Pressure-induced spin crossover in a Fe78Si9B13 metallic glass

Liang, Tao; Zhang, Fei; Zhang, Xin; Chen, Xiehang; Chen, Songyi; Lou, Hongbo; Zeng, Zhidan; Xu, Dazhe; Yang, Ke; Xiao, Yuming; Chow, Paul; Shen, Baolong; Zeng, Qiaoshi

doi:10.1063/5.0050830

Title: Pressure-induced spin crossover in a Fe₇₈Si₉B₁₃ metallic glass

Journal Article · Thu Apr 22 00:00:00 EDT 2021 · Journal of Applied Physics

DOI:https://doi.org/10.1063/5.0050830· OSTI ID:1788213

^[1];

^[2]; Zhang, Xin ^[3];

^[3]; Chen, Songyi ^[3];

^[3];

^[3]; Xu, Dazhe ^[3]; Yang, Ke ^[4]; Xiao, Yuming ^[5];

^[5]; Shen, Baolong ^[6];

^[1]

Southeast Univ., Nanjing (China); Center for High Pressure Science and Technology Advanced Research, Shanghai (China)
Center for High Pressure Science and Technology Advanced Research, Shanghai (China); Chinese Academy of Sciences, Dongguan (China)
Center for High Pressure Science and Technology Advanced Research, Shanghai (China)
Chinese Academy of Sciences, Shanghai (China)
Argonne National Lab. (ANL), Argonne, IL (United States)
Southeast Univ., Nanjing (China)

The pressure effect on structures and properties of a Fe₇₈Si₉B₁₃ metallic glass was investigated by in situ high-pressure synchrotron Fe Kβ x-ray emission spectroscopy and x-ray diffraction, and electrical resistivity measurements up to ~51 GPa. The study reveals a reversible and continuous pressure-induced high- to low-spin crossover of Fe atoms in an amorphous structure. The changes of the local spin moment can be scaled to match its average atomic distance shrinkage very well during compression. The crossover of electronic spin states in the Fe₇₈Si₉B₁₃ metallic glass resembles that of typical crystalline Fe-bearing materials but without a sharp atomic volume collapse and an abrupt electrical resistivity jump. Furthermore, these findings could help guide applications of Fe-based metallic glasses as a soft ferromagnetic material at extreme conditions and also improve our understanding of magnetism and coupling of its changes with disordered atomic structures and other properties in metallic glasses.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Natural Science Foundation of China (NSFC); USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC02-06CH11357; 51871054; U1930401

OSTI ID:: 1788213

Alternate ID(s):: OSTI ID: 1779545

Journal Information:: Journal of Applied Physics, Vol. 129, Issue 16; ISSN 0021-8979

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Title: Pressure-induced spin crossover in a Fe₇₈Si₉B₁₃ metallic glass