su, K. B. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 171, Issue 1-2 https://doi.org/10.1016/0022-0728(84)80125-4	journal	August 1984
Formal redox potentials of the dehydro-l-ascorbic acid/l-ascorbic acid system Tur'yan, Yakov I.; Kohen, Ron Journal of Electroanalytical Chemistry, Vol. 380, Issue 1-2 https://doi.org/10.1016/0022-0728(94)03524-7	journal	January 1995
Metal phthalocyanines and porphyrins as photosensitizers for reduction of water to hydrogen Darwent, James R.; Douglas, Petter; Harriman, Anthony Coordination Chemistry Reviews, Vol. 44, Issue 1 https://doi.org/10.1016/S0010-8545(00)80518-4	journal	June 1982
Trans-effects in octahedral transition metal complexes Coe, Benjamin J.; Glenwright, Susan J. Coordination Chemistry Reviews, Vol. 203, Issue 1 https://doi.org/10.1016/S0010-8545(99)00184-8	journal	June 2000
Work function, electronegativity, and electrochemical behaviour of metals Trasatti, Sergio Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 39, Issue 1 https://doi.org/10.1016/S0022-0728(72)80485-6	journal	September 1972
Desulfovibrio desulfuricans iron hydrogenase: the structure shows unusual coordination to an active site Fe binuclear center Nicolet, Yvain; Piras, Claudine; Legrand, Pierre Structure, Vol. 7, Issue 1, p. 13-23 https://doi.org/10.1016/S0969-2126(99)80005-7	journal	January 1999
The problem with platinum Sealy, Cordelia Materials Today, Vol. 11, Issue 12 https://doi.org/10.1016/S1369-7021(08)70254-2	journal	December 2008
Catalytic hydrogen production at cobalt centres Losse, Sebastian; Vos, Johannes G.; Rau, Sven Coordination Chemistry Reviews, Vol. 254, Issue 21-22 https://doi.org/10.1016/j.ccr.2010.06.004	journal	November 2010
Mimicking hydrogenases: From biomimetics to artificial enzymes Simmons, Trevor R.; Berggren, Gustav; Bacchi, Marine Coordination Chemistry Reviews, Vol. 270-271 https://doi.org/10.1016/j.ccr.2013.12.018	journal	July 2014
Recent developments in hydrogen evolving molecular cobalt(II)–polypyridyl catalysts Queyriaux, Nicolas; Jane, Reuben T.; Massin, Julien Coordination Chemistry Reviews, Vol. 304-305 https://doi.org/10.1016/j.ccr.2015.03.014	journal	December 2015
Hydrogen-activating models of hydrogenases Xu, Tao; Chen, Dafa; Hu, Xile Coordination Chemistry Reviews, Vol. 303 https://doi.org/10.1016/j.ccr.2015.05.007	journal	November 2015
Thermal and photocatalytic production of hydrogen with earth-abundant metal complexes Fukuzumi, Shunichi; Lee, Yong-Min; Nam, Wonwoo Coordination Chemistry Reviews, Vol. 355 https://doi.org/10.1016/j.ccr.2017.07.014	journal	January 2018
Electro and photoreduction of CO 2 driven by manganese-carbonyl molecular catalysts Stanbury, Matthew; Compain, Jean-Daniel; Chardon-Noblat, Sylvie Coordination Chemistry Reviews, Vol. 361 https://doi.org/10.1016/j.ccr.2018.01.014	journal	April 2018
Manganese carbonyl complexes for CO 2 reduction Sinopoli, Alessandro; La Porte, Nathan T.; Martinez, Jose F. Coordination Chemistry Reviews, Vol. 365 https://doi.org/10.1016/j.ccr.2018.03.011	journal	June 2018
The crystal structure of C176A mutated [Fe]‐hydrogenase suggests an acyl‐iron ligation in the active site iron complex Hiromoto, Takeshi; Ataka, Kenichi; Pilak, Oliver FEBS Letters, Vol. 583, Issue 3 https://doi.org/10.1016/j.febslet.2009.01.017	journal	January 2009
Hydrogen production in a neutral aqueous solution with a water-soluble copper complex Xin, Zhi-Juan; Liu, Si; Li, Cheng-Bo International Journal of Hydrogen Energy, Vol. 42, Issue 7 https://doi.org/10.1016/j.ijhydene.2016.11.103	journal	February 2017
Measuring and interpreting quantum efficiency for hydrogen photo-production using Pt-titania catalysts Fontelles-Carceller, Olga; Muñoz-Batista, Mario J.; Rodríguez-Castellón, Enrique Journal of Catalysis, Vol. 347 https://doi.org/10.1016/j.jcat.2017.01.012	journal	March 2017
Photosynthetic Water Splitting Provides a Blueprint for Artificial Leaf Technology Barber, James Joule, Vol. 1, Issue 1 https://doi.org/10.1016/j.joule.2017.07.016	journal	September 2017
Characterization of Ni, NiMo, NiW and NiFe electroactive coatings as electrocatalysts for hydrogen evolution in an acidic medium Navarro-Flores, Elisa; Chong, Zhiwen; Omanovic, Sasha Journal of Molecular Catalysis A: Chemical, Vol. 226, Issue 2 https://doi.org/10.1016/j.molcata.2004.10.029	journal	February 2005
Electrocatalytic hydrogen evolution by an iron complex containing a nitro-functionalized polypyridyl ligand Hartley, Carolyn L.; DiRisio, Ryan J.; Chang, Trevor Y. Polyhedron, Vol. 114 https://doi.org/10.1016/j.poly.2015.11.023	journal	August 2016
Theory and Application of Cyclic Voltammetry for Measurement of Electrode Reaction Kinetics. Nicholson, R. S. Analytical Chemistry, Vol. 37, Issue 11 https://doi.org/10.1021/ac60230a016	journal	October 1965
Molecular Electrocatalysts for Oxidation of Hydrogen Using Earth-Abundant Metals: Shoving Protons Around with Proton Relays Bullock, R. Morris; Helm, Monte L. Accounts of Chemical Research, Vol. 48, Issue 7 https://doi.org/10.1021/acs.accounts.5b00069	journal	June 2015
Metal–Polypyridyl Catalysts for Electro- and Photochemical Reduction of Water to Hydrogen Zee, David Z.; Chantarojsiri, Teera; Long, Jeffrey R. Accounts of Chemical Research, Vol. 48, Issue 7 https://doi.org/10.1021/acs.accounts.5b00082	journal	June 2015
Understanding the Kinetics and Spectroscopy of Photoredox Catalysis and Transition-Metal-Free Alternatives Pitre, Spencer P.; McTiernan, Christopher D.; Scaiano, Juan C. Accounts of Chemical Research, Vol. 49, Issue 6 https://doi.org/10.1021/acs.accounts.6b00012	journal	March 2016
Organic Photoredox Catalysis Romero, Nathan A.; Nicewicz, David A. Chemical Reviews, Vol. 116, Issue 17 https://doi.org/10.1021/acs.chemrev.6b00057	journal	June 2016
Hydrogen and Dihydrogen Bonds in the Reactions of Metal Hydrides Belkova, Natalia V.; Epstein, Lina M.; Filippov, Oleg A. Chemical Reviews, Vol. 116, Issue 15 https://doi.org/10.1021/acs.chemrev.6b00091	journal	June 2016
Nickel Hydride Complexes Eberhardt, Nathan A.; Guan, Hairong Chemical Reviews, Vol. 116, Issue 15 https://doi.org/10.1021/acs.chemrev.6b00259	journal	June 2016
Energy-Related Small Molecule Activation Reactions: Oxygen Reduction and Hydrogen and Oxygen Evolution Reactions Catalyzed by Porphyrin- and Corrole-Based Systems Zhang, Wei; Lai, Wenzhen; Cao, Rui Chemical Reviews, Vol. 117, Issue 4 https://doi.org/10.1021/acs.chemrev.6b00299	journal	November 2016
