How Chloride Suppresses Photoinduced Phase Segregation in Mixed Halide Perovskites

Cho, Junsang; Kamat, Prashant V.

doi:10.1021/acs.chemmater.0c02100

Title: How Chloride Suppresses Photoinduced Phase Segregation in Mixed Halide Perovskites

Journal Article · Thu Jun 25 00:00:00 EDT 2020 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.0c02100· OSTI ID:1799624

;

Not provided.

Cite

Export

Save

Research Organization:: Univ. of Notre Dame, IN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: FC02-04ER15533

OSTI ID:: 1799624

Journal Information:: Chemistry of Materials, Vol. 32, Issue 14; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (46)

Fully textured monolithic perovskite/silicon tandem solar cells with 25.2% power conversion efficiency Sahli, Florent; Werner, Jérémie; Kamino, Brett A. Nature Materials, Vol. 17, Issue 9 https://doi.org/10.1038/s41563-018-0115-4	journal	June 2018
A fluorene-terminated hole-transporting material for highly efficient and stable perovskite solar cells Jeon, Nam Joong; Na, Hyejin; Jung, Eui Hyuk Nature Energy, Vol. 3, Issue 8 https://doi.org/10.1038/s41560-018-0200-6	journal	July 2018
Photoinduced Anion Segregation in Mixed Halide Perovskites Brennan, Michael C.; Ruth, Anthony; Kamat, Prashant V. Trends in Chemistry, Vol. 2, Issue 4 https://doi.org/10.1016/j.trechm.2020.01.010	journal	April 2020
Triple-halide wide–band gap perovskites with suppressed phase segregation for efficient tandems Xu, Jixian; Boyd, Caleb C.; Yu, Zhengshan J. Science, Vol. 367, Issue 6482 https://doi.org/10.1126/science.aaz5074	journal	March 2020
A mixed-cation lead mixed-halide perovskite absorber for tandem solar cells McMeekin, D. P.; Sadoughi, G.; Rehman, W. Science, Vol. 351, Issue 6269 https://doi.org/10.1126/science.aad5845	journal	January 2016
Progress on Perovskite Materials and Solar Cells with Mixed Cations and Halide Anions Ono, Luis K.; Juarez-Perez, Emilio J.; Qi, Yabing ACS Applied Materials & Interfaces, Vol. 9, Issue 36 https://doi.org/10.1021/acsami.7b06001	journal	July 2017
Intrinsic Halide Segregation at Nanometer Scale Determines the High Efficiency of Mixed Cation/Mixed Halide Perovskite Solar Cells Gratia, Paul; Grancini, Giulia; Audinot, Jean-Nicolas Journal of the American Chemical Society, Vol. 138, Issue 49 https://doi.org/10.1021/jacs.6b10049	journal	December 2016
Light-Induced Phase Segregation in Halide-Perovskite Absorbers Slotcavage, Daniel J.; Karunadasa, Hemamala I.; McGehee, Michael D. ACS Energy Letters, Vol. 1, Issue 6 https://doi.org/10.1021/acsenergylett.6b00495	journal	November 2016
Tracking Iodide and Bromide Ion Segregation in Mixed Halide Lead Perovskites during Photoirradiation Yoon, Seog Joon; Draguta, Sergiu; Manser, Joseph S. ACS Energy Letters, Vol. 1, Issue 1 https://doi.org/10.1021/acsenergylett.6b00158	journal	June 2016
Rationalizing the light-induced phase separation of mixed halide organic–inorganic perovskites Draguta, Sergiu; Sharia, Onise; Yoon, Seog Joon Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00284-2	journal	August 2017
