Mobilization of trace metals from caprock and formation rocks at the Illinois Basin – Decatur Project demonstration site under geological carbon dioxide sequestration conditions

Shao, Hongbo; Freiburg, Jared T.; Berger, Peter M.; Taylor, Alexander H.; Cohen, Hanna F.; Locke, Randall A.

doi:10.1016/j.chemgeo.2020.119758

Mobilization of trace metals from caprock and formation rocks at the Illinois Basin – Decatur Project demonstration site under geological carbon dioxide sequestration conditions

Journal Article · Fri Jun 19 00:00:00 EDT 2020 · Chemical Geology

DOI:https://doi.org/10.1016/j.chemgeo.2020.119758· OSTI ID:1799716

^[1]; Freiburg, Jared T. ^[2]; Berger, Peter M. ^[3]; Taylor, Alexander H. ^[2]; Cohen, Hanna F. ^[2]; Locke, Randall A. ^[2]

Univ. of Illinois at Urbana-Champaign, IL (United States); OSTI
Univ. of Illinois at Urbana-Champaign, IL (United States)
Univ. of Tasmania, Hobart, TAS (Australia)

One concern for geologic CO₂ sequestration is the potential leakage of CO₂ or CO₂-saturated brine containing trace metals into overlying aquifers, which poses the risk of adversely affecting underground sources of drinking water. In this work, rock and brine samples collected in the Illinois Basin – Decatur Project (IBDP), a large-scale geological CO₂ sequestration demonstration project in Decatur, Illinois, USA, as well as synthetic brine samples were used to understand the mobilization of trace metals as a result of CO₂–rock–brine interactions under IBDP-specific conditions (50 °C and 20.6 MPa). Rock sample characterization indicated that, at the IBDP site, trace metal concentrations were greatest in cap rock samples from the Eau Claire Formation, compared with those from formations above and below this Formation. The natural brine samples collected from the Mt. Simon Sandstone reservoir were highly reducing and saline, with trace metal concentrations up to 680 times greater than the U.S. Environmental Protection Agency-prescribed drinking water standards. Batch leaching experiments indicated that both trace metal mobilization from rock and immobilization from the brine occurred when high-pressure CO₂ was introduced into the rock-brine system. The amounts of metals mobilized from the rock generally accounted for <5% of the total metals in the rock, but for some metals, including Ni, Pb, and Tl, up to 63% of the metals in the rock were mobilized to the brine. Leaching of trace metals into synthetic brines was different from that into the natural brine. The results of this study provided current information on the trace element sources and will help in risk simulations and experimental design to further evaluate potential impact of leakage on groundwater quality, which is important for future GCS projects to consider for monitoring and containment assurance purposes.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Illinois at Urbana-Champaign, IL (United States)

Sponsoring Organization:: USDOE; USDOE Office of Fossil Energy (FE)

Grant/Contract Number:: FC26-05NT42588

OSTI ID:: 1799716

Alternate ID(s):: OSTI ID: 1634275

Journal Information:: Chemical Geology, Journal Name: Chemical Geology Vol. 550; ISSN 0009-2541

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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58 GEOSCIENCES
The Illinois Basin – Decatur Project
geological CO2 sequestration
mobilization
natural brine
synthetic brine
trace metal

Mobilization of trace metals from caprock and formation rocks at the Illinois Basin – Decatur Project demonstration site under geological carbon dioxide sequestration conditions

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