Quaterpyridines as Scaffolds for Functional Metallosupramolecular Materials Gorczyński, Adam; Harrowfield, Jack M.; Patroniak, Violetta Chemical Reviews, Vol. 116, Issue 23 https://doi.org/10.1021/acs.chemrev.6b00377	journal	November 2016
Homogeneously Catalyzed Electroreduction of Carbon Dioxide—Methods, Mechanisms, and Catalysts Francke, Robert; Schille, Benjamin; Roemelt, Michael Chemical Reviews, Vol. 118, Issue 9 https://doi.org/10.1021/acs.chemrev.7b00459	journal	January 2018
Light-Driven Proton Reduction in Aqueous Medium Catalyzed by a Family of Cobalt Complexes with Tetradentate Polypyridine-Type Ligands Tong, Lianpeng; Kopecky, Andrew; Zong, Ruifa Inorganic Chemistry, Vol. 54, Issue 16 https://doi.org/10.1021/acs.inorgchem.5b00915	journal	July 2015
Electrocatalytic Dihydrogen Production by an Earth-Abundant Manganese Bipyridine Catalyst Sampson, Matthew D.; Kubiak, Clifford P. Inorganic Chemistry, Vol. 54, Issue 14 https://doi.org/10.1021/acs.inorgchem.5b01080	journal	June 2015
Bimetallic Complexes Supported by a Redox-Active Ligand with Fused Pincer-Type Coordination Sites Wang, Denan; Lindeman, Sergey V.; Fiedler, Adam T. Inorganic Chemistry, Vol. 54, Issue 17 https://doi.org/10.1021/acs.inorgchem.5b01380	journal	August 2015
Reactivity of Proton Sources with a Nickel Hydride Complex in Acetonitrile: Implications for the Study of Fuel-Forming Catalysts Rountree, Eric S.; Dempsey, Jillian L. Inorganic Chemistry, Vol. 55, Issue 10 https://doi.org/10.1021/acs.inorgchem.6b00885	journal	May 2016
Iron Polypyridyl Complexes for Photocatalytic Hydrogen Generation Hartley, Carolyn L.; DiRisio, Ryan J.; Screen, Megan E. Inorganic Chemistry, Vol. 55, Issue 17 https://doi.org/10.1021/acs.inorgchem.6b01413	journal	August 2016
Decoding Proton-Coupled Electron Transfer with Potential–p K _a Diagrams McCarthy, Brian D.; Dempsey, Jillian L. Inorganic Chemistry, Vol. 56, Issue 3 https://doi.org/10.1021/acs.inorgchem.6b02325	journal	January 2017
Light-Induced H ₂ Evolution with a Macrocyclic Cobalt Diketo-Pyrphyrin as a Proton-Reducing Catalyst Joliat-Wick, Evelyne; Weder, Nicola; Klose, Daniel Inorganic Chemistry, Vol. 57, Issue 3 https://doi.org/10.1021/acs.inorgchem.7b02992	journal	January 2018
Mechanistic Insights into Homogeneous Electrocatalytic and Photocatalytic Hydrogen Evolution Catalyzed by High-Spin Ni(II) Complexes with S ₂ N ₂ -Type Tetradentate Ligands Hong, Dachao; Tsukakoshi, Yuto; Kotani, Hiroaki Inorganic Chemistry, Vol. 57, Issue 12 https://doi.org/10.1021/acs.inorgchem.8b00881	journal	May 2018
Mechanistic Role of Two-State Reactivity in a Molecular MoS ₂ Edge-Site Analogue for Hydrogen Evolution Electrocatalysis Schaugaard, Richard; Jarrold, Caroline Chick; Raghavachari, Krishnan Inorganic Chemistry, Vol. 57, Issue 15 https://doi.org/10.1021/acs.inorgchem.8b01184	journal	July 2018
Molecular Cobalt Catalysts for H ₂ Generation with Redox Activity and Proton Relays in the Second Coordination Sphere Kohler, Lars; Niklas, Jens; Johnson, Ryan C. Inorganic Chemistry, Vol. 58, Issue 2 https://doi.org/10.1021/acs.inorgchem.8b03297	journal	December 2018
Recent Development in Hydrogen Evolution Reaction Catalysts and Their Practical Implementation Vesborg, Peter C. K.; Seger, Brian; Chorkendorff, Ib The Journal of Physical Chemistry Letters, Vol. 6, Issue 6 https://doi.org/10.1021/acs.jpclett.5b00306	journal	March 2015
Reactivity and Mechanism Studies of Hydrogen Evolution Catalyzed by Copper Corroles Lei, Haitao; Fang, Huayi; Han, Yongzhen ACS Catalysis, Vol. 5, Issue 9 https://doi.org/10.1021/acscatal.5b00666	journal	August 2015
Linear Free Energy Relationships in the Hydrogen Evolution Reaction: Kinetic Analysis of a Cobaloxime Catalyst Rountree, Eric S.; Martin, Daniel J.; McCarthy, Brian D. ACS Catalysis, Vol. 6, Issue 5 https://doi.org/10.1021/acscatal.6b00667	journal	April 2016
Elucidating the Key Role of pH on Light-Driven Hydrogen Evolution by a Molecular Cobalt Catalyst Natali, Mirco ACS Catalysis, Vol. 7, Issue 2 https://doi.org/10.1021/acscatal.6b03087	journal	January 2017
Hydrogen Evolution Catalysis by a Sparsely Substituted Cobalt Chlorin Maher, Andrew G.; Passard, Guillaume; Dogutan, Dilek K. ACS Catalysis, Vol. 7, Issue 5 https://doi.org/10.1021/acscatal.7b00969	journal	April 2017
Hydricity of Transition-Metal Hydrides: Thermodynamic Considerations for CO ₂ Reduction Waldie, Kate M.; Ostericher, Andrew L.; Reineke, Mark H. ACS Catalysis, Vol. 8, Issue 2 https://doi.org/10.1021/acscatal.7b03396	journal	January 2018
Challenging the [Ru(bpy) ₃ ] ²⁺ Photosensitizer with a Triazatriangulenium Robust Organic Dye for Visible-Light-Driven Hydrogen Production in Water Gueret, Robin; Poulard, Laurélie; Oshinowo, Matthew ACS Catalysis, Vol. 8, Issue 5 https://doi.org/10.1021/acscatal.7b04000	journal	March 2018
Tuning Reactivity of Bioinspired [NiFe]-Hydrogenase Models by Ligand Design and Modeling the CO Inhibition Process Brazzolotto, Deborah; Wang, Lianke; Tang, Hao ACS Catalysis, Vol. 8, Issue 11 https://doi.org/10.1021/acscatal.8b02830	journal	September 2018
Interpreting the Electrocatalytic Voltammetry of Homogeneous Catalysts by the Foot of the Wave Analysis and Its Wider Implications Wang, Vincent C. -C.; Johnson, Ben A. ACS Catalysis, Vol. 9, Issue 8 https://doi.org/10.1021/acscatal.9b00850	journal	June 2019
Fuel from Water: The Photochemical Generation of Hydrogen from Water Han, Zhiji; Eisenberg, Richard Accounts of Chemical Research, Vol. 47, Issue 8 https://doi.org/10.1021/ar5001605	journal	June 2014
Hydrogen Evolution Catalyzed by Cobaloximes Dempsey, Jillian L.; Brunschwig, Bruce S.; Winkler, Jay R. Accounts of Chemical Research, Vol. 42, Issue 12 https://doi.org/10.1021/ar900253e	journal	December 2009
Proton-Coupled Electron Transfer Huynh, My Hang V.; Meyer, Thomas J. Chemical Reviews, Vol. 107, Issue 11 https://doi.org/10.1021/cr0500030	journal	November 2007
Hydrogen Production by Molecular Photocatalysis Esswein, Arthur J.; Nocera, Daniel G. Chemical Reviews, Vol. 107, Issue 10 https://doi.org/10.1021/cr050193e	journal	October 2007
Occurrence, Classification, and Biological Function of Hydrogenases: An Overview Vignais, Paulette M.; Billoud, Bernard Chemical Reviews, Vol. 107, Issue 10, p. 4206-4272 https://doi.org/10.1021/cr050196r	journal	October 2007
Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects Savéant, Jean-Michel Chemical Reviews, Vol. 108, Issue 7, p. 2348-2378 https://doi.org/10.1021/cr068079z	journal	July 2008
Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications Warren, Jeffrey J.; Tronic, Tristan A.; Mayer, James M. Chemical Reviews, Vol. 110, Issue 12 https://doi.org/10.1021/cr100085k	journal	December 2010
Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis Prier, Christopher K.; Rankic, Danica A.; MacMillan, David W. C. Chemical Reviews, Vol. 113, Issue 7 https://doi.org/10.1021/cr300503r	journal	March 2013
Hydrogenases Lubitz, Wolfgang; Ogata, Hideaki; Rüdiger, Olaf Chemical Reviews, Vol. 114, Issue 8 https://doi.org/10.1021/cr4005814	journal	March 2014
Deactivation in Homogeneous Transition Metal Catalysis: Causes, Avoidance, and Cure Crabtree, Robert H. Chemical Reviews, Vol. 115, Issue 1 https://doi.org/10.1021/cr5004375	journal	November 2014
Structural and Functional Analogues of the Active Sites of the [Fe]-, [NiFe]-, and [FeFe]-Hydrogenases ^† Tard, Cédric; Pickett, Christopher J. Chemical Reviews, Vol. 109, Issue 6 https://doi.org/10.1021/cr800542q	journal	June 2009
Chemical Redox Agents for Organometallic Chemistry Connelly, Neil G.; Geiger, William E. Chemical Reviews, Vol. 96, Issue 2 https://doi.org/10.1021/cr940053x	journal	January 1996
Determining the Overpotential for a Molecular Electrocatalyst Appel, Aaron M.; Helm, Monte L. ACS Catalysis, Vol. 4, Issue 2 https://doi.org/10.1021/cs401013v	journal	December 2013
Catalyzing the Hydrogen Evolution Reaction (HER) with Molybdenum Sulfide Nanomaterials Benck, Jesse D.; Hellstern, Thomas R.; Kibsgaard, Jakob ACS Catalysis, Vol. 4, Issue 11 https://doi.org/10.1021/cs500923c	journal	October 2014
High-Efficiency Electrochemical Hydrogen Evolution Catalyzed by Tungsten Phosphide Submicroparticles Xing, Zhicai; Liu, Qian; Asiri, Abdullah M. ACS Catalysis, Vol. 5, Issue 1 https://doi.org/10.1021/cs5014943	journal	November 2014
Tetragonal vs. trigonal coordination in copper(II) complexes with tripod ligands: structures and properties of [Cu(C21H24N4)Cl]PF6 and [Cu(C18H18N4)Cl]PF6 Karlin, Kenneth D.; Hayes, Jon C.; Juen, Shi. Inorganic Chemistry, Vol. 21, Issue 11 https://doi.org/10.1021/ic00141a049	journal	November 1982
Cobalt-catalyzed evolution of molecular hydrogen Connolly, Philip; Espenson, James H. Inorganic Chemistry, Vol. 25, Issue 16 https://doi.org/10.1021/ic00236a006	journal	July 1986
Electrocatalytic properties of (tetraazacyclotetradecane)nickel(2+) and Ni2(biscyclam)4+ with respect to carbon dioxide and water reduction Collin, Jean Paul; Jouaiti, Abdelaziz; Sauvage, Jean Pierre Inorganic Chemistry, Vol. 27, Issue 11 https://doi.org/10.1021/ic00284a030	journal	June 1988
A Periodic Walk: A Series of First-Row Transition Metal Complexes with the Pentadentate Ligand PY5 ^† Klein Gebbink, Robertus J. M.; Jonas, Robert T.; Goldsmith, Christian R. Inorganic Chemistry, Vol. 41, Issue 18 https://doi.org/10.1021/ic025617r	journal	September 2002
Proton Electroreduction Catalyzed by Cobaloximes: Functional Models for Hydrogenases Razavet, Mathieu; Artero, Vincent; Fontecave, Marc Inorganic Chemistry, Vol. 44, Issue 13 https://doi.org/10.1021/ic050167z	journal	June 2005
Cobaloximes as Functional Models for Hydrogenases. 2. Proton Electroreduction Catalyzed by Difluoroborylbis(dimethylglyoximato)cobalt(II) Complexes in Organic Media Baffert, Carole; Artero, Vincent; Fontecave, Marc Inorganic Chemistry, Vol. 46, Issue 5 https://doi.org/10.1021/ic061625m	journal	March 2007
Reversible Apical Coordination of Imidazole between the Ni(III) and Ni(II) Oxidation States of a Dithiolate Complex: A Process Related to the Ni Superoxide Dismutase Gennari, Marcello; Orio, Maylis; Pécaut, Jacques Inorganic Chemistry, Vol. 49, Issue 14 https://doi.org/10.1021/ic100945n	journal	July 2010
H ₂ Evolution and Molecular Electrocatalysts: Determination of Overpotentials and Effect of Homoconjugation Fourmond, Vincent; Jacques, Pierre-André; Fontecave, Marc Inorganic Chemistry, Vol. 49, Issue 22 https://doi.org/10.1021/ic101187v	journal	November 2010
First-Row Transition Metal Complexes of the Strongly Donating Pentadentate Ligand PY4Im Smith, Jeremy M.; Long, Jeffrey R. Inorganic Chemistry, Vol. 49, Issue 23 https://doi.org/10.1021/ic1018407	journal	December 2010
Influence of Mixed Thiolate/Thioether versus Dithiolate Coordination on the Accessibility of the Uncommon +I and +III Oxidation States for the Nickel Ion: An Experimental and Computational Study Gennari, Marcello; Orio, Maylis; Pécaut, Jacques Inorganic Chemistry, Vol. 50, Issue 8 https://doi.org/10.1021/ic200063d	journal	April 2011
Water Oxidation Catalysis: Influence of Anionic Ligands upon the Redox Properties and Catalytic Performance of Mononuclear Ruthenium Complexes Tong, Lianpeng; Wang, Ying; Duan, Lele Inorganic Chemistry, Vol. 51, Issue 6 https://doi.org/10.1021/ic201348u	journal	February 2012
Preface: Forum on Redox-Active Ligands Chirik, Paul J. Inorganic Chemistry, Vol. 50, Issue 20 https://doi.org/10.1021/ic201881k	journal	October 2011
Mechanistic Details for Cobalt Catalyzed Photochemical Hydrogen Production in Aqueous Solution: Efficiencies of the Photochemical and Non-Photochemical Steps Shan, Bing; Baine, Teera; Ma, Xuan Anh N. Inorganic Chemistry, Vol. 52, Issue 9 https://doi.org/10.1021/ic302381w	journal	April 2013
Direct Determination of Equilibrium Potentials for Hydrogen Oxidation/Production by Open Circuit Potential Measurements in Acetonitrile Roberts, John A. S.; Bullock, R. Morris Inorganic Chemistry, Vol. 52, Issue 7 https://doi.org/10.1021/ic302461q	journal	June 2012
Cobalt Corrole Catalyst for Efficient Hydrogen Evolution Reaction from H ₂ O under Ambient Conditions: Reactivity, Spectroscopy, and Density Functional Theory Calculations Mondal, Biswajit; Sengupta, Kushal; Rana, Atanu Inorganic Chemistry, Vol. 52, Issue 6 https://doi.org/10.1021/ic4000473	journal	February 2013
3d Element Complexes of Pentadentate Bipyridine-Pyridine-Based Ligand Scaffolds: Structures and Photocatalytic Activities Bachmann, Cyril; Guttentag, Miguel; Spingler, Bernhard Inorganic Chemistry, Vol. 52, Issue 10 https://doi.org/10.1021/ic4004017	journal	April 2013
Development of Molecular Electrocatalysts for Energy Storage DuBois, Daniel L. Inorganic Chemistry, Vol. 53, Issue 8 https://doi.org/10.1021/ic4026969	journal	February 2014
Hydrogen Evolution Catalyzed by an Iron Polypyridyl Complex in Aqueous Solutions Connor, G. P.; Mayer, K. J.; Tribble, C. S. Inorganic Chemistry, Vol. 53, Issue 11 https://doi.org/10.1021/ic500069c	journal	May 2014