Shift Happens . How Halide Ion Defects Influence Photoinduced Segregation in Mixed Halide Perovskites Yoon, Seog Joon; Kuno, Masaru; Kamat, Prashant V. ACS Energy Letters, Vol. 2, Issue 7 https://doi.org/10.1021/acsenergylett.7b00357	journal	June 2017
Light-Induced Anion Phase Segregation in Mixed Halide Perovskites Brennan, Michael C.; Draguta, Sergiu; Kamat, Prashant V. ACS Energy Letters, Vol. 3, Issue 1 https://doi.org/10.1021/acsenergylett.7b01151	journal	November 2017
Reversible Removal of Intermixed Shallow States by Light Soaking in Multication Mixed Halide Perovskite Films Guo, Dengyang; Andaji Garmaroudi, Zahra; Abdi-Jalebi, Mojtaba ACS Energy Letters, Vol. 4, Issue 10 https://doi.org/10.1021/acsenergylett.9b01726	journal	September 2019
Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency Saliba, Michael; Matsui, Taisuke; Seo, Ji-Youn Energy & Environmental Science, Vol. 9, Issue 6 https://doi.org/10.1039/C5EE03874J	journal	January 2016
Impact of Surfaces on Photoinduced Halide Segregation in Mixed-Halide Perovskites Belisle, Rebecca A.; Bush, Kevin A.; Bertoluzzi, Luca ACS Energy Letters, Vol. 3, Issue 11 https://doi.org/10.1021/acsenergylett.8b01562	journal	October 2018
Electronic Traps and Phase Segregation in Lead Mixed-Halide Perovskite Knight, Alexander J.; Wright, Adam D.; Patel, Jay B. ACS Energy Letters, Vol. 4, Issue 1 https://doi.org/10.1021/acsenergylett.8b02002	journal	November 2018
TiO ₂ -Assisted Halide Ion Segregation in Mixed Halide Perovskite Films DuBose, Jeffrey T.; Kamat, Prashant V. Journal of the American Chemical Society, Vol. 142, Issue 11 https://doi.org/10.1021/jacs.0c00434	journal	February 2020
Electrochemical Hole Injection Selectively Expels Iodide from Mixed Halide Perovskite Films Samu, Gergely F.; Balog, Ádám; De Angelis, Filippo Journal of the American Chemical Society, Vol. 141, Issue 27 https://doi.org/10.1021/jacs.9b04568	journal	June 2019
Suppression of atomic vacancies via incorporation of isovalent small ions to increase the stability of halide perovskite solar cells in ambient air Saidaminov, Makhsud I.; Kim, Junghwan; Jain, Ankit Nature Energy, Vol. 3, Issue 8 https://doi.org/10.1038/s41560-018-0192-2	journal	July 2018
Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber Stranks, S. D.; Eperon, G. E.; Grancini, G. Science, Vol. 342, Issue 6156, p. 341-344 https://doi.org/10.1126/science.1243982	journal	October 2013
Impact of microstructure on local carrier lifetime in perovskite solar cells de Quilettes, D. W.; Vorpahl, S. M.; Stranks, S. D. Science, Vol. 348, Issue 6235 https://doi.org/10.1126/science.aaa5333	journal	April 2015
Influence of Cl Incorporation in Perovskite Precursor on the Crystal Growth and Storage Stability of Perovskite Solar Cells Zhang, Hui; Lv, Yifan; Wang, Jinpei ACS Applied Materials & Interfaces, Vol. 11, Issue 6 https://doi.org/10.1021/acsami.8b19390	journal	January 2019
Enhanced Performance of Perovskite Solar Cells with Zinc Chloride Additives Jin, Junjie; Li, Hao; Chen, Cong ACS Applied Materials & Interfaces, Vol. 9, Issue 49 https://doi.org/10.1021/acsami.7b15310	journal	December 2017
