Ultrafast and Controllable Phase Evolution by Flash Joule Heating

Chen, Weiyin; Li, John Tianci; Wang, Zhe; Algozeeb, Wala A.; Luong, Duy Xuan; Kittrell, Carter; McHugh, Emily A.; Advincula, Paul A.; Wyss, Kevin M.; Beckham, Jacob L.; Stanford, Michael G.; Jiang, Bo; Tour, James M.

doi:10.1021/acsnano.1c03536

Ultrafast and Controllable Phase Evolution by Flash Joule Heating

Journal Article · Thu Jun 17 00:00:00 EDT 2021 · ACS Nano

DOI:https://doi.org/10.1021/acsnano.1c03536· OSTI ID:1798515

Chen, Weiyin ^[1]; ^[2]; Wang, Zhe ^[2]; Algozeeb, Wala A. ^[2]; ^[2]; ^[2]; McHugh, Emily A. ^[2]; Advincula, Paul A. ^[2]; Wyss, Kevin M. ^[2]; Beckham, Jacob L. ^[2]; ^[2]; Jiang, Bo ^[2]; ^[2]

Rice Univ., Houston, TX (United States); Rice University
Rice Univ., Houston, TX (United States)

Flash Joule heating (FJH), an advanced material synthesis technique, has been used for the production of high-quality carbon materials. Direct current discharge through the precursors by large capacitors has successfully converted carbon-based starting materials into bulk quantities of turbostratic graphene by the FJH process. However, the formation of other carbon allotropes, such as nanodiamonds and concentric carbon materials, as well as the covalent functionalization of different carbon allotropes by the FJH process, remains challenging. Here, we report the solvent-free FJH synthesis of three different fluorinated carbon allotropes: fluorinated nanodiamonds, fluorinated turbostratic graphene and fluorinated concentric carbon. This is done by millisecond flashing of organic fluorine compounds and fluoride precursors. Spectroscopic analysis confirms the modification of the electronic states and the existence of various short-range and long-range orders in the different fluorinated carbon allotropes. As a result, the flash time-dependent relationship is further demonstrated to control the phase evolution and product compositions.

View Accepted Manuscript (DOE)

Research Organization:: Rice Univ., Houston, TX (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE), Clean Coal and Carbon Management

Grant/Contract Number:: FE0031794

OSTI ID:: 1798515

Journal Information:: ACS Nano, Journal Name: ACS Nano Journal Issue: 7 Vol. 15; ISSN 1936-0851

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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