Electrocatalytic Proton Reduction by a Dicobalt Tetrakis-Schiff Base Macrocycle in Nonaqueous Electrolyte Kal, Subhadeep; Filatov, Alexander S.; Dinolfo, Peter H. Inorganic Chemistry, Vol. 53, Issue 14 https://doi.org/10.1021/ic500121f	journal	June 2014
Proton-Coupled Electron Transfer in Molecular Electrocatalysis: Theoretical Methods and Design Principles Solis, Brian H.; Hammes-Schiffer, Sharon Inorganic Chemistry, Vol. 53, Issue 13 https://doi.org/10.1021/ic5002896	journal	April 2014
Evaluation of Homogeneous Electrocatalysts by Cyclic Voltammetry Rountree, Eric S.; McCarthy, Brian D.; Eisenhart, Thomas T. Inorganic Chemistry, Vol. 53, Issue 19 https://doi.org/10.1021/ic500658x	journal	September 2014
Electrochemical Reduction of Brønsted Acids by Glassy Carbon in Acetonitrile—Implications for Electrocatalytic Hydrogen Evolution McCarthy, Brian D.; Martin, Daniel J.; Rountree, Eric S. Inorganic Chemistry, Vol. 53, Issue 16 https://doi.org/10.1021/ic500770k	journal	July 2014
Electronic Effects on a Mononuclear Co Complex with a Pentadentate Ligand for Catalytic H ₂ Evolution Vennampalli, Manohar; Liang, Guangchao; Katta, Lakshmi Inorganic Chemistry, Vol. 53, Issue 19 https://doi.org/10.1021/ic500840e	journal	September 2014
Catalysis of Proton Reduction by a [BO ₄ ]-Bridged Dicobalt Glyoxime Laga, Stephanie M.; Blakemore, James D.; Henling, Lawrence M. Inorganic Chemistry, Vol. 53, Issue 24 https://doi.org/10.1021/ic501804h	journal	November 2014
Mechanism of Photocatalytic Hydrogen Generation by a Polypyridyl-Based Cobalt Catalyst in Aqueous Solution Rodenberg, Alexander; Orazietti, Margherita; Probst, Benjamin Inorganic Chemistry, Vol. 54, Issue 2 https://doi.org/10.1021/ic502591a	journal	December 2014
Sulfinato Iron(III) Complex for Electrocatalytic Proton Reduction Cavell, Andrew C.; Hartley, Carolyn L.; Liu, Dan Inorganic Chemistry, Vol. 54, Issue 7 https://doi.org/10.1021/ic5030394	journal	March 2015
Mechanistic Studies of Hydrogen Evolution in Aqueous Solution Catalyzed by a Tertpyridine–Amine Cobalt Complex Lewandowska-Andralojc, Anna; Baine, Teera; Zhao, Xuan Inorganic Chemistry, Vol. 54, Issue 9 https://doi.org/10.1021/ic5031137	journal	April 2015
Ru(II) Complexes of Tetradentate Ligands Related to 2,9-Di(pyrid-2‘-yl)-1,10-phenanthroline Zhang, Gang; Zong, Ruifa; Tseng, Huan-Wei Inorganic Chemistry, Vol. 47, Issue 3 https://doi.org/10.1021/ic701798v	journal	February 2008
Visible Light-Driven Hydrogen Production from Aqueous Protons Catalyzed by Molecular Cobaloxime Catalysts Du, Pingwu; Schneider, Jacob; Luo, Genggeng Inorganic Chemistry, Vol. 48, Issue 11 https://doi.org/10.1021/ic900389z	journal	June 2009
Homogeneous catalysis of the photoreduction of water. 6. Mediation by polypyridine complexes of ruthenium(II) and cobalt(II) in alkaline media Krishnan, C. V.; Brunschwig, Bruce S.; Creutz, Carol Journal of the American Chemical Society, Vol. 107, Issue 7 https://doi.org/10.1021/ja00293a035	journal	April 1985
Homogeneous catalysis of the photoreduction of water by visible light. 2. Mediation by a tris(2,2'-bipyridine)ruthenium(II)-cobalt(II) bipyridine system Krishnan, C. V.; Sutin, Norman Journal of the American Chemical Society, Vol. 103, Issue 8 https://doi.org/10.1021/ja00398a066	journal	April 1981
Electrocatalytic reduction of carbon dioxide by using macrocycles of nickel and cobalt Fisher, Barbara J.; Eisenberg, Richard Journal of the American Chemical Society, Vol. 102, Issue 24, p. 7361-7363 https://doi.org/10.1021/ja00544a035	journal	September 1980
Reevaluation of the formation constants of the hydrated proton in acetonitrile Chantooni, Miran K.; Kolthoff, Izaak M. Journal of the American Chemical Society, Vol. 92, Issue 8 https://doi.org/10.1021/ja00711a007	journal	April 1970
Electrochemical oxidation of tertiary amines. Effect of structure upon reversibility Nelsen, S. F.; Hintz, P. J. Journal of the American Chemical Society, Vol. 94, Issue 20 https://doi.org/10.1021/ja00775a041	journal	October 1972
Theory of Catalytic Polarographic Currents Delahay, Paul; Stiehl, George L. Journal of the American Chemical Society, Vol. 74, Issue 14 https://doi.org/10.1021/ja01134a014	journal	July 1952
Discovery and High-Throughput Screening of Heteroleptic Iridium Complexes for Photoinduced Hydrogen Production Goldsmith, Jonas I.; Hudson, William R.; Lowry, Michael S. Journal of the American Chemical Society, Vol. 127, Issue 20 https://doi.org/10.1021/ja0427101	journal	May 2005
2,9-Di-(2‘-pyridyl)-1,10-phenanthroline: A Tetradentate Ligand for Ru(II) Zong, Ruifa; Thummel, Randolph P. Journal of the American Chemical Society, Vol. 126, Issue 35 https://doi.org/10.1021/ja047410y	journal	September 2004
Biomimetic Hydrogen Evolution: MoS ₂ Nanoparticles as Catalyst for Hydrogen Evolution Hinnemann, Berit; Moses, Poul Georg; Bonde, Jacob Journal of the American Chemical Society, Vol. 127, Issue 15 https://doi.org/10.1021/ja0504690	journal	April 2005
Electrocatalytic Hydrogen Evolution at Low Overpotentials by Cobalt Macrocyclic Glyoxime and Tetraimine Complexes Hu, Xile; Brunschwig, Bruce S.; Peters, Jonas C. Journal of the American Chemical Society, Vol. 129, Issue 29 https://doi.org/10.1021/ja067876b	journal	July 2007
A Redox-Switchable Single-Molecule Magnet Incorporating [Re(CN) ₇ ] ^3- Freedman, Danna E.; Jenkins, David M.; Iavarone, Anthony T. Journal of the American Chemical Society, Vol. 130, Issue 10 https://doi.org/10.1021/ja077527x	journal	March 2008
Hydrogen Generation by Hangman Metalloporphyrins Lee, Chang Hoon; Dogutan, Dilek K.; Nocera, Daniel G. Journal of the American Chemical Society, Vol. 133, Issue 23 https://doi.org/10.1021/ja202136y	journal	June 2011
Molecular Cobalt Pentapyridine Catalysts for Generating Hydrogen from Water Sun, Yujie; Bigi, Julian P.; Piro, Nicholas A. Journal of the American Chemical Society, Vol. 133, Issue 24 https://doi.org/10.1021/ja202743r	journal	June 2011
Catalytic Turnover of [FeFe]-Hydrogenase Based on Single-Molecule Imaging Madden, Christopher; Vaughn, Michael D.; Díez-Pérez, Ismael Journal of the American Chemical Society, Vol. 134, Issue 3 https://doi.org/10.1021/ja207461t	journal	October 2011
Electrocatalytic Hydrogen Evolution in Acidic Water with Molecular Cobalt Tetraazamacrocycles McCrory, Charles C. L.; Uyeda, Christopher; Peters, Jonas C. Journal of the American Chemical Society, Vol. 134, Issue 6 https://doi.org/10.1021/ja210661k	journal	February 2012
Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis Costentin, Cyrille; Drouet, Samuel; Robert, Marc Journal of the American Chemical Society, Vol. 134, Issue 27, p. 11235-11242 https://doi.org/10.1021/ja303560c	journal	June 2012
Catalytic Four-Electron Reduction of O ₂ via Rate-Determining Proton-Coupled Electron Transfer to a Dinuclear Cobalt-μ-1,2-peroxo Complex Fukuzumi, Shunichi; Mandal, Sukanta; Mase, Kentaro Journal of the American Chemical Society, Vol. 134, Issue 24 https://doi.org/10.1021/ja303674n	journal	June 2012
Synthetic Models for the Active Site of the [FeFe]-Hydrogenase: Catalytic Proton Reduction and the Structure of the Doubly Protonated Intermediate Carroll, Maria E.; Barton, Bryan E.; Rauchfuss, Thomas B. Journal of the American Chemical Society, Vol. 134, Issue 45 https://doi.org/10.1021/ja309216v	journal	November 2012
Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction Popczun, Eric J.; McKone, James R.; Read, Carlos G. Journal of the American Chemical Society, Vol. 135, Issue 25 https://doi.org/10.1021/ja403440e	journal	June 2013
Robust Cuprous Phenanthroline Sensitizer for Solar Hydrogen Photocatalysis Khnayzer, Rony S.; McCusker, Catherine E.; Olaiya, Babatunde S. Journal of the American Chemical Society, Vol. 135, Issue 38 https://doi.org/10.1021/ja407816f	journal	September 2013
Protonation Equilibrium and Hydrogen Production by a Dinuclear Cobalt–Hydride Complex Reduced by Cobaltocene with Trifluoroacetic Acid Mandal, Sukanta; Shikano, Shinya; Yamada, Yusuke Journal of the American Chemical Society, Vol. 135, Issue 41 https://doi.org/10.1021/ja408080z	journal	October 2013
Manganese Catalysts with Bulky Bipyridine Ligands for the Electrocatalytic Reduction of Carbon Dioxide: Eliminating Dimerization and Altering Catalysis Sampson, Matthew D.; Nguyen, An D.; Grice, Kyle A. Journal of the American Chemical Society, Vol. 136, Issue 14 https://doi.org/10.1021/ja501252f	journal	February 2014
Visible Light-Driven Hydrogen Evolution from Water Catalyzed by A Molecular Cobalt Complex Tong, Lianpeng; Zong, Ruifa; Thummel, Randolph P. Journal of the American Chemical Society, Vol. 136, Issue 13 https://doi.org/10.1021/ja501257d	journal	March 2014
Molecular Catalysis of H ₂ Evolution: Diagnosing Heterolytic versus Homolytic Pathways Costentin, Cyrille; Dridi, Hachem; Savéant, Jean-Michel Journal of the American Chemical Society, Vol. 136, Issue 39 https://doi.org/10.1021/ja505845t	journal	September 2014
Evidence from in Situ X-ray Absorption Spectroscopy for the Involvement of Terminal Disulfide in the Reduction of Protons by an Amorphous Molybdenum Sulfide Electrocatalyst Lassalle-Kaiser, Benedikt; Merki, Daniel; Vrubel, Heron Journal of the American Chemical Society, Vol. 137, Issue 1 https://doi.org/10.1021/ja510328m	journal	December 2014
Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices McCrory, Charles C. L.; Jung, Suho; Ferrer, Ivonne M. Journal of the American Chemical Society, Vol. 137, Issue 13 https://doi.org/10.1021/ja510442p	journal	March 2015
Homogeneous Catalysis of Electrochemical Hydrogen Evolution by Iron(0) Porphyrins Bhugun, Iqbal; Lexa, Doris; Savéant, Jean-Michel Journal of the American Chemical Society, Vol. 118, Issue 16 https://doi.org/10.1021/ja954326x	journal	January 1996
C−H Bond Activation by a Ferric Methoxide Complex: A Model for the Rate-Determining Step in the Mechanism of Lipoxygenase Jonas, Robert T.; Stack, T. D. P. Journal of the American Chemical Society, Vol. 119, Issue 36 https://doi.org/10.1021/ja971503g	journal	September 1997
The Cobalt Hydride that Never Was: Revisiting Schrauzer’s “Hydridocobaloxime” Lacy, David C.; Roberts, Gerri M.; Peters, Jonas C. Journal of the American Chemical Society, Vol. 137, Issue 14 https://doi.org/10.1021/jacs.5b01838	journal	April 2015
Potential-Dependent Electrocatalytic Pathways: Controlling Reactivity with p K _a for Mechanistic Investigation of a Nickel-Based Hydrogen Evolution Catalyst Rountree, Eric S.; Dempsey, Jillian L. Journal of the American Chemical Society, Vol. 137, Issue 41 https://doi.org/10.1021/jacs.5b08297	journal	October 2015
Manganese Electrocatalysts with Bulky Bipyridine Ligands: Utilizing Lewis Acids To Promote Carbon Dioxide Reduction at Low Overpotentials Sampson, Matthew D.; Kubiak, Clifford P. Journal of the American Chemical Society, Vol. 138, Issue 4 https://doi.org/10.1021/jacs.5b12215	journal	January 2016
Insight into the Iron–Molybdenum Cofactor of Nitrogenase from Synthetic Iron Complexes with Sulfur, Carbon, and Hydride Ligands Čorić, Ilija; Holland, Patrick L. Journal of the American Chemical Society, Vol. 138, Issue 23 https://doi.org/10.1021/jacs.6b00747	journal	June 2016
Reaction Parameters Influencing Cobalt Hydride Formation Kinetics: Implications for Benchmarking H ₂ -Evolution Catalysts Elgrishi, Noémie; Kurtz, Daniel A.; Dempsey, Jillian L. Journal of the American Chemical Society, Vol. 139, Issue 1 https://doi.org/10.1021/jacs.6b10148	journal	December 2016
Visible-Light-Driven Photocatalytic CO ₂ Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production Hong, Dachao; Tsukakoshi, Yuto; Kotani, Hiroaki Journal of the American Chemical Society, Vol. 139, Issue 19 https://doi.org/10.1021/jacs.7b01956	journal	May 2017
Homogeneous Molecular Catalysis of Electrochemical Reactions: Catalyst Benchmarking and Optimization Strategies Costentin, Cyrille; Savéant, Jean-Michel Journal of the American Chemical Society, Vol. 139, Issue 24 https://doi.org/10.1021/jacs.7b02879	journal	June 2017
Operando Spectroscopic Analysis of CoP Films Electrocatalyzing the Hydrogen-Evolution Reaction Saadi, Fadl H.; Carim, Azhar I.; Drisdell, Walter S. Journal of the American Chemical Society, Vol. 139, Issue 37 https://doi.org/10.1021/jacs.7b07606	journal	September 2017
Electronic and Steric Tuning of Catalytic H ₂ Evolution by Cobalt Complexes with Pentadentate Polypyridyl-Amine Ligands Wang, Ping; Liang, Guangchao; Reddy, M. Ramana Journal of the American Chemical Society, Vol. 140, Issue 29 https://doi.org/10.1021/jacs.8b05108	journal	June 2018
Isolation and oxidation-reduction of methylviologen cation radicals. Novel disproportionation in charge-transfer salts by x-ray crystallography Bockman, T. M.; Kochi, J. K. The Journal of Organic Chemistry, Vol. 55, Issue 13, p. 4127-4135 https://doi.org/10.1021/jo00300a033	journal	June 1990
