Asymmetric Volcano Trend in Oxygen Reduction Activity of Pt and Non-Pt Catalysts: In Situ Identification of the Site-Blocking Effect

Li, J; Alsudairi, A.; Ma, Z.; Mukerjee, S.; Jia, Q.

doi:10.1021/jacs.6b11072

Asymmetric Volcano Trend in Oxygen Reduction Activity of Pt and Non-Pt Catalysts: In Situ Identification of the Site-Blocking Effect

Journal Article · 31 December 2021 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.6b11072· OSTI ID:1786309

Li, J; Alsudairi, A.; Ma, Z.; Mukerjee, S.; Jia, Q.

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: ~OTHER

DOE Contract Number:: SC0012704

OSTI ID:: 1786309

Report Number(s):: BNL-221614-2021-JACI

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 4 Vol. 139; ISSN 0002-7863

Country of Publication:: United States

Language:: English

References (31)

A New Fuel Cell Cathode Catalyst Jasinski, Raymond Nature, Vol. 201, Issue 4925, p. 1212-1213 https://doi.org/10.1038/2011212a0	journal	March 1964
Activity Descriptor Identification for Oxygen Reduction on Platinum-Based Bimetallic Nanoparticles: In Situ Observation of the Linear Composition–Strain–Activity Relationship Jia, Qingying; Liang, Wentao; Bates, Michael K. ACS Nano, Vol. 9, Issue 1 https://doi.org/10.1021/nn506721f	journal	January 2015
A Possible Interpretation for the High Catalytic Activity of Heat-Treated Non-Precious Metal Nx/C Catalysts for O2 Reduction in Terms of Their Formal Potentials Zagal, José H.; Ponce, Ingrid; Baez, Daniela Electrochemical and Solid-State Letters, Vol. 15, Issue 6 https://doi.org/10.1149/2.032206esl	journal	January 2012
High-performance transition metal-doped Pt3Ni octahedra for oxygen reduction reaction Huang, X.; Zhao, Z.; Cao, L. Science, Vol. 348, Issue 6240 https://doi.org/10.1126/science.aaa8765	journal	June 2015
Defects do Catalysis: CO Monolayer Oxidation and Oxygen Reduction Reaction on Hollow PtNi/C Nanoparticles Dubau, Laetitia; Nelayah, Jaysen; Moldovan, Simona ACS Catalysis, Vol. 6, Issue 7 https://doi.org/10.1021/acscatal.6b01106	journal	June 2016
Elucidating Oxygen Reduction Active Sites in Pyrolyzed Metal–Nitrogen Coordinated Non-Precious-Metal Electrocatalyst Systems Tylus, Urszula; Jia, Qingying; Strickland, Kara The Journal of Physical Chemistry C, Vol. 118, Issue 17 https://doi.org/10.1021/jp500781v	journal	April 2014
Density functional studies of functionalized graphitic materials with late transition metals for oxygen reduction reactions Calle-Vallejo, Federico; Martínez, José Ignacio; Rossmeisl, Jan Physical Chemistry Chemical Physics, Vol. 13, Issue 34 https://doi.org/10.1039/c1cp21228a	journal	January 2011
The redox mechanism of the chelate-catalysed oxygen cathode Beck, F. Journal of Applied Electrochemistry, Vol. 7, Issue 3 https://doi.org/10.1007/BF00618991	journal	May 1977
Activity Descriptor Identification for Oxygen Reduction on Nonprecious Electrocatalysts: Linking Surface Science to Coordination Chemistry Ramaswamy, Nagappan; Tylus, Urszula; Jia, Qingying Journal of the American Chemical Society, Vol. 135, Issue 41 https://doi.org/10.1021/ja405149m	journal	October 2013
Experimental Observation of Redox-Induced Fe–N Switching Behavior as a Determinant Role for Oxygen Reduction Activity Jia, Qingying; Ramaswamy, Nagappan; Hafiz, Hasnain ACS Nano, Vol. 9, Issue 12 https://doi.org/10.1021/acsnano.5b05984	journal	October 2015
Generation of Active Sites by Potential-Driven Surface Processes: A Central Aspect of Electrocatalysis Gottesfeld, S. ECS Transactions, Vol. 61, Issue 31 https://doi.org/10.1149/06131.0001ecst	journal	September 2014
On the effect of a heat treatment on the structure of carbon-supported metalloporphyrins and phthalocyanines van Veen, J. A. R.; Colijn, H. A.; van Baar, J. F. Electrochimica Acta, Vol. 33, Issue 6 https://doi.org/10.1016/S0013-4686(98)80010-8	journal	June 1988
Just a Dream—or Future Reality? Gasteiger, Hubert A.; Marković, Nenad M Science, Vol. 324, Issue 5923, p. 48-49 https://doi.org/10.1126/science.1172083	journal	April 2009
Improved Oxygen Reduction Activity on Pt₃Ni(111) via Increased Surface Site Availability Stamenkovic, V. R.; Fowler, B.; Mun, B. S. Science, Vol. 315, Issue 5811, p. 493-497 https://doi.org/10.1126/science.1135941	journal	January 2007
