Cation and anion topotactic transformations in cobaltite thin films leading to Ruddlesden-Popper phases

Chiu, I-Ting; Lee, Min-Han; Cheng, Shaobo; Zhang, Shenli; Heki, Larry; Zhang, Zhen; Mohtashami, Yahya; Lapa, Pavel N.; Feng, Mingzhen; Shafer, Padraic; N'Diaye, Alpha T.; Mehta, Apurva; Schuller, Jon A.; Galli, Giulia; Ramanathan, Shriram; Zhu, Yimei; Schuller, Ivan K.; Takamura, Yayoi

doi:10.1103/physrevmaterials.5.064416

Cation and anion topotactic transformations in cobaltite thin films leading to Ruddlesden-Popper phases

Journal Article · Thu Jun 24 00:00:00 EDT 2021 · Physical Review Materials

DOI:https://doi.org/10.1103/physrevmaterials.5.064416· OSTI ID:1798563

Chiu, I-Ting ^[1]; ^[2]; Cheng, Shaobo ^[3]; ^[4]; Heki, Larry ^[5]; Zhang, Zhen ^[6]; Mohtashami, Yahya ^[5]; Lapa, Pavel N. ^[2]; ^[7]; Shafer, Padraic ^[8]; N'Diaye, Alpha T. ^[8]; ^[9]; Schuller, Jon A. ^[5]; ^[10]; Ramanathan, Shriram ^[6]; ^[3]; ^[2]; ^[7]

Univ. of California, Davis, CA (United States); University of California, Davis
Univ. of California, San Diego, La Jolla, CA (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Univ. of Chicago, IL (United States)
Univ. of California, Santa Barbara, CA (United States)
Purdue Univ., West Lafayette, IN (United States)
Univ. of California, Davis, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Univ. of Chicago, IL (United States); Argonne National Lab. (ANL), Lemont, IL (United States)

Topotactic transformations involve structural changes between related crystal structures due to a loss or gain of material while retaining a crystallographic relationship. The perovskite oxide La_0.7Sr_0.3CoO₃ (LSCO) is an ideal system for investigating phase transformations due to its high oxygen vacancy conductivity, relatively low oxygen vacancy formation energy, and strong coupling of the magnetic and electronic properties to the oxygen stoichiometry. While the transition between cobaltite perovskite and brownmillerite (BM) phases has been widely reported, further reduction beyond the BM phase lacks systematic studies. In this paper, we study the evolution of the physical properties of LSCO thin films upon exposure to highly reducing environments. We observe the rarely reported crystalline Ruddlesden-Popper phase, which involves the loss of both oxygen anions and cobalt cations upon annealing where the cobalt is found as isolated Co ions or Co nanoparticles. First-principles calculations confirm that the concurrent loss of oxygen and cobalt ions is thermodynamically possible through an intermediary BM phase. Furthermore, the strong correlation of the magnetic and electronic properties to the crystal structure highlights the potential of utilizing ion migration as a basis for emerging applications such as neuromorphic computing.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States); SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States); Univ. of California, Davis, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231; AC02-76SF00515; SC0012704; SC0019273

OSTI ID:: 1798563

Alternate ID(s):: OSTI ID: 1807947
OSTI ID: 1814034
OSTI ID: 1868556

Report Number(s):: BNL--221809-2021-JAAM

Journal Information:: Physical Review Materials, Journal Name: Physical Review Materials Journal Issue: 6 Vol. 5; ISSN 2475-9953

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

References (68)