Extension of the Self-Consistent Spectrophotometric Basicity Scale in Acetonitrile to a Full Span of 28 p K _a Units: Unification of Different Basicity Scales Kaljurand, Ivari; Kütt, Agnes; Sooväli, Lilli The Journal of Organic Chemistry, Vol. 70, Issue 3 https://doi.org/10.1021/jo048252w	journal	February 2005
Synthetic Approaches to Polypyridyl Bridging Ligands with Proximal Multidentate Binding Sites Zong, Ruifa; Wang, Dong; Hammitt, Richard The Journal of Organic Chemistry, Vol. 71, Issue 1 https://doi.org/10.1021/jo051937r	journal	January 2006
A Comprehensive Self-Consistent Spectrophotometric Acidity Scale of Neutral Brønsted Acids in Acetonitrile Kütt, Agnes; Leito, Ivo; Kaljurand, Ivari The Journal of Organic Chemistry, Vol. 71, Issue 7 https://doi.org/10.1021/jo060031y	journal	March 2006
Pentakis(trifluoromethyl)phenyl, a Sterically Crowded and Electron-withdrawing Group: Synthesis and Acidity of Pentakis(trifluoromethyl)benzene, -toluene, -phenol, and -aniline Kütt, Agnes; Movchun, Valeria; Rodima, Toomas The Journal of Organic Chemistry, Vol. 73, Issue 7 https://doi.org/10.1021/jo702513w	journal	April 2008
Determination of the Quantum Yield for the Photochemical Generation of Hydroxyl Radicals in TiO ₂ Suspensions Sun, Lizhong; Bolton, James R. The Journal of Physical Chemistry, Vol. 100, Issue 10 https://doi.org/10.1021/jp9505800	journal	January 1996
Crystal structure of the nickel–iron hydrogenase from Desulfovibrio gigas Volbeda, Anne; Charon, Marie-Hélène; Piras, Claudine Nature, Vol. 373, Issue 6515 https://doi.org/10.1038/373580a0	journal	February 1995
A molecular molybdenum-oxo catalyst for generating hydrogen from water Karunadasa, Hemamala I.; Chang, Christopher J.; Long, Jeffrey R. Nature, Vol. 464, Issue 7293 https://doi.org/10.1038/nature08969	journal	April 2010
The crystal structure of an oxygen-tolerant hydrogenase uncovers a novel iron-sulphur centre Fritsch, Johannes; Scheerer, Patrick; Frielingsdorf, Stefan Nature, Vol. 479, Issue 7372 https://doi.org/10.1038/nature10505	journal	October 2011
Biomimetic assembly and activation of [FeFe]-hydrogenases Berggren, G.; Adamska, A.; Lambertz, C. Nature, Vol. 499, Issue 7456 https://doi.org/10.1038/nature12239	journal	June 2013
Hydrogens detected by subatomic resolution protein crystallography in a [NiFe] hydrogenase Ogata, Hideaki; Nishikawa, Koji; Lubitz, Wolfgang Nature, Vol. 520, Issue 7548 https://doi.org/10.1038/nature14110	journal	January 2015
An iron complex with pendent amines as a molecular electrocatalyst for oxidation of hydrogen Liu, Tianbiao; DuBois, Daniel L.; Bullock, R. Morris Nature Chemistry, Vol. 5, Issue 3 https://doi.org/10.1038/nchem.1571	journal	February 2013
Nickel-centred proton reduction catalysis in a model of [NiFe] hydrogenase Brazzolotto, Deborah; Gennari, Marcello; Queyriaux, Nicolas Nature Chemistry, Vol. 8, Issue 11 https://doi.org/10.1038/nchem.2575	journal	July 2016
Structural and functional synthetic model of mono-iron hydrogenase featuring an anthracene scaffold Seo, Junhyeok; Manes, Taylor A.; Rose, Michael J. Nature Chemistry, Vol. 9, Issue 6 https://doi.org/10.1038/nchem.2707	journal	January 2017
Hydrogen evolution by a metal-free electrocatalyst Zheng, Yao; Jiao, Yan; Zhu, Yihan Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4783	journal	April 2014
Highly porous non-precious bimetallic electrocatalysts for efficient hydrogen evolution Lu, Qi; Hutchings, Gregory S.; Yu, Weiting Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7567	journal	March 2015
A metal-free polymeric photocatalyst for hydrogen production from water under visible light Wang, Xinchen; Maeda, Kazuhiko; Thomas, Arne Nature Materials, Vol. 8, Issue 1 https://doi.org/10.1038/nmat2317	journal	November 2008
Materials for solar fuels and chemicals Montoya, Joseph H.; Seitz, Linsey C.; Chakthranont, Pongkarn Nature Materials, Vol. 16, Issue 1 https://doi.org/10.1038/nmat4778	journal	December 2016
Electrochemical and spectroscopic methods for evaluating molecular electrocatalysts Lee, Katherine J.; Elgrishi, Noémie; Kandemir, Banu Nature Reviews Chemistry, Vol. 1, Issue 5 https://doi.org/10.1038/s41570-017-0039	journal	May 2017
General synthesis and definitive structural identification of MN4C4 single-atom catalysts with tunable electrocatalytic activities Fei, Huilong; Dong, Juncai; Feng, Yexin Nature Catalysis, Vol. 1, Issue 1 https://doi.org/10.1038/s41929-017-0008-y	journal	January 2018
Bridging homogeneous and heterogeneous catalysis by heterogeneous single-metal-site catalysts Cui, Xinjiang; Li, Wu; Ryabchuk, Pavel Nature Catalysis, Vol. 1, Issue 6 https://doi.org/10.1038/s41929-018-0090-9	journal	June 2018
Identification of single-atom active sites in carbon-based cobalt catalysts during electrocatalytic hydrogen evolution Cao, Linlin; Luo, Qiquan; Liu, Wei Nature Catalysis, Vol. 2, Issue 2 https://doi.org/10.1038/s41929-018-0203-5	journal	December 2018
Small molecule mimics of hydrogenases: hydrides and redox Gloaguen, Frédéric; Rauchfuss, Thomas B. Chem. Soc. Rev., Vol. 38, Issue 1 https://doi.org/10.1039/B801796B	journal	January 2009
Electrocatalytic reduction of protons to hydrogen by a water-compatible cobalt polypyridyl platform Bigi, Julian P.; Hanna, Tamara E.; Harman, W. Hill Chem. Commun., Vol. 46, Issue 6 https://doi.org/10.1039/B915846D	journal	January 2010
Homogeneous photocatalytic production of hydrogen from water by a bioinspired [Fe ₂ S ₂ ] catalyst with high turnover numbers Zhang, Pan; Wang, Mei; Na, Yong Dalton Trans., Vol. 39, Issue 5 https://doi.org/10.1039/B923159P	journal	January 2010
Redox-active ligands in catalysis Luca, Oana R.; Crabtree, Robert H. Chem. Soc. Rev., Vol. 42, Issue 4 https://doi.org/10.1039/C2CS35228A	journal	January 2013
Complexes of earth-abundant metals for catalytic electrochemical hydrogen generation under aqueous conditions Thoi, V. Sara; Sun, Yujie; Long, Jeffrey R. Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/C2CS35272A	journal	January 2013
A highly stable polypyridyl-based cobalt catalyst for homo- and heterogeneous photocatalytic water reduction Guttentag, Miguel; Rodenberg, Alexander; Bachmann, Cyril Dalton Trans., Vol. 42, Issue 2 https://doi.org/10.1039/C2DT31699D	journal	January 2013
Photocatalytic hydrogen production from a noble metal free system based on a water soluble porphyrin derivative and a cobaloxime catalyst Lazarides, Theodore; Delor, Milan; Sazanovich, Igor V. Chem. Commun., Vol. 50, Issue 5 https://doi.org/10.1039/C3CC45025B	journal	January 2014
