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Tailored porous carbons enabled by persistent micelles with glassy cores

Journal Article · · Materials Advances
DOI:https://doi.org/10.1039/D1MA00146A· OSTI ID:1787422

Herein, we report the unique usage of glassy core micelles for the fabrication of mesoporous carbons with independent control of the material wall thickness and the template dimensions.

Sponsoring Organization:
USDOE
Grant/Contract Number:
AC04-94AL85000; AC52-07NA27344; NA0003525
OSTI ID:
1787422
Alternate ID(s):
OSTI ID: 1798150
Journal Information:
Materials Advances, Journal Name: Materials Advances Journal Issue: 16 Vol. 2; ISSN MAADC9; ISSN 2633-5409
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (64)

Recent Progress in the Synthesis of Porous Carbon Materials journal August 2006
Carbon Materials for Chemical Capacitive Energy Storage journal September 2011
Nanoengineering of a Magnetically Separable Hydrogenation Catalyst journal August 2004
Synthesis of a Large-Scale Highly Ordered Porous Carbon Film by Self-Assembly of Block Copolymers journal November 2004
Ordered Mesoporous Polymers and Homologous Carbon Frameworks: Amphiphilic Surfactant Templating and Direct Transformation journal November 2005
Mesoporous Carbon Materials: Synthesis and Modification journal May 2008
Highly Ordered Mesoporous Carbonaceous Frameworks from a Template of a Mixed Amphiphilic Triblock-Copolymer System of PEO–PPO–PEO and Reverse PPO–PEO–PPO journal October 2007
The glass temperature and related properties of polystyrene. Influence of molecular weight journal September 1954
The dependence of glass transition temperature on molecular weight for poly(propylene oxide) and poly(butylene oxide) journal February 1965
Full Gamut Wall Tunability from Persistent Micelle Templates via Ex Situ Hydrolysis journal March 2019
Recent Advances in the Separation of Rare Earth Elements Using Mesoporous Hybrid Materials journal May 2018
Reaction steps in gas sorption by impregnated carbon journal January 1978
Activated carbon for gas separation and storage journal January 1996
Preparation of porous carbons from phenol–formaldehyde resins with chemical and physical activation journal January 2000
Synthesis of ordered mesoporous carbon films, powders, and fibers by direct triblock-copolymer-templating method using an ethanol/water system journal September 2009
Templated mesoporous carbons: Synthesis and applications journal October 2016
A review of adsorptive remediation of environmental pollutants from aqueous phase by ordered mesoporous carbon journal January 2021
Graphitization of phenolic resins for carbon-based refractories journal August 2017
Effect of furfural alcohol/phenol-formaldehyde resin mass ratio on the properties of porous carbon journal October 2013
A Graphitized-Carbon Monolithic Column journal September 2003
Ordered Mesoporous to Macroporous Oxides with Tunable Isomorphic Architectures: Solution Criteria for Persistent Micelle Templates journal February 2016
Expanded Kinetic Control for Persistent Micelle Templates with Solvent Selection journal April 2018
Control of Pore Size in Ordered Mesoporous Carbon-Silica by Hansen Solubility Parameters of Swelling Agent journal October 2019
Tuning H 2 S Release by Controlling Mobility in a Micelle Core journal January 2019
Nickel Nanofoam/Different Phases of Ordered Mesoporous Carbon Composite Electrodes for Superior Capacitive Energy Storage journal August 2016
Controlling Multicompartment Morphologies Using Solvent Conditions and Chemical Modification journal August 2016
Assembly of Hollow Carbon Nanospheres on Graphene Nanosheets and Creation of Iron–Nitrogen-Doped Porous Carbon for Oxygen Reduction journal May 2018
General Predictive Syntheses of Cubic, Hexagonal, and Lamellar Silica and Titania Mesostructured Thin Films § journal August 2002
A Family of Highly Ordered Mesoporous Polymer Resin and Carbon Structures from Organic−Organic Self-Assembly journal September 2006
Ultra-Large-Pore Mesoporous Carbons Templated from Poly(ethylene oxide)- b -Polystyrene Diblock Copolymer by Adding Polystyrene Homopolymer as a Pore Expander journal December 2008
Design of Amphiphilic ABC Triblock Copolymer for Templating Synthesis of Large-Pore Ordered Mesoporous Carbons with Tunable Pore Wall Thickness journal September 2009