Topotactic Phase Transformation of the Brownmillerite SrCoO _2.5 to the Perovskite SrCoO _3- _δ Jeen, H.; Choi, W. S.; Freeland, J. W. Advanced Materials, Vol. 25, Issue 27 https://doi.org/10.1002/adma.201300531	journal	July 2013
Topotactic Phase Transition Driving Memristive Behavior Nallagatla, Venkata R.; Heisig, Thomas; Baeumer, Christoph Advanced Materials, Vol. 31, Issue 40 https://doi.org/10.1002/adma.201903391	journal	August 2019
Uncovering the Effect of Lattice Strain and Oxygen Deficiency on Electrocatalytic Activity of Perovskite Cobaltite Thin Films Liu, Xi; Zhang, Lei; Zheng, Yun Advanced Science, Vol. 6, Issue 6 https://doi.org/10.1002/advs.201801898	journal	January 2019
Perovskite Oxide for Solid Oxide Fuel Cells Ishihara, Tatsumi Fuel Cells and Hydrogen Energy https://doi.org/10.1007/978-0-387-77708-5	book	January 2009
Structural and photoluminescence studies of Co2+ doped Ca–Li hydroxyapatite nanopowders Ravindranadh, K.; Babu, B.; Rao, M. C. Journal of Materials Science: Materials in Electronics, Vol. 26, Issue 9 https://doi.org/10.1007/s10854-015-3268-9	journal	June 2015
Absorption and luminescence of tetrahedral Co2+ ion in MgAl2O4 Kuleshov, N. V.; Mikhailov, V. P.; Scherbitsky, V. G. Journal of Luminescence, Vol. 55, Issue 5-6 https://doi.org/10.1016/0022-2313(93)90021-E	journal	August 1993
Cobalt nanoparticles for biomedical applications: Facile synthesis, physiochemical characterization, cytotoxicity behavior and biocompatibility Ansari, S. M.; Bhor, R. D.; Pai, K. R. Applied Surface Science, Vol. 414 https://doi.org/10.1016/j.apsusc.2017.03.002	journal	August 2017
Pseudopotentials periodic table: From H to Pu Dal Corso, Andrea Computational Materials Science, Vol. 95 https://doi.org/10.1016/j.commatsci.2014.07.043	journal	December 2014
Magnetism at spinel thin film interfaces probed through soft X-ray spectroscopy techniques Chopdekar, R. V.; Liberati, M.; Takamura, Y. Journal of Magnetism and Magnetic Materials, Vol. 322, Issue 19 https://doi.org/10.1016/j.jmmm.2010.05.005	journal	October 2010
Topotactic phase transformations by concerted dual-ion migration of B-site cation and oxygen in multivalent cobaltite La–Sr–Co–Ox films Li, Jia; Guan, Meng-Xue; Nan, Peng-Fei Nano Energy, Vol. 78 https://doi.org/10.1016/j.nanoen.2020.105215	journal	December 2020
Modified Oxygen Defect Chemistry at Transition Metal Oxide Heterostructures Probed by Hard X-ray Photoelectron Spectroscopy and X-ray Diffraction Chen, Yan; Fong, Dillon D.; Herbert, F. William Chemistry of Materials, Vol. 30, Issue 10 https://doi.org/10.1021/acs.chemmater.8b00808	journal	April 2018
Magnetic, Structural, and Chemical Properties of Cobalt Nanoparticles Synthesized in Ionic Liquids Morcos, Bishoy; Lecante, Pierre; Morel, Robert Langmuir, Vol. 34, Issue 24 https://doi.org/10.1021/acs.langmuir.8b00271	journal	May 2018
Voltage-Controlled Topotactic Phase Transition in Thin-Film SrCoO _x Monitored by In Situ X-ray Diffraction Lu, Qiyang; Yildiz, Bilge Nano Letters, Vol. 16, Issue 2 https://doi.org/10.1021/acs.nanolett.5b04492	journal	January 2016
Controlling Magnetization Vector Depth Profiles of La _0.7 Sr _0.3 CoO ₃ /La _0.7 Sr _0.3 MnO ₃ Exchange Spring Bilayers via Interface Reconstruction Kane, Alexander M.; Chiu, I-Ting; Ahlm, Nolan J. ACS Applied Materials & Interfaces, Vol. 12, Issue 40 https://doi.org/10.1021/acsami.0c09417	journal	August 2020
