The impact of 2H9/2 → 4I13/2 emission from Er3+ ions on ratiometric optical temperature sensing with Yb3+/Er3+ co-doped upconversion materials

Xia, Xiaojing; Volpi, Azzurra; Roh, Joo D.; De Siena, Michael C.; Gamelin, Daniel R.; Hehlen, Markus P.; Pauzauskie, Peter J.

doi:10.1016/j.jlumin.2021.118006

Title: The impact of ²H_9/2 → ⁴I_13/2 emission from Er³⁺ ions on ratiometric optical temperature sensing with Yb³⁺/Er³⁺ co-doped upconversion materials

Journal Article · Sat Mar 13 00:00:00 EST 2021 · Journal of Luminescence

DOI:https://doi.org/10.1016/j.jlumin.2021.118006· OSTI ID:1797393

^[1]; Volpi, Azzurra ^[2]; Roh, Joo D. ^[1];

^[3];

^[1];

^[4]; Pauzauskie, Peter J. ^[5]

Univ. of Washington, Seattle, WA (United States)
Univ. of New Mexico, Albuquerque, NM (United States)
Univ. of Washington, Seattle, WA (United States); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Univ. of Washington, Seattle, WA (United States); Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Yb³⁺/Er³⁺ co-doped upconversion materials are widely used for luminescence intensity ratio (LIR) thermometry, where the relative intensity ratio of the green luminescence transitions (²H_11/2 ⁴I_15/2 and ⁴S_3/2 ⁴I_15/2 ) of Er³⁺ dopant ions changes with temperature. In this work we report on the impact of an additional transition from the ²H_9/2 level to the intermediate ⁴I_13/2 level, which overlaps with the green luminescence normally used for LIR thermometry. The ²H_9/2 ⁴I_13/2 emission overlaps extensively with the ⁴S_3/2 ⁴I_15/2 emission and is more sensitive to pump power. The wavelength intervals used to integrate both ²H_11/2 ⁴I_15/2 and ⁴S_3/2 ⁴I_15/2 luminescence need be selected carefully in order to achieve accurate temperature readouts.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE; National Science Foundation (NSF); US Air Force Office of Scientific Research (AFOSR)

Grant/Contract Number:: AC05-76RL01830; NNCI-1542101

OSTI ID:: 1797393

Report Number(s):: PNNL-SA-160779

Journal Information:: Journal of Luminescence, Vol. 236; ISSN 0022-2313

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Title: The impact of 2H9/2 → 4I13/2 emission from Er3+ ions on ratiometric optical temperature sensing with Yb3+/Er3+ co-doped upconversion materials

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Title: The impact of ²H_9/2 → ⁴I_13/2 emission from Er³⁺ ions on ratiometric optical temperature sensing with Yb³⁺/Er³⁺ co-doped upconversion materials