Non‐Precious Metal Catalysts Prepared By Zeolitic Imidazolate Frameworks: The Ligand Influence to Morphology and Performance

Barkholtz, H. M.; Chong, L.; Kaiser, Z. B.; Liu, D. J.

doi:10.1002/fuce.201500164

Non‐Precious Metal Catalysts Prepared By Zeolitic Imidazolate Frameworks: The Ligand Influence to Morphology and Performance

Journal Article · Wed Jul 06 00:00:00 EDT 2016 · Fuel Cells

DOI:https://doi.org/10.1002/fuce.201500164· OSTI ID:1786410

Barkholtz, H. M.; Chong, L.; Kaiser, Z. B.; Liu, D. J.

Abstract

A new, “one‐pot” synthesis to produce highly active non‐PGM electrocatalysts for PEM fuel cells was previously developed by pyrolyzing Fe doped zeolitic imidazolate framework (ZIF) materials prepared by solid‐state interaction. Excellent catalytic oxygen reduction reaction (ORR) activities were found through rotating ring‐disk electrode (RRDE) and single fuel cell tests. In this study, we compared the ORR activities and structural properties of two catalysts derived from ZIFs containing imidazole and methyl imidazole ligands, respectively. Our results indicate that alkyl group substitution in the imidazolate ligand has a profound effect on the final catalyst performance.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

OSTI ID:: 1786410

Alternate ID(s):: OSTI ID: 1332999

Journal Information:: Fuel Cells, Journal Name: Fuel Cells Journal Issue: 4 Vol. 16; ISSN 1615-6846

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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