Controlling Metal–Insulator Transitions in Vanadium Oxide Thin Films by Modifying Oxygen Stoichiometry Lee, Min-Han; Kalcheim, Yoav; Valle, Javier del ACS Applied Materials & Interfaces, Vol. 13, Issue 1 https://doi.org/10.1021/acsami.0c18327	journal	December 2020
Enhancing Electrode Performance by Exsolved Nanoparticles: A Superior Cobalt-Free Perovskite Electrocatalyst for Solid Oxide Fuel Cells Yang, Guangming; Zhou, Wei; Liu, Meilin ACS Applied Materials & Interfaces, Vol. 8, Issue 51 https://doi.org/10.1021/acsami.6b12157	journal	December 2016
Interfacial-Redox-Induced Tuning of Superconductivity in YBa ₂ Cu ₃ O _7-δ Murray, Peyton D.; Gilbert, Dustin A.; Grutter, Alexander J. ACS Applied Materials & Interfaces, Vol. 12, Issue 4 https://doi.org/10.1021/acsami.9b18820	journal	December 2019
Strong Effect of B-Site Substitution on the Reactivity of Layered Perovskite Oxides Probed via Isopropanol Conversion Tan, Shuai; Sayed, Farheen; Yang, Shize ACS Materials Letters, Vol. 1, Issue 2 https://doi.org/10.1021/acsmaterialslett.9b00095	journal	July 2019
Electrostatic versus Electrochemical Doping and Control of Ferromagnetism in Ion-Gel-Gated Ultrathin La _0.5 Sr _0.5 CoO _3−δ Walter, Jeff; Wang, Helin; Luo, Bing ACS Nano, Vol. 10, Issue 8 https://doi.org/10.1021/acsnano.6b03403	journal	July 2016
Structural similarities among oxygen-deficient perovskites Anderson, Mark T.; Vaughey, John T.; Poeppelmeier, Kenneth R. Chemistry of Materials, Vol. 5, Issue 2 https://doi.org/10.1021/cm00026a003	journal	February 1993
Thermal and Chemical Expansion of Sr-Doped Lanthanum Cobalt Oxide (La ₁ _- _x Sr _x CoO ₃ _- _δ ) No authors listed Chemistry of Materials, Vol. 17, Issue 17 https://doi.org/10.1021/cm050905h	journal	August 2005
Synthesis and Structural Characterization of La _{1− x} A _x MnO _2.5 (A = Ba, Sr, Ca) Phases: Mapping the Variants of the Brownmillerite Structure Parsons, Thomas G.; D’Hondt, Hans; Hadermann, Joke Chemistry of Materials, Vol. 21, Issue 22 https://doi.org/10.1021/cm902535m	journal	November 2009
Infinite-layer iron oxide with a square-planar coordination Tsujimoto, Y.; Tassel, C.; Hayashi, N. Nature, Vol. 450, Issue 7172, p. 1062-1065 https://doi.org/10.1038/nature06382	journal	December 2007
Electric-field control of tri-state phase transformation with a selective dual-ion switch Lu, Nianpeng; Zhang, Pengfei; Zhang, Qinghua Nature, Vol. 546, Issue 7656 https://doi.org/10.1038/nature22389	journal	May 2017
High-spin ground states via electron delocalization in mixed-valence imidazolate-bridged divanadium complexes Bechlars, Bettina; D'Alessandro, Deanna M.; Jenkins, David M. Nature Chemistry, Vol. 2, Issue 5 https://doi.org/10.1038/nchem.585	journal	March 2010
Highly thermal-stable ferromagnetism by a natural composite Ma, Tianyu; Gou, Junming; Hu, Shanshan Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms13937	journal	January 2017
Ionic transport in hybrid lead iodide perovskite solar cells Eames, Christopher; Frost, Jarvist M.; Barnes, Piers R. F. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8497	journal	June 2015
Reversible redox reactions in an epitaxially stabilized SrCoOx oxygen sponge Jeen, Hyoungjeen; Choi, Woo Seok; Biegalski, Michael D. Nature Materials, Vol. 12, Issue 11 https://doi.org/10.1038/nmat3736	journal	August 2013