Steady state oxygenreduction and cyclic voltammetry Rossmeisl, Jan; Karlberg, Gustav S.; Jaramillo, Thomas Faraday Discuss., Vol. 140 https://doi.org/10.1039/B802129E	journal	January 2009
Effect of heat treatment on the performance of carbon-supported transition-metal chelates in the electrochemical reduction of oxygen van Veen, J. A. Rob; van Baar, Jan F.; Kroese, Kees J. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 77, Issue 11 https://doi.org/10.1039/f19817702827	journal	January 1981
Oxygen Reduction on Carbon-Supported Pt−Ni and Pt−Co Alloy Catalysts Paulus, U. A.; Wokaun, A.; Scherer, G. G. The Journal of Physical Chemistry B, Vol. 106, Issue 16 https://doi.org/10.1021/jp013442l	journal	April 2002
Spectroscopic insights into the nature of active sites in iron–nitrogen–carbon electrocatalysts for oxygen reduction in acid Jia, Qingying; Ramaswamy, Nagappan; Tylus, Urszula Nano Energy, Vol. 29 https://doi.org/10.1016/j.nanoen.2016.03.025	journal	November 2016
Electrochemical surface area measurements of platinum- and palladium-based nanoparticles Shao, Minhua; Odell, Jonathan H.; Choi, Sang-Il Electrochemistry Communications, Vol. 31 https://doi.org/10.1016/j.elecom.2013.03.011	journal	June 2013
Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs Gasteiger, Hubert A.; Kocha, Shyam S.; Sompalli, Bhaskar Applied Catalysis B: Environmental, Vol. 56, Issue 1-2, p. 9-35 https://doi.org/10.1016/j.apcatb.2004.06.021	journal	March 2005
Changing the Activity of Electrocatalysts for Oxygen Reduction by Tuning the Surface Electronic Structure Stamenkovic, Vojislav; Mun, Bongjin Simon; Mayrhofer, Karl J. J. Angewandte Chemie, Vol. 118, Issue 18 https://doi.org/10.1002/ange.200504386	journal	April 2006
Quantifying the density and utilization of active sites in non-precious metal oxygen electroreduction catalysts Sahraie, Nastaran Ranjbar; Kramm, Ulrike I.; Steinberg, Julian Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9618	journal	October 2015
A Mechanistic Study of O[sub 2] Reduction on Water Soluble Phthalocyanines Adsorbed on Graphite Electrodes Zagal, J. Journal of The Electrochemical Society, Vol. 127, Issue 7 https://doi.org/10.1149/1.2129940	journal	January 1980
Understanding the electrocatalysis of oxygen reduction on platinum and its alloys Stephens, Ifan E. L.; Bondarenko, Alexander S.; Grønbjerg, Ulrik Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee03590a	journal	January 2012
Structural and mechanistic basis for the high activity of Fe–N–C catalysts toward oxygen reduction Li, Jingkun; Ghoshal, Shraboni; Liang, Wentao Energy & Environmental Science, Vol. 9, Issue 7 https://doi.org/10.1039/C6EE01160H	journal	January 2016
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode Nørskov, J. K.; Rossmeisl, J.; Logadottir, A. The Journal of Physical Chemistry B, Vol. 108, Issue 46 https://doi.org/10.1021/jp047349j	journal	November 2004
Does CO poison Fe-based catalysts for ORR? Birry, Laurent; Zagal, José H.; Dodelet, Jean-Pol Electrochemistry Communications, Vol. 12, Issue 5 https://doi.org/10.1016/j.elecom.2010.02.016	journal	May 2010
Redox potential and electrocatalysis of O2 reduction on transition metal chelates van der Putten, A.; Elzing, A.; Visscher, W. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 221, Issue 1-2 https://doi.org/10.1016/0022-0728(87)80248-6	journal	April 1987
Reactivity Descriptors for the Activity of Molecular MN4 Catalysts for the Oxygen Reduction Reaction Zagal, José H.; Koper, Marc T. M. Angewandte Chemie International Edition, Vol. 55, Issue 47 https://doi.org/10.1002/anie.201604311	journal	September 2016
Pt-Oxide Coverage-Dependent Oxygen Reduction Reaction (ORR) Kinetics Subramanian, N. P.; Greszler, T. A.; Zhang, J. Journal of The Electrochemical Society, Vol. 159, Issue 5 https://doi.org/10.1149/2.088205jes	journal	January 2012
Oxygen reduction on vacuum-deposited and absorbed transition-metal phthalocyanine films Van Der Putten, A.; Elzing, A.; Visscher, W. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 214, Issue 1-2 https://doi.org/10.1016/0022-0728(86)80121-8	journal	December 1986

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