Refractive Index of Ethanol–Water Mixtures and Density and Refractive Index of Ethanol–Water–Ethyl Ether Mixtures. journal May 1946
A Facile Aqueous Route to Synthesize Highly Ordered Mesoporous Polymers and Carbon Frameworks with Iad Bicontinuous Cubic Structure journal October 2005
Synthesis of Mesoporous Carbon Materials via Enhanced Hydrogen-Bonding Interaction journal April 2006
Ordered Mesoporous Silicas and Carbons with Large Accessible Pores Templated from Amphiphilic Diblock Copolymer Poly(ethylene oxide)- b -polystyrene journal February 2007
Nonionic Triblock and Star Diblock Copolymer and Oligomeric Surfactant Syntheses of Highly Ordered, Hydrothermally Stable, Mesoporous Silica Structures journal June 1998
Nanostructured Thermosets from Self-Assembled Amphiphilic Block Copolymer/Epoxy Resin Mixtures journal September 1998
Universal Conditions for the Controlled Polymerization of Acrylates, Methacrylates, and Styrene via Cu(0)-RDRP journal January 2017
Uniform Ordered Two-Dimensional Mesoporous TiO 2 Nanosheets from Hydrothermal-Induced Solvent-Confined Monomicelle Assembly journal February 2018
Versatile Nanoemulsion Assembly Approach to Synthesize Functional Mesoporous Carbon Nanospheres with Tunable Pore Sizes and Architectures journal April 2019
Ordered Nanoporous Carbons with Broadly Tunable Pore Size Using Bottlebrush Block Copolymer Templates journal September 2019
Density, Viscosity, Refractive Index, and Speed of Sound in Aqueous Mixtures of N,N-Dimethylformamide, Dimethyl Sulfoxide, N,N-Dimethylacetamide, Acetonitrile, Ethylene Glycol, Diethylene Glycol, 1,4-Dioxane, Tetrahydrofuran, 2-Methoxyethanol, and 2-Ethoxyethanol at 298.15 K journal July 1995
Drying of Organic Solvents: Quantitative Evaluation of the Efficiency of Several Desiccants journal December 2010
Adsorption of Gases and Vapors on Carbon Molecular Sieves journal July 1997
Molecular Exchange in Ordered Diblock Copolymer Micelles journal May 2011
Pore Size Control in Cross-Linked Polymer Resins by Reverse Micellar Imprinting journal May 1997
Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles journal July 2001
Novel synthesis of porous carbons with tunable pore size by surfactant-templated sol–gel process and carbonisation journal January 2002
Thick wall mesoporous carbons with a large pore structure templated from a weakly hydrophobic PEO–PMMA diblock copolymer journal January 2008
Direct synthesis of ordered mesoporous carbons journal January 2013
Porous carbon spheres and monoliths: morphology control, pore size tuning and their applications as Li-ion battery anode materials journal January 2014
Synthesis of mesoporous carbon nanoparticles with large and tunable pore sizes journal January 2015
Ordered mesoporous titania from highly amphiphilic block copolymers: tuned solution conditions enable highly ordered morphologies and ultra-large mesopores journal January 2015
Ordered mesoporous carbon and its applications for electrochemical energy storage and conversion journal January 2017
Recent advances in functionalized micro and mesoporous carbon materials: synthesis and applications journal January 2018
How to make persistent micelle templates in 24 hours and know it using X-ray scattering journal January 2017
Ordered mesoporous carbons from lignin: a new class of biobased electrodes for supercapacitors journal January 2019
Widely tunable persistent micelle templates via homopolymer swelling journal January 2019
Anionic surfactant induced mesophase transformation to synthesize highly ordered large-pore mesoporous silica structures journal January 2006
Catalyst-free soft-template synthesis of ordered mesoporous carbon tailored using phloroglucinol/glyoxylic acid environmentally friendly precursors journal January 2014
Second‐Order Transition Temperatures and Related Properties of Polystyrene. I. Influence of Molecular Weight journal June 1950
Mechanism of Molecular Exchange in Diblock Copolymer Micelles: Hypersensitivity to Core Chain Length journal January 2010
A Neutral Templating Route to Mesoporous Molecular Sieves journal February 1995
Carbon Structures with Three-Dimensional Periodicity at Optical Wavelengths journal October 1998

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