Atomic-resolution imaging of electrically induced oxygen vacancy migration and phase transformation in SrCoO2.5-σ Zhang, Qinghua; He, Xu; Shi, Jinan Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00121-6	journal	July 2017
Understanding the metal-to-insulator transition in La1−xSrxCoO3−δ and its applications for neuromorphic computing Zhang, Shenli; Galli, Giulia npj Computational Materials, Vol. 6, Issue 1 https://doi.org/10.1038/s41524-020-00437-w	journal	November 2020
Strongly Coupled Magnetic and Electronic Transitions in Multivalent Strontium Cobaltites Lee, J. H.; Choi, Woo Seok; Jeen, H. Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-16246-z	journal	November 2017
Magnetization and magneto-transport staircaselike behavior in layered perovskite Sr2CoO4 at low temperature Li, Qiuhang; Yuan, Xueping; Xing, Lei Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep27712	journal	June 2016
Square planar coordinate iron oxides Tassel, Cédric; Kageyama, Hiroshi Chem. Soc. Rev., Vol. 41, Issue 6 https://doi.org/10.1039/C1CS15218A	journal	January 2012
In situ non-aqueous nucleation and growth of next generation rare-earth-free permanent magnets Yoon, Hyojung; Xu, Aoran; Sterbinsky, George E. Physical Chemistry Chemical Physics, Vol. 17, Issue 2 https://doi.org/10.1039/C4CP04451G	journal	January 2015
In situ exsolution of Ni particles on the PrBaMn ₂ O ₅ SOFC electrode material monitored by high temperature neutron powder diffraction under hydrogen Bahout, Mona; Managutti, Praveen B.; Dorcet, Vincent Journal of Materials Chemistry A, Vol. 8, Issue 7 https://doi.org/10.1039/C9TA10159D	journal	January 2020
Arranging strategies for A-site cations: impact on the stability and carrier migration of hybrid perovskite materials Jian, Wei; Jia, Ran; Zhang, Hong-Xing Inorganic Chemistry Frontiers, Vol. 7, Issue 8 https://doi.org/10.1039/D0QI00102C	journal	January 2020
A new form of oxygen deficient 1201-cobaltite (Tl_0.4Sr_0.5Co_0.1)Sr₂CoO_{5 – δ}: structure, transport and magnetic properties Maignan, A.; Pelloquin, D.; Martin, C. Journal of Materials Chemistry, Vol. 12, Issue 4, p. 1009-1016 https://doi.org/10.1039/b108377p	journal	March 2002
Reduction and oxidation of SrCoO_2.5 thin films at low temperatures Ichikawa, Noriya; Iwanowska, Monika; Kawai, Masanori Dalton Transactions, Vol. 41, Issue 35, p. 10507-10510 https://doi.org/10.1039/c2dt30317e	journal	January 2012
Impact of niobium doping upon the magnetotransport properties of the oxygen-deficient perovskite SrCo1−xNbxO3−δ Motohashi, T.; Caignaert, V.; Pralong, V. Applied Physics Letters, Vol. 86, Issue 19 https://doi.org/10.1063/1.1925312	journal	May 2005
Commentary: The Materials Project: A materials genome approach to accelerating materials innovation Jain, Anubhav; Ong, Shyue Ping; Hautier, Geoffroy APL Materials, Vol. 1, Issue 1 https://doi.org/10.1063/1.4812323	journal	July 2013
Reversible control of magnetism in La _0.67 Sr _0.33 MnO ₃ through chemically-induced oxygen migration Grutter, A. J.; Gilbert, D. A.; Alaan, U. S. Applied Physics Letters, Vol. 108, Issue 8 https://doi.org/10.1063/1.4942645	journal	February 2016
Magnetic properties of polycrystalline cobalt nanoparticles Bautin, V. A.; Seferyan, A. G.; Nesmeyanov, M. S. AIP Advances, Vol. 7, Issue 4 https://doi.org/10.1063/1.4979889	journal	April 2017
Synthesis and characterisation of ferromagnetic hexagonal cobalt nanoparticles Rao, K. Srinivasa; Balaji, T.; Lingappaa, Y. Journal of Experimental Nanoscience, Vol. 8, Issue 2 https://doi.org/10.1080/17458080.2011.563323	journal	February 2013
