Mechanisms of water oxidation on heterogeneous catalyst surfaces

Yang, Xiaogang; Wang, Yuanxing; Li, Chang Ming; Wang, Dunwei

doi:10.1007/s12274-021-3607-5

Mechanisms of water oxidation on heterogeneous catalyst surfaces

Journal Article · Mon Jun 07 04:00:00 EDT 2021 · Nano Research

DOI:https://doi.org/10.1007/s12274-021-3607-5· OSTI ID:1787230

Yang, Xiaogang ^[1]; Wang, Yuanxing ^[2]; Li, Chang Ming ^[3]; Wang, Dunwei ^[2]

Suzhou Univ. of Science and Technology (China); Boston College
Boston College, Chestnut Hill, MA (United States)
Suzhou Univ. of Science and Technology (China); Southwest Univ., Chongqing (China)

Water oxidation, an essential step in photosynthesis, has attracted intense research attention. Understanding the reaction pathways at the electrocatalyst/water interface is of great importance for the development of water oxidation catalysts. How the water is oxidized on the electrocatalyst surface by the positive charges is still an open question. This review summarizes current advances in studies on surface chemistry within the context of water oxidation, including the intermediates, reaction mechanisms, and their influences on the reaction kinetics. The Tafel analyses of some electrocatalysts and the rate-laws relative to charge consumption rates are also presented. Moreover, how the multiple charge transfer relies on the intermediate coverage and the accumulated charge numbers is outlined. Finally, the intermediates and rate-determining steps on some water oxidation catalysts are discussed based on density functional theories.

View Accepted Manuscript (DOE)

Research Organization:: Boston College, Chestnut Hill, MA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: SC0020261

OSTI ID:: 1787230

Journal Information:: Nano Research, Journal Name: Nano Research Journal Issue: 10 Vol. 14; ISSN 1998-0124

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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Mechanisms of water oxidation on heterogeneous catalyst surfaces

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