Production of hydrogen by electrocatalysis: making the H–H bond by combining protons and hydrides Bullock, R. Morris; Appel, Aaron M.; Helm, Monte L. Chem. Commun., Vol. 50, Issue 24 https://doi.org/10.1039/C3CC46135A	journal	January 2014
The cobalt corrole catalyzed hydrogen evolution reaction: surprising electronic effects and characterization of key reaction intermediates Mahammed, Atif; Mondal, Biswajit; Rana, Atanu Chem. Commun., Vol. 50, Issue 21 https://doi.org/10.1039/C3CC48462A	journal	January 2014
Towards a comprehensive understanding of visible-light photogeneration of hydrogen from water using cobalt( ii ) polypyridyl catalysts Khnayzer, R. S.; Thoi, V. S.; Nippe, M. Energy Environ. Sci., Vol. 7, Issue 4 https://doi.org/10.1039/C3EE43982H	journal	January 2014
Earth-abundant hydrogen evolution electrocatalysts McKone, James R.; Marinescu, Smaranda C.; Brunschwig, Bruce S. Chem. Sci., Vol. 5, Issue 3 https://doi.org/10.1039/C3SC51711J	journal	January 2014
Ascorbate as an electron relay between an irreversible electron donor and Ru( ii ) or Re( i ) photosensitizers Bachmann, Cyril; Probst, Benjamin; Guttentag, Miguel Chem. Commun., Vol. 50, Issue 51 https://doi.org/10.1039/C4CC01500B	journal	January 2014
Photoinduced hydrogen evolution by a pentapyridine cobalt complex: elucidating some mechanistic aspects Deponti, Elisa; Luisa, Alessandra; Natali, Mirco Dalton Trans., Vol. 43, Issue 43 https://doi.org/10.1039/C4DT02269F	journal	January 2014
Toward the rational benchmarking of homogeneous H ₂ -evolving catalysts Artero, Vincent; Saveant, Jean-Michel Energy Environ. Sci., Vol. 7, Issue 11 https://doi.org/10.1039/C4EE01709A	journal	January 2014
Hydrogen photogeneration catalyzed by a cobalt complex of a pentadentate aminopyridine-based ligand Song, Xiaowei; Wen, Huimin; Ma, Chengbing New Journal of Chemistry, Vol. 39, Issue 3 https://doi.org/10.1039/C4NJ01858C	journal	January 2015
Molecular polypyridine-based metal complexes as catalysts for the reduction of CO ₂ Elgrishi, Noémie; Chambers, Matthew B.; Wang, Xia Chemical Society Reviews, Vol. 46, Issue 3 https://doi.org/10.1039/C5CS00391A	journal	January 2017
The mechanism of hydrogen evolution in Cu(bztpen)-catalysed water reduction: a DFT study Liao, Rong-Zhen; Wang, Mei; Sun, Licheng Dalton Transactions, Vol. 44, Issue 21 https://doi.org/10.1039/C5DT01008J	journal	January 2015
Cobalt complexes of tetradentate, bipyridine-based macrocycles: their structures, properties and photocatalytic proton reduction Joliat, E.; Schnidrig, S.; Probst, B. Dalton Transactions, Vol. 45, Issue 4 https://doi.org/10.1039/C5DT04426J	journal	January 2016
Photocatalytic hydrogen evolution by Cu( ii ) complexes Wang, Junfei; Li, Chao; Zhou, Qianxiong Dalton Transactions, Vol. 45, Issue 13 https://doi.org/10.1039/C5DT04628A	journal	January 2016
Bioinspired design of redox-active ligands for multielectron catalysis: effects of positioning pyrazine reservoirs on cobalt for electro- and photocatalytic generation of hydrogen from water Jurss, Jonah W.; Khnayzer, Rony S.; Panetier, Julien A. Chemical Science, Vol. 6, Issue 8 https://doi.org/10.1039/C5SC01414J	journal	January 2015
Efficient electro/photocatalytic water reduction using a [Ni ^II (N ₂ Py ₃ )] ²⁺ complex Kankanamalage, Pavithra H. A.; Mazumder, Shivnath; Tiwari, Vishwas Chemical Communications, Vol. 52, Issue 91 https://doi.org/10.1039/C6CC06629A	journal	January 2016
Hydride & dihydrogen complexes of earth abundant metals: structure, reactivity, and applications to catalysis Robinson, S. J. Connelly; Heinekey, D. M. Chemical Communications, Vol. 53, Issue 4 https://doi.org/10.1039/C6CC07529K	journal	January 2017
The photophysics of photoredox catalysis: a roadmap for catalyst design Arias-Rotondo, Daniela M.; McCusker, James K. Chemical Society Reviews, Vol. 45, Issue 21 https://doi.org/10.1039/C6CS00526H	journal	January 2016
Qualitative extension of the EC′ Zone Diagram to a molecular catalyst for a multi-electron, multi-substrate electrochemical reaction Martin, Daniel J.; McCarthy, Brian D.; Rountree, Eric S. Dalton Transactions, Vol. 45, Issue 24 https://doi.org/10.1039/C6DT00302H	journal	January 2016
Single-atom dispersed Co–N–C catalyst: structure identification and performance for hydrogenative coupling of nitroarenes Liu, Wengang; Zhang, Leilei; Yan, Wensheng Chemical Science, Vol. 7, Issue 9 https://doi.org/10.1039/C6SC02105K	journal	January 2016
A mechanism study on the hydrogen evolution reaction catalyzed by molybdenum disulfide complexes Yang, Ti-Long; Ni, Shao-Fei; Qin, Peng Chemical Communications, Vol. 54, Issue 9 https://doi.org/10.1039/C7CC08632F	journal	January 2018
Energy transfer catalysis mediated by visible light: principles, applications, directions Strieth-Kalthoff, Felix; James, Michael J.; Teders, Michael Chemical Society Reviews, Vol. 47, Issue 19 https://doi.org/10.1039/C8CS00054A	journal	January 2018
Electrocatalytic hydrogen evolution with gallium hydride and ligand-centered reduction Wang, Ni; Lei, Haitao; Zhang, Zongyao Chemical Science, Vol. 10, Issue 8 https://doi.org/10.1039/C8SC05247F	journal	January 2019
Interaction of palladium( II ) acetate with substituted pyridines, including a cyclometallation reaction and the structure of [Pd{meso-[(py)PhMeC] ₂ C ₅ H ₃ N}(O ₂ CMe)][O ₂ CMe]·3H ₂ O Canty, Allan J.; Minchin, Nigel J.; Skelton, Brian W. J. Chem. Soc., Dalton Trans., Issue 10 https://doi.org/10.1039/DT9860002205	journal	January 1986
Cobalt and nickel complexes of 2,2′ : 6′,2″ : 6″,2‴-quaterpyridine as catalysts for electrochemical reduction of carbon dioxide Lam, Kin-Ming; Wong, Kwok-Yin; Yang, San-Ming J. Chem. Soc., Dalton Trans., Issue 7 https://doi.org/10.1039/DT9950001103	journal	January 1995
Photochromic heterocyclic fulgides. Part 3. The use of (E)-α-(2,5-dimethyl-3-furylethylidene)(isopropylidene)succinic anhydride as a simple convenient chemical actinometer Heller, Harry G.; Langan, John R. J. Chem. Soc., Perkin Trans. 2, Issue 2 https://doi.org/10.1039/P29810000341	journal	January 1981
Evolution in the understanding of [Fe]-hydrogenase Corr, Michael J.; Murphy, John A. Chemical Society Reviews, Vol. 40, Issue 5 https://doi.org/10.1039/c0cs00150c	journal	January 2011
Molecular systems for light driven hydrogen production Eckenhoff, William T.; Eisenberg, Richard Dalton Transactions, Vol. 41, Issue 42 https://doi.org/10.1039/c2dt30823a	journal	January 2012
A cobalt(ii) quaterpyridine complex as a visible light-driven catalyst for both water oxidation and reduction Leung, Chi-Fai; Ng, Siu-Mui; Ko, Chi-Chiu Energy & Environmental Science, Vol. 5, Issue 7 https://doi.org/10.1039/c2ee21840b	journal	January 2012
