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Low power threshold photochemical upconversion using a zirconium( iv ) LMCT photosensitizer

Journal Article · · Chemical Science
DOI:https://doi.org/10.1039/D1SC01662H· OSTI ID:1787115

The LMCT photosensitizer Zr( Mes PDP Ph ) 2 paired with DPA-based acceptors enabled low power threshold photochemical upconversion with record-setting quantum efficiencies.

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0011979
OSTI ID:
1787115
Alternate ID(s):
OSTI ID: 1786989
Journal Information:
Chemical Science, Journal Name: Chemical Science Journal Issue: 26 Vol. 12; ISSN 2041-6520; ISSN CSHCBM
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (77)

Photochemical Upconversion: Anthracene Dimerization Sensitized to Visible Light by a RuII Chromophore journal September 2006
Ruthenium(II) Polyimine-Coumarin Dyad with Non-emissive 3IL Excited State as Sensitizer for Triplet-Triplet Annihilation Based Upconversion journal July 2011
Activation of a Photodissociative Ruthenium Complex by Triplet-Triplet Annihilation Upconversion in Liposomes journal December 2013
Discovery of Key TIPS‐Naphthalene for Efficient Visible‐to‐UV Photon Upconversion under Sunlight and Room Light** journal November 2020
Towards the IR Limit of the Triplet-Triplet Annihilation-Supported Up-Conversion: Tetraanthraporphyrin journal November 2008
Ruthenium(II)–Polyimine–Coumarin Light‐Harvesting Molecular Arrays: Design Rationale and Application for Triplet–Triplet‐Annihilation‐Based Upconversion journal March 2012
Application of Visible-to-UV Photon Upconversion to Photoredox Catalysis: The Activation of Aryl Bromides journal September 2015
Ligand-Tuneable, Red-Emitting Iridium(III) Complexes for Efficient Triplet-Triplet Annihilation Upconversion Performance journal June 2018
Iridium(III) Sensitisers and Energy Upconversion: The Influence of Ligand Structure upon TTA‐UC Performance journal January 2021
Fluorescence of the antharacenes following Tn → T1 excitation studied by a double excitation method journal September 1976
Photon upconversion based on sensitized triplet–triplet annihilation journal November 2010
Visible-Light-Initiated Free-Radical Polymerization by Homomolecular Triplet-Triplet Annihilation journal November 2020
Efficient S2 state production in ZnTPP–PMMA thin films by triplet–triplet annihilation: Evidence of solute aggregation in photon upconversion systems journal June 2009
Homomolecular non-coherent photon upconversion by triplet–triplet annihilation using a zinc porphyrin on wide bandgap semiconductors journal April 2014
Recent advances of donor-acceptor type carbazole-based molecules for light emitting applications journal December 2019
High efficiency non-doped deep-blue and fluorescent/phosphorescent white organic light-emitting diodes based on an anthracene derivative journal May 2015
Effects of Ligand Substitution on the Optical and Electrochemical Properties of (Pyridinedipyrrolide)zirconium Photosensitizers journal September 2020
Efficient Visible to Near-UV Photochemical Upconversion Sensitized by a Long Lifetime Cu(I) MLCT Complex journal May 2015
Cuprous Phenanthroline MLCT Chromophore Featuring Synthetically Tailored Photophysics journal September 2016
Enhancing the Visible-Light Absorption and Excited-State Properties of Cu(I) MLCT Excited States journal February 2018
Transient Absorption Dynamics of Sterically Congested Cu(I) MLCT Excited States journal March 2015
Energy Transfer Dynamics in Triplet–Triplet Annihilation Upconversion Using a Bichromophoric Heavy-Atom-Free Sensitizer journal July 2018
Porphyrin–Anthracene Complexes: Potential in Triplet–Triplet Annihilation Upconversion journal August 2016
Intramolecular Triplet–Triplet Annihilation Upconversion in 9,10-Diphenylanthracene Oligomers and Dendrimers journal October 2016
Visible-Light-Driven Triplet Sensitization of Polycyclic Aromatic Hydrocarbons Using Thionated Perinones journal June 2020
Triplet–Triplet Annihilation-Based Upconversion Sensitized by a Reverse Micellar Assembly of Amphiphilic Ruthenium Complexes journal July 2019
CdSe Quantum Dot Sensitized Molecular Photon Upconversion Solar Cells journal November 2019
A Robust Visible-Light-Harvesting Cyclometalated Ir(III) Diimine Sensitizer for Homogeneous Photocatalytic Hydrogen Production journal January 2020
On the Quantum Yield of Photon Upconversion via Triplet–Triplet Annihilation journal June 2020
Triplet-Sensitization by Lead Halide Perovskite Thin Films for Near-Infrared-to-Visible Upconversion journal March 2019
Photon Upconversion from Near-Infrared to Blue Light with TIPS-Anthracene as an Efficient Triplet–Triplet Annihilator journal November 2019
Supra-Nanosecond Dynamics of a Red-to-Blue Photon Upconversion System journal March 2009
Electrolytic oxidation of 9,10-diphenylanthracene and properties of its free radical cation and anion journal July 1968
UV Light Generation and Challenging Photoreactions Enabled by Upconversion in Water journal May 2020
A Luminescent Zirconium(IV) Complex as a Molecular Photosensitizer for Visible Light Photoredox Catalysis journal September 2016