MAPbI_3-xCl_x Mixed Halide Perovskite for Hybrid Solar Cells: The Role of Chloride as Dopant on the Transport and Structural Properties Colella, Silvia; Mosconi, Edoardo; Fedeli, Paolo Chemistry of Materials, Vol. 25, Issue 22, p. 4613-4618 https://doi.org/10.1021/cm402919x	journal	November 2013
Investigation Regarding the Role of Chloride in Organic–Inorganic Halide Perovskites Obtained from Chloride Containing Precursors Dar, M. Ibrahim; Arora, Neha; Gao, Peng Nano Letters, Vol. 14, Issue 12 https://doi.org/10.1021/nl503279x	journal	November 2014
Enhanced Efficiency of Hot-Cast Large-Area Planar Perovskite Solar Cells/Modules Having Controlled Chloride Incorporation Liao, Hsueh-Chung; Guo, Peijun; Hsu, Che-Pu Advanced Energy Materials, Vol. 7, Issue 8 https://doi.org/10.1002/aenm.201601660	journal	December 2016
Unraveling the Formation Mechanism and Ferroelastic Behavior of MAPbI ₃ Perovskite Thin Films Prepared in the Presence of Chloride Medjahed, Asma Aicha; Dally, Pia; Zhou, Tao Chemistry of Materials, Vol. 32, Issue 8 https://doi.org/10.1021/acs.chemmater.9b04239	journal	March 2020
Role of Chloride in the Morphological Evolution of Organo-Lead Halide Perovskite Thin Films Williams, Spencer T.; Zuo, Fan; Chueh, Chu-Chen ACS Nano, Vol. 8, Issue 10 https://doi.org/10.1021/nn5041922	journal	October 2014
Grain Engineering for Perovskite/Silicon Monolithic Tandem Solar Cells with Efficiency of 25.4% Chen, Bo; Yu, Zhengshan; Liu, Kong Joule, Vol. 3, Issue 1 https://doi.org/10.1016/j.joule.2018.10.003	journal	January 2019
Vertical recrystallization for highly efficient and stable formamidinium-based inverted-structure perovskite solar cells Xie, Fengxian; Chen, Chun-Chao; Wu, Yongzhen Energy & Environmental Science, Vol. 10, Issue 9 https://doi.org/10.1039/C7EE01675A	journal	January 2017
Efficient Planar Perovskite Solar Cells Based on 1.8 eV Band Gap CH ₃ NH ₃ PbI ₂ Br Nanosheets via Thermal Decomposition Zhao, Yixin; Zhu, Kai Journal of the American Chemical Society, Vol. 136, Issue 35 https://doi.org/10.1021/ja5071398	journal	August 2014
Chloride Insertion–Immobilization Enables Bright, Narrowband, and Stable Blue-Emitting Perovskite Diodes Ma, Dongxin; Todorović, Petar; Meshkat, Shadi Journal of the American Chemical Society, Vol. 142, Issue 11 https://doi.org/10.1021/jacs.9b12323	journal	March 2020
Charge Carrier Recombination Dynamics of Two-Dimensional Lead Halide Perovskites Cho, Junsang; DuBose, Jeffrey T.; Kamat, Prashant V. The Journal of Physical Chemistry Letters, Vol. 11, Issue 7 https://doi.org/10.1021/acs.jpclett.0c00392	journal	March 2020
How Interplay between Photo and Thermal Activation Dictates Halide Ion Segregation in Mixed Halide Perovskites Elmelund, Tor; Seger, Brian; Kuno, Masaru ACS Energy Letters, Vol. 5, Issue 1 https://doi.org/10.1021/acsenergylett.9b02265	journal	November 2019
Chemical Management for Colorful, Efficient, and Stable Inorganic–Organic Hybrid Nanostructured Solar Cells Noh, Jun Hong; Im, Sang Hyuk; Heo, Jin Hyuck Nano Letters, Vol. 13, Issue 4, p. 1764-1769 https://doi.org/10.1021/nl400349b	journal	March 2013
Persistent Dopants and Phase Segregation in Organolead Mixed-Halide Perovskites Rosales, Bryan A.; Men, Long; Cady, Sarah D. Chemistry of Materials, Vol. 28, Issue 19 https://doi.org/10.1021/acs.chemmater.6b01874	journal	August 2016
