Chiral Four-Wave Mixing Signals with Circularly Polarized X-ray Pulses

Rouxel, Jérémy R.; Rajabi, Ahmadreza; Mukamel, Shaul

doi:10.1021/acs.jctc.0c00416

Chiral Four-Wave Mixing Signals with Circularly Polarized X-ray Pulses

Journal Article · Tue Jul 28 00:00:00 EDT 2020 · Journal of Chemical Theory and Computation

DOI:https://doi.org/10.1021/acs.jctc.0c00416· OSTI ID:1800154

^[1]; Rajabi, Ahmadreza ^[2]; ^[2]

Univ. of California, Irvine, CA (United States). Dept. of Chemistry. Dept. of Physics and Astronomy; OSTI
Univ. of California, Irvine, CA (United States). Dept. of Chemistry. Dept. of Physics and Astronomy

Chiral four-wave mixing signals are calculated using the irreducible tensor formalism. Different polarization and crossing angle configurations allow to single out the magnetic dipole and the electric quadrupole interactions. Other configurations can reveal that the chiral interaction occurs at a given step within the nonlinear interaction pathways. Applications are made to the study of valence excitations of S-ibuprofen by chiral stimulated X-ray Raman signals at the carbon K-edge and by chiral visible 2D electronic spectroscopy.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, Irvine, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-04ER15571

OSTI ID:: 1800154

Journal Information:: Journal of Chemical Theory and Computation, Journal Name: Journal of Chemical Theory and Computation Journal Issue: 9 Vol. 16; ISSN 1549-9618

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
X-rays
excited states
magnetic properties
molecular structure
polarization

Chiral Four-Wave Mixing Signals with Circularly Polarized X-ray Pulses

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