A Zirconium Photosensitizer with a Long-Lived Excited State: Mechanistic Insight into Photoinduced Single-Electron Transfer journal April 2018
Upconverted Emission from Pyrene and Di- tert -butylpyrene Using Ir(ppy) 3 as Triplet Sensitizer journal October 2006
Annihilation Limit of a Visible-to-UV Photon Upconversion Composition Ascertained from Transient Absorption Kinetics journal May 2013
Photophysics of Soret-Excited Tetrapyrroles in Solution. IV. Radiationless Decay and Triplet−Triplet Annihilation Investigated Using Tetraphenylporphinato Sn(IV) journal September 2009
Kinetic Analysis of Photochemical Upconversion by Triplet−Triplet Annihilation: Beyond Any Spin Statistical Limit journal May 2010
Getting to the (Square) Root of the Problem: How to Make Noncoherent Pumped Upconversion Linear journal January 2012
Photochemical Upconversion: The Primacy of Kinetics journal November 2014
Triplet Sensitized Red-to-Blue Photon Upconversion journal November 2009
Amplifying the Red-Emission of Upconverting Nanoparticles for Biocompatible Clinically Used Prodrug-Induced Photodynamic Therapy journal October 2014
Selective and Mutual Sensitization of Delayed Fluorescence journal March 1965
Amplified stimulated emission in upconversion nanoparticles for super-resolution nanoscopy journal February 2017
Thermally activated delayed photoluminescence from pyrenyl-functionalized CdSe quantum dots journal December 2017
Realization of high-efficiency fluorescent organic light-emitting diodes with low driving voltage journal May 2019
Delayed fluorescence from a zirconium(iv) photosensitizer with ligand-to-metal charge-transfer excited states journal March 2020
A bright future for photosensitizers journal March 2020
Photoredox catalysis using infrared light via triplet fusion upconversion journal January 2019
Anti-Stokes delayed fluorescence from metal–organic bichromophores journal January 2004
On the efficiency limit of triplet–triplet annihilation for photochemical upconversion journal January 2010
Upconversion-powered photoelectrochemistry journal January 2012
Visible light-absorbing rhenium( i ) tricarbonyl complexes as triplet photosensitizers in photooxidation and triplet–triplet annihilation upconversion journal January 2013
A bis-cyclometalated iridium complex as a benchmark sensitizer for efficient visible-to-UV photon upconversion journal January 2014
Non-symmetric 9,10-diphenylanthracene-based deep-blue emitters with enhanced charge transport properties journal January 2014
Triplet–triplet annihilation photon-upconversion: towards solar energy applications journal January 2014
Upconverting nanoparticles: a versatile platform for wide-field two-photon microscopy and multi-modal in vivo imaging journal January 2015
Photochemical upconversion: present status and prospects for its application to solar energy conversion journal January 2015
Photophysical characterization of the 9,10-disubstituted anthracene chromophore and its applications in triplet–triplet annihilation photon upconversion journal January 2015
Photochemical upconversion in water journal January 2017
Photoinduced structural distortions and singlet–triplet intersystem crossing in Cu( i ) MLCT excited states monitored by optically gated fluorescence spectroscopy journal January 2017
Determinants of the efficiency of photon upconversion by triplet–triplet annihilation in the solid state: zinc porphyrin derivatives in PVA journal January 2017
Sensitized photon upconversion in anthracene-based zirconium metal–organic frameworks journal January 2018
Nondoped blue fluorescent organic light-emitting diodes based on benzonitrile-anthracene derivative with 10.06% external quantum efficiency and low efficiency roll-off journal January 2019
Leaping across the visible range: near-infrared-to-violet photon upconversion employing a silyl-substituted anthracene journal January 2020
TIPS-pentacene triplet exciton generation on PbS quantum dots results from indirect sensitization journal January 2020
Low power upconversion using MLCT sensitizers journal January 2005
Reevaluation of absolute luminescence quantum yields of standard solutions using a spectrometer with an integrating sphere and a back-thinned CCD detector journal January 2009
Low power, non-coherent sensitized photon up-conversion: modelling and perspectives journal January 2012
Rhenium(i) tricarbonyl polypyridine complexes showing strong absorption of visible light and long-lived triplet excited states as a triplet photosensitizer for triplet–triplet annihilation upconversion journal January 2012
Upconversion-induced fluorescence in multicomponent systems: Steady-state excitation power threshold journal November 2008
Direct observation of triplet energy transfer from semiconductor nanocrystals journal January 2016
Electronic structure in the transition metal block and its implications for light harvesting journal January 2019
Electronic energy-pooling processes in polyatomic molecules journal March 1989
Highly efficient long-life blue fluorescent organic light-emitting diode exhibiting triplet–triplet annihilation effects enhanced by a novel hole-transporting material journal April 2014

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