High Chloride Doping Levels Stabilize the Perovskite Phase of Cesium Lead Iodide Dastidar, Subham; Egger, David A.; Tan, Liang Z. Nano Letters, Vol. 16, Issue 6 https://doi.org/10.1021/acs.nanolett.6b00635	journal	May 2016
Chloride Incorporation Process in CH ₃ NH ₃ PbI _{3– x} Cl _x Perovskites via Nanoscale Bandgap Maps Chae, Jungseok; Dong, Qingfeng; Huang, Jinsong Nano Letters, Vol. 15, Issue 12 https://doi.org/10.1021/acs.nanolett.5b03556	journal	November 2015
Synergetic Effect of Chloride Doping and CH ₃ NH ₃ PbCl ₃ on CH ₃ NH ₃ PbI _{3− x} Cl _x Perovskite-Based Solar Cells Xu, Feng; Zhang, Taiyang; Li, Ge ChemSusChem, Vol. 10, Issue 11 https://doi.org/10.1002/cssc.201700487	journal	May 2017
Tailoring Triple‐Anion Perovskite Material for Indoor Light Harvesting with Restrained Halide Segregation and Record High Efficiency Beyond 36% Cheng, Rui; Chung, Chih‐Chun; Zhang, Hong Advanced Energy Materials, Vol. 9, Issue 38 https://doi.org/10.1002/aenm.201901980	journal	August 2019
Bidirectional Halide Ion Exchange in Paired Lead Halide Perovskite Films with Thermal Activation Elmelund, Tor; Scheidt, Rebecca A.; Seger, Brian ACS Energy Letters, Vol. 4, Issue 8 https://doi.org/10.1021/acsenergylett.9b01280	journal	July 2019
Suppressed Halide Ion Migration in 2D Lead Halide Perovskites Cho, Junsang; DuBose, Jeffrey T.; Le, An Ngoc Thien ACS Materials Letters, Vol. 2, Issue 6 https://doi.org/10.1021/acsmaterialslett.0c00124	journal	April 2020
Charge Transfer Dynamics of Phase-Segregated Halide Perovskites: CH ₃ NH ₃ PbCl ₃ and CH ₃ NH ₃ PbI ₃ or (C ₄ H ₉ NH ₃ ) ₂ (CH ₃ NH ₃ ) _{n −1} Pb _n I _{3 n +1} Mixtures Cao, Duyen H.; Guo, Peijun; Mannodi-Kanakkithodi, Arun ACS Applied Materials & Interfaces, Vol. 11, Issue 9 https://doi.org/10.1021/acsami.8b20928	journal	February 2019
Reversible photo-induced trap formation in mixed-halide hybrid perovskites for photovoltaics Hoke, Eric T.; Slotcavage, Daniel J.; Dohner, Emma R. Chemical Science, Vol. 6, Issue 1 https://doi.org/10.1039/C4SC03141E	journal	January 2015
Band alignment of the hybrid halide perovskites CH ₃ NH ₃ PbCl ₃ , CH ₃ NH ₃ PbBr ₃ and CH ₃ NH ₃ PbI ₃ Butler, Keith T.; Frost, Jarvist M.; Walsh, Aron Materials Horizons, Vol. 2, Issue 2 https://doi.org/10.1039/C4MH00174E	journal	January 2015
Band Edge Energies and Excitonic Transition Probabilities of Colloidal CsPbX ₃ (X = Cl, Br, I) Perovskite Nanocrystals Ravi, Vikash Kumar; Markad, Ganesh B.; Nag, Angshuman ACS Energy Letters, Vol. 1, Issue 4 https://doi.org/10.1021/acsenergylett.6b00337	journal	September 2016

Similar Records

Shift Happens . How Halide Ion Defects Influence Photoinduced Segregation in Mixed Halide Perovskites

Journal Article · Thu Jun 01 00:00:00 EDT 2017 · ACS Energy Letters · OSTI ID:1799624

Yoon, Seog Joon; Kuno, Masaru; Kamat, Prashant V.

Photoinduced Phase Segregation in Mixed Halide Perovskites: Thermodynamic and Kinetic Aspects of Cl–Br Segregation

Journal Article · Tue Oct 13 00:00:00 EDT 2020 · Advanced Optical Materials · OSTI ID:1799624

Cho, Junsang; Kamat, Prashant V.