Unravel unusual hardening behavior of a Pd–Ni–P metallic glass in its supercooled liquid region

Cao, Y. H.; Du, Q.; Liu, X. J.; Wang, L.; Wu, Y.; Wang, H.; Jiang, S. H.; Ren, Y.; Nieh, T. G.; Lu, Z. P.

doi:10.1063/5.0039755

Title: Unravel unusual hardening behavior of a Pd–Ni–P metallic glass in its supercooled liquid region

Journal Article · Mon Mar 22 00:00:00 EDT 2021 · Applied Physics Letters

DOI:https://doi.org/10.1063/5.0039755· OSTI ID:1797976

Cao, Y. H. ^[1]; Du, Q. ^[1];

^[1];

^[2]; Wu, Y. ^[1];

^[1]; Jiang, S. H. ^[1]; Ren, Y. ^[3]; Nieh, T. G. ^[4];

^[1]

University of Science and Technology Beijing (China)
Beijing Institute of Technology (China)
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Univ. of Tennessee, Knoxville, TN (United States)

Monolithic metallic glasses often exhibit work softening induced by high atom mobility in the supercooled liquid region in tension. In this work, we report an unusual viscous flow of the Pd_42.5Ni_42.5P₁₅ metallic glass in its supercooled liquid region, which is characterized by a remarkable hardening behavior with decent plasticity during tension. To unravel the causes of this unusual hardening, we conducted structural and thermodynamic analyses by employing several experiments, including dynamic mechanical analysis, differential scanning calorimetry, high-resolution transmission electron microscopy, and in situ heating synchrotron high-energy x-ray diffraction. It was found that the unusual hardening behavior was attributed to structural ordering during deformation, rather than nanocrystallization or structural relaxation observed, sometimes, in metallic glasses deformed in supercooled liquid region. We also incorporated an additional work hardening region in the modified deformation map for metallic glasses.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Natural Science Foundation of China (NSFC)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1797976

Journal Information:: Applied Physics Letters, Vol. 118, Issue 12; ISSN 0003-6951

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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