How Well Do Approximate Models of Adsorption-Based CO 2 Capture Processes Predict Results of Detailed Process Models?

Park, Jongwoo; Rubiera Landa, Héctor Octavio; Kawajiri, Yoshiaki; Realff, Matthew J.; Lively, Ryan P.; Sholl, David S.

doi:10.1021/acs.iecr.9b05363

How Well Do Approximate Models of Adsorption-Based CO ₂ Capture Processes Predict Results of Detailed Process Models?

Journal Article · Wed Dec 18 00:00:00 EST 2019 · Industrial and Engineering Chemistry Research

DOI:https://doi.org/10.1021/acs.iecr.9b05363· OSTI ID:1799845

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Georgia Inst. of Technology, Atlanta, GA (United States); OSTI
Georgia Inst. of Technology, Atlanta, GA (United States)
Georgia Inst. of Technology, Atlanta, GA (United States); Nagoya Univ. (Japan)

Appropriate selection of adsorbent materials is essential in developing adsorption-based processes such as CO₂ capture. Approximate methods to evaluate material candidates exist using adsorbent evaluation metrics or simplified process models. These approximate methods do not, of course, completely describe the performance of adsorbents in real separation processes. Here, we assess the correlations between approximate predictions and detailed process models of pressure swing adsorption (PSA) at subambient temperatures for postcombustion CO₂ capture using metal–organic frameworks (MOFs). Our research indicates that CO₂ swing capacity and adsorbent performance score are useful in predicting the ranking of materials for this process. These results illustrate the opportunities and challenges in bridging approximate and detailed methods for evaluating adsorbents for cyclic separations processes.

View Accepted Manuscript (DOE)

Research Organization:: Georgia Institute of Technology, Atlanta, GA (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE)

Grant/Contract Number:: FE0026433

OSTI ID:: 1799845

Journal Information:: Industrial and Engineering Chemistry Research, Journal Name: Industrial and Engineering Chemistry Research Journal Issue: 15 Vol. 59; ISSN 0888-5885

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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