Beyond electrostatic modification: design and discovery of functional oxide phases via ionic-electronic doping Zhang, Hai-Tian; Zhang, Zhen; Zhou, Hua Advances in Physics: X, Vol. 4, Issue 1 https://doi.org/10.1080/23746149.2018.1523686	journal	October 2018
QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials Giannozzi, Paolo; Baroni, Stefano; Bonini, Nicola Journal of Physics: Condensed Matter, Vol. 21, Issue 39, Article No. 395502 https://doi.org/10.1088/0953-8984/21/39/395502	journal	September 2009
Advanced capabilities for materials modelling with Quantum ESPRESSO Giannozzi, P.; Andreussi, O.; Brumme, T. Journal of Physics: Condensed Matter, Vol. 29, Issue 46 https://doi.org/10.1088/1361-648X/aa8f79	journal	October 2017
Evolution of Metallicity in Vanadium Dioxide by Creation of Oxygen Vacancies Zhang, Zhen; Zuo, Fan; Wan, Chenghao Physical Review Applied, Vol. 7, Issue 3 https://doi.org/10.1103/PhysRevApplied.7.034008	journal	March 2017
Special points for Brillouin-zone integrations Monkhorst, Hendrik J.; Pack, James D. Physical Review B, Vol. 13, Issue 12, p. 5188-5192 https://doi.org/10.1103/PhysRevB.13.5188	journal	June 1976
Intrinsic luminescence excitation spectrum and extended x-ray absorption fine structure above the K edge in Ca F 2 Bianconi, A.; Jackson, D.; Monahan, K. Physical Review B, Vol. 17, Issue 4 https://doi.org/10.1103/PhysRevB.17.2021	journal	February 1978
Experimental proof of magnetic x-ray dichroism van der Laan, Gerrit; Thole, Bernard T.; Sawatzky, George A. Physical Review B, Vol. 34, Issue 9 https://doi.org/10.1103/PhysRevB.34.6529	journal	November 1986
Sign dependence of the x-ray magnetic linear dichroism on the antiferromagnetic spin axis in La Fe O 3 thin films Czekaj, S.; Nolting, F.; Heyderman, L. J. Physical Review B, Vol. 73, Issue 2 https://doi.org/10.1103/PhysRevB.73.020401	journal	January 2006
Influence of crystal field on anisotropic x-ray magnetic linear dichroism at the Co 2 + L 2 , 3 edges van der Laan, Gerrit; Arenholz, Elke; Chopdekar, Rajesh V. Physical Review B, Vol. 77, Issue 6 https://doi.org/10.1103/PhysRevB.77.064407	journal	February 2008
Crystallographic and magnetic structure of SrCoO 2.5 brownmillerite: Neutron study coupled with band-structure calculations Munoz, A.; de la Calle, C.; Alonso, J. Physical Review B, Vol. 78, Issue 5, Article No. 054404 https://doi.org/10.1103/PhysRevB.78.054404	journal	August 2008
Correlation induced half-metallicity in a ferromagnetic single-layered compound: Sr 2 CoO 4 Pandey, Sudhir K. Physical Review B, Vol. 81, Issue 3 https://doi.org/10.1103/PhysRevB.81.035114	journal	January 2010
X-ray absorption and magnetic circular dichroism of LaCoO 3 , La 0.7 Ce 0.3 CoO 3 , and La 0.7 Sr 0.3 CoO 3 films: Evidence for cobalt-valence-dependent magnetism Merz, M.; Nagel, P.; Pinta, C. Physical Review B, Vol. 82, Issue 17 https://doi.org/10.1103/PhysRevB.82.174416	journal	November 2010
Pressure dependence of Curie temperature and resistivity in complex Heusler alloys Bose, S. K.; Kudrnovský, J.; Drchal, V. Physical Review B, Vol. 84, Issue 17 https://doi.org/10.1103/PhysRevB.84.174422	journal	November 2011
( Sr , Na ) ( Zn , Mn ) 2 As 2 : A diluted ferromagnetic semiconductor with the hexagonal CaAl 2 Si 2 type structure Chen, B. J.; Zhao, K.; Deng, Z. Physical Review B, Vol. 90, Issue 15 https://doi.org/10.1103/PhysRevB.90.155202	journal	October 2014
