Dynamic infrared gas analysis from longleaf pine fuel beds burned in a wind tunnel: observation of phenol in pyrolysis and combustion phases

Banach, Catherine A.; Bradley, Ashley M.; Tonkyn, Russell G.; Williams, Olivia N.; Chong, Joey; Weise, David; Myers, Tanya L.; Johnson, Timothy J.

doi:10.5194/amt-14-2359-2021

Dynamic infrared gas analysis from longleaf pine fuel beds burned in a wind tunnel: observation of phenol in pyrolysis and combustion phases

Journal Article · Fri Mar 26 00:00:00 EDT 2021 · Atmospheric Measurement Techniques (Online)

DOI:https://doi.org/10.5194/amt-14-2359-2021· OSTI ID:1787479

^[1]; Bradley, Ashley M. ^[1]; Tonkyn, Russell G. ^[1]; Williams, Olivia N. ^[1]; Chong, Joey ^[2]; ^[2]; ^[1]; ^[1]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
USDA Forest Service, Riverside, CA (United States)

Pyrolysis is the first step in a series of chemical and physical processes that produce flammable organic gases from wildland fuels that can result in a wildland fire. We report results using a new time-resolved Fourier transform infrared (FTIR) method that correlates the measured FTIR spectrum with an infrared thermal image sequence, enabling the identification and quantification of gases within different phases of the fire process. The flame from burning fuel beds composed of pine needles (Pinus palustris) and mixtures of sparkleberry, fetterbush, and inkberry plants was the natural heat source for pyrolysis. Extractive gas samples were analyzed and identified in both static and dynamic modes synchronized to thermal infrared imaging: a total of 29 gases were identified including small alkanes, alkenes, aldehydes, nitrogen compounds, and aromatics, most previously measured by FTIR in wildland fires. This study presents one of the first identifications of phenol associated with both pre-combustion and combustion phases using ca. 1 Hz temporal resolution. Preliminary results indicate ~2.5× greater phenol emissions from sparkleberry and inkberry compared to fetterbush, with differing temporal profiles.

View Accepted Manuscript (DOE)

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1787479

Report Number(s):: PNNL-SA--155481

Journal Information:: Atmospheric Measurement Techniques (Online), Journal Name: Atmospheric Measurement Techniques (Online) Journal Issue: 3 Vol. 14; ISSN 1867-8548

Publisher:: Copernicus Publications, EGUCopyright Statement

Country of Publication:: United States

Language:: English

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