Tailoring chemoenzymatic oxidation via in situ peracids

Re, Rebecca N.; Proessdorf, Johanna C.; La Clair, James J.; Subileau, Maeva; Burkart, Michael D.

doi:10.1039/c9ob01814j

Tailoring chemoenzymatic oxidation via in situ peracids

Journal Article · Thu Oct 10 00:00:00 EDT 2019 · Organic and Biomolecular Chemistry

DOI:https://doi.org/10.1039/c9ob01814j· OSTI ID:1799473

^[1]; Proessdorf, Johanna C. ^[2]; ^[2]; ^[3]; ^[2]

Univ. of California, San Diego, CA (United States). Dept. of Chemistry and Biochemistry; OSTI
Univ. of California, San Diego, CA (United States). Dept. of Chemistry and Biochemistry
Univ. of California, San Diego, CA (United States). Dept. of Chemistry and Biochemistry; Univ. Montpellier (France). UMR IATE. Montpellier SupAgro. INRA

Epoxidation chemistry often suffers from the challenging handling of peracids and thus requires in situ preparation. Here, we describe a two-phase enzymatic system that allows the effective generation of peracids and directly translate their activity to the epoxidation of olefins. We demonstrate the approach by application to lipid and olefin epoxidation as well as sulfide oxidation. These methods offer useful applications to synthetic modifications and scalable green processes.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, San Diego, CA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Bioenergy Technologies Office

Grant/Contract Number:: EE0008246

OSTI ID:: 1799473

Alternate ID(s):: OSTI ID: 1571831

Journal Information:: Organic and Biomolecular Chemistry, Journal Name: Organic and Biomolecular Chemistry Journal Issue: 43 Vol. 17; ISSN 1477-0520

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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