Scorpionates of the “Tetrahedral Enforcer” Variety as Ancillary Ligands for Dinitrogen Complexes of First Row Transition Metals (Cr–Co)

Cummins, Daniel C.; Yap, Glenn P. A.; Theopold, Klaus H.

doi:10.1002/ejic.201501326

Scorpionates of the “Tetrahedral Enforcer” Variety as Ancillary Ligands for Dinitrogen Complexes of First Row Transition Metals (Cr–Co)

Journal Article · Thu Feb 18 00:00:00 EST 2016 · European Journal of Inorganic Chemistry

DOI:https://doi.org/10.1002/ejic.201501326· OSTI ID:1786702

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Department of Chemistry and Biochemistry University of Delaware 19716 Newark DE USA

Dinitrogen complexes of the first row transition metals Cr–Co supported by 2 ^nd generation hydrotris(pyrazolyl)borate (Tp ^R,R′ ) ligands were characterized by structure and reactivity. Compounds of the type (Tp ^R,R′ M) _n (N ₂ ) ( n = 1,2) were prepared and evaluated as precursors for small molecule activation, with specific application to reactions of O ₂ .

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: FG02-92ER14273

OSTI ID:: 1786702

Journal Information:: European Journal of Inorganic Chemistry, Journal Name: European Journal of Inorganic Chemistry Journal Issue: 15-16 Vol. 2016; ISSN 1434-1948

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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