A tridentate Ni pincer for aqueous electrocatalytic hydrogen production Luca, Oana R.; Konezny, Steven J.; Blakemore, James D. New Journal of Chemistry, Vol. 36, Issue 5 https://doi.org/10.1039/c2nj20912h	journal	January 2012
Electrocatalytic hydrogen evolution from neutral water by molecular cobalt tripyridine–diamine complexes Zhang, Peili; Wang, Mei; Gloaguen, Frederic Chemical Communications, Vol. 49, Issue 82 https://doi.org/10.1039/c3cc43491e	journal	January 2013
Recent developments in transition metal carbides and nitrides as hydrogen evolution electrocatalysts Chen, Wei-Fu; Muckerman, James T.; Fujita, Etsuko Chemical Communications, Vol. 49, Issue 79 https://doi.org/10.1039/c3cc44076a	journal	January 2013
Voltammetric and spectroscopic characterization of early intermediates in the Co(ii)–polypyridyl-catalyzed reduction of water Singh, Wangkheimayum Marjit; Mirmohades, Mohammad; Jane, Reuben T. Chemical Communications, Vol. 49, Issue 77 https://doi.org/10.1039/c3cc44655g	journal	January 2013
Reactions of [FeFe]-hydrogenase models involving the formation of hydrides related to proton reduction and hydrogen oxidation Wang, Ning; Wang, Mei; Chen, Lin Dalton Transactions, Vol. 42, Issue 34 https://doi.org/10.1039/c3dt51371h	journal	January 2013
A mechanistic study of proton reduction catalyzed by a pentapyridine cobalt complex: evidence for involvement of an anation-based pathway King, Amanda E.; Surendranath, Yogesh; Piro, Nicholas A. Chemical Science, Vol. 4, Issue 4 https://doi.org/10.1039/c3sc22239j	journal	January 2013
Catalytic proton reduction with transition metal complexes of the redox-active ligand bpy2PYMe Nippe, Michael; Khnayzer, Rony S.; Panetier, Julien A. Chemical Science, Vol. 4, Issue 10 https://doi.org/10.1039/c3sc51660a	journal	January 2013
An unexpected role of the monodentate ligand in photocatalytic hydrogen production of the pentadentate ligand-based cobalt complexes Xie, Jingfan; Zhou, Qianxiong; Li, Chao Chemical Communications, Vol. 50, Issue 49 https://doi.org/10.1039/c4cc01471e	journal	January 2014
Powering the planet: Chemical challenges in solar energy utilization Lewis, N. S.; Nocera, D. G. Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735 https://doi.org/10.1073/pnas.0603395103	journal	October 2006
Molecular mechanisms of cobalt-catalyzed hydrogen evolution Marinescu, S. C.; Winkler, J. R.; Gray, H. B. Proceedings of the National Academy of Sciences, Vol. 109, Issue 38 https://doi.org/10.1073/pnas.1213442109	journal	September 2012
Electro- and Photocatalytic Hydrogen Production by Molecular Cobalt Complexes With Pentadentate Ligands Zhao, Xuan; Wang, Ping; Long, Melissa Comments on Inorganic Chemistry, Vol. 37, Issue 5 https://doi.org/10.1080/02603594.2016.1266618	journal	September 2016
Photophysics of Halogenated Fluoresceins: Involvement of Both Intramolecular Electron Transfer and Heavy Atom Effect in the Deactivation of Excited States Zhang, Xian-Fu; Zhang, Iris; Liu, Lihong Photochemistry and Photobiology, Vol. 86, Issue 3 https://doi.org/10.1111/j.1751-1097.2010.00706.x	journal	March 2010
Artificial Photosynthesis: From Molecular Catalysts for Light-driven Water Splitting to Photoelectrochemical Cells Andreiadis, Eugen S.; Chavarot-Kerlidou, Murielle; Fontecave, Marc Photochemistry and Photobiology, Vol. 87, Issue 5 https://doi.org/10.1111/j.1751-1097.2011.00966.x	journal	August 2011
Identification of Active Edge Sites for Electrochemical H₂ Evolution from MoS₂ Nanocatalysts Jaramillo, T. F.; Jorgensen, K. P.; Bonde, J. Science, Vol. 317, Issue 5834, p. 100-102 https://doi.org/10.1126/science.1141483	journal	July 2007
The Crystal Structure of [Fe]-Hydrogenase Reveals the Geometry of the Active Site Shima, S.; Pilak, O.; Vogt, S. Science, Vol. 321, Issue 5888 https://doi.org/10.1126/science.1158978	journal	July 2008
A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s^-1 for H₂ Production Helm, M. L.; Stewart, M. P.; Bullock, R. M. Science, Vol. 333, Issue 6044, p. 863-866 https://doi.org/10.1126/science.1205864	journal	August 2011
Evidence for Interstitial Carbon in Nitrogenase FeMo Cofactor Spatzal, T.; Aksoyoglu, M.; Zhang, L. Science, Vol. 334, Issue 6058 https://doi.org/10.1126/science.1214025	journal	November 2011
A Molecular MoS2 Edge Site Mimic for Catalytic Hydrogen Generation Karunadasa, H. I.; Montalvo, E.; Sun, Y. Science, Vol. 335, Issue 6069 https://doi.org/10.1126/science.1215868	journal	February 2012
A Functional [NiFe]Hydrogenase Mimic That Catalyzes Electron and Hydride Transfer from H2 Ogo, S.; Ichikawa, K.; Kishima, T. Science, Vol. 339, Issue 6120 https://doi.org/10.1126/science.1231345	journal	February 2013
X-ray Crystal Structure of the Fe-Only Hydrogenase (CpI) from Clostridium pasteurianum to 1.8 Angstrom Resolution Peters, J. W. Science, Vol. 282, Issue 5395 https://doi.org/10.1126/science.282.5395.1853	journal	December 1998
Research opportunities to advance solar energy utilization Lewis, N. S. Science, Vol. 351, Issue 6271 https://doi.org/10.1126/science.aad1920	journal	January 2016
Glossary of terms used in photocatalysis and radiation catalysis (IUPAC Recommendations 2011) Braslavsky, Silvia E.; Braun, André M.; Cassano, Alberto E. Pure and Applied Chemistry, Vol. 83, Issue 4 https://doi.org/10.1351/PAC-REC-09-09-36	journal	March 2011
Light induced electron transfer reactions of metal complexes Sutin, N.; Creutz, C. Pure and Applied Chemistry, Vol. 52, Issue 12 https://doi.org/10.1351/pac198052122717	journal	January 1980

Similar Records

Mononuclear ruthenium polypyridine complexes that catalyze water oxidation

Journal Article · Thu Aug 04 20:00:00 EDT 2016 · Chemical Science · OSTI ID:1434583

Spectroscopic Characterisation of a Bio-Inspired Ni-Based Proton Reduction Catalyst Bearing a Pentadentate N₂S₃ Ligand with Improved Photocatalytic Activity

Journal Article · Mon Jan 20 19:00:00 EST 2020 · Chemistry - A European Journal · OSTI ID:1763722

Mechanistic aspects of CO₂ reduction catalysis with manganese-based molecular catalysts

Journal Article · Tue Jul 17 20:00:00 EDT 2018 · Coordination Chemistry Reviews · OSTI ID:1460701

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

First-row transition metal polypyridine complexes that catalyze proton to hydrogen reduction

Citation Formats

References (238)

Similar Records

Related Subjects