Exchange coupling in (111)-oriented L a 0.7 S r 0.3 Mn O 3 / L a 0.7 S r 0.3 Fe O 3 superlattices Jia, Yue; Chopdekar, Rajesh V.; Arenholz, Elke Physical Review B, Vol. 92, Issue 9 https://doi.org/10.1103/PhysRevB.92.094407	journal	September 2015
Insulating Ferromagnetic LaCoO 3 − δ Films: A Phase Induced by Ordering of Oxygen Vacancies Biškup, Neven; Salafranca, Juan; Mehta, Virat Physical Review Letters, Vol. 112, Issue 8 https://doi.org/10.1103/PhysRevLett.112.087202	journal	February 2014
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Intergranular Giant Magnetoresistance in a Spontaneously Phase Separated Perovskite Oxide Wu, J.; Lynn, J. W.; Glinka, C. J. Physical Review Letters, Vol. 94, Issue 3 https://doi.org/10.1103/PhysRevLett.94.037201	journal	January 2005
Ionic tuning of cobaltites at the nanoscale Gilbert, Dustin A.; Grutter, Alexander J.; Murray, Peyton D. Physical Review Materials, Vol. 2, Issue 10 https://doi.org/10.1103/PhysRevMaterials.2.104402	journal	October 2018
X-ray nanodiffraction studies of ionically controlled nanoscale phase separation in cobaltites Rippy, Geoffery; Trinh, Lacey; Kane, Alexander M. Physical Review Materials, Vol. 3, Issue 8 https://doi.org/10.1103/PhysRevMaterials.3.082001	journal	August 2019
GenX : an extensible X-ray reflectivity refinement program utilizing differential evolution Björck, Matts; Andersson, Gabriella Journal of Applied Crystallography, Vol. 40, Issue 6 https://doi.org/10.1107/S0021889807045086	journal	November 2007
Optical constants, band gap, and infrared-active phonons of (LaAlO ₃ ) _0.3 (Sr ₂ AlTaO ₆ ) _0.35 (LSAT) from spectroscopic ellipsometry Nunley, Timothy Nathan; Willett-Gies, Travis I.; Cooke, Jacqueline A. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 34, Issue 5 https://doi.org/10.1116/1.4960356	journal	September 2016
Morphology, structure, and nucleation of out-of-phase boundaries (OPBs) in epitaxial films of layered oxides Zurbuchen, M. A.; Tian, W.; Pan, X. Q. Journal of Materials Research, Vol. 22, Issue 6 https://doi.org/10.1557/JMR.2007.0198	journal	June 2007
Assessing Cobalt Metal Nanoparticles Uptake by Cancer Cells Using Live Raman Spectroscopy Rauwel, Erwan; Al-Arag, Siham; Salehi, Hamideh International Journal of Nanomedicine, Vol. Volume 15 https://doi.org/10.2147/IJN.S258060	journal	January 2020
Magnetic Field-Assisted Gene Delivery: Achievements and Therapeutic Potential I. Schwerdt, Jose; F. Goya, Gerardo; Pilar Calatayud, M. Current Gene Therapy, Vol. 12, Issue 2 https://doi.org/10.2174/156652312800099616	journal	March 2012

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Cation and anion topotactic transformations in cobaltite thin films leading to Ruddlesden-Popper phases.

Journal Article · Thu Jun 24 00:00:00 EDT 2021 · Physical Review Materials · OSTI ID:1868556

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
Cobaltite thin films
Crystal defects
Electrical conductivity
Electronic structure of atoms & molecules
Epitaxial strain
First-principles calculations
Magnetic oxides
Magnetism
Phase transitions
Ruddlesden-Popper
Topotactic transformations

Cation and anion topotactic transformations in cobaltite thin films leading to Ruddlesden-Popper phases

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