Photoelektronenspektroskopie an der Graphen‐Flüssigelektrolyt‐Grenzfläche zur Bestimmung der elektronischen Struktur eines elektrochemisch abgeschiedenen Cobalt/Graphen‐Elektrokatalysators

Velasco‐Velez, Juan J.; Pfeifer, Verena; Hävecker, Michael; Weatherup, Robert S.; Arrigo, Rosa; Chuang, Cheng‐Hao; Stotz, Eugen; Weinberg, Gisela; Salmeron, Miquel; Schlögl, Robert; Knop‐Gericke, Axel

doi:10.1002/ange.201506044

Photoelektronenspektroskopie an der Graphen‐Flüssigelektrolyt‐Grenzfläche zur Bestimmung der elektronischen Struktur eines elektrochemisch abgeschiedenen Cobalt/Graphen‐Elektrokatalysators (in German)

Journal Article · Wed Oct 14 00:00:00 EDT 2015 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201506044· OSTI ID:1786064

Velasco‐Velez, Juan J.; Pfeifer, Verena; Hävecker, Michael; Weatherup, Robert S.; Arrigo, Rosa; Chuang, Cheng‐Hao; Stotz, Eugen; Weinberg, Gisela; Salmeron, Miquel; Schlögl, Robert; Knop‐Gericke, Axel

Abstract

Elektrochemisch gewachsenes Cobalt auf Graphen weist außergewöhnliche Katalysatoreigenschaften für die Sauerstoffentwicklungsreaktion (OER) auf und bietet die Möglichkeit, die Morphologie und die chemischen Eigenschaften während der Abscheidung zu kontrollieren. Es gibt allerdings noch kein ausreichendes Verständnis der atomaren Struktur dieses Hybridmaterials. Um die elektronische Struktur von Co/Graphen aufzuklären, haben wir eine Durchflusszelle entwickelt, die durch eine Graphenmembran abgeschlossen wird und elektronische und chemische Informationen über die aktiven Oberflächen unter atmosphärischem Druck und in der Gegenwart von flüssigen Elektrolyten unter Verwendung von Röntgenphotoelektronenspektroskopie (XPS) liefert. Wir konnten zeigen, dass Cobalt an Graphen über Carbonyl‐ähnliche Spezies bindet, d. h. Co(CO) _x , und so die Reduktion von Co ³⁺ zu Co ²⁺ fördert, das als aktives Zentrum des Katalysators vermutet wird.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1786064

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 48 Vol. 127; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: German

References (50)

In-situ-Studie der Gasphasen-Wasserelektrolyse auf Platin mittels NAP-XPS Arrigo, Rosa; Hävecker, Michael; Schuster, Manfred E. Angewandte Chemie, Vol. 125, Issue 44 https://doi.org/10.1002/ange.201304765	journal	September 2013
In Situ Observation of Surface Species on Iridium Oxide Nanoparticles during the Oxygen Evolution Reaction Sanchez Casalongue, Hernan G.; Ng, May Ling; Kaya, Sarp Angewandte Chemie, Vol. 126, Issue 28 https://doi.org/10.1002/ange.201402311	journal	May 2014
In Situ Study of the Gas-Phase Electrolysis of Water on Platinum by NAP-XPS Arrigo, Rosa; Hävecker, Michael; Schuster, Manfred E. Angewandte Chemie International Edition, Vol. 52, Issue 44 https://doi.org/10.1002/anie.201304765	journal	September 2013
In Situ Observation of Surface Species on Iridium Oxide Nanoparticles during the Oxygen Evolution Reaction Sanchez Casalongue, Hernan G.; Ng, May Ling; Kaya, Sarp Angewandte Chemie International Edition, Vol. 53, Issue 28 https://doi.org/10.1002/anie.201402311	journal	May 2014
XPS Structural Studies of Nano-composite Non-platinum Electrocatalysts for Polymer Electrolyte Fuel Cells Artyushkova, Kateryna; Levendosky, Stephen; Atanassov, Plamen Topics in Catalysis, Vol. 46, Issue 3-4 https://doi.org/10.1007/s11244-007-9002-y	journal	November 2007
The free energy of transfer of Pb(II) ion and electrode kinetics of the Pb(II)/Pb(Hg) system in dimethyl sulfoxide (DMSO) and DMSO-water mixtures Broda, A.; Stroka, J.; Galus, Z. Electrochimica Acta, Vol. 28, Issue 6 https://doi.org/10.1016/0013-4686(83)85153-6	journal	June 1983
Cyclic voltammetric studies of pure and doped films of cobalt hydroxide in 1 M KOH Ismail, J.; Ahmed, M. F.; Vishnu Kamath, P. Journal of Power Sources, Vol. 36, Issue 4 https://doi.org/10.1016/0378-7753(91)80076-A	journal	December 1991
Influence of the coordination sphere on the mechanism of cobalt nucleation onto glassy carbon Palomar-Pardavé, Manuel; González, Ignacio; Soto, Ana B. Journal of Electroanalytical Chemistry, Vol. 443, Issue 1 https://doi.org/10.1016/S0022-0728(97)00496-8	journal	February 1998
Co-ZSM-5 catalysts for N2O decomposition da Cruz, R. S.; Mascarenhas, A. J. S.; Andrade, H. M. C. Applied Catalysis B: Environmental, Vol. 18, Issue 3-4 https://doi.org/10.1016/S0926-3373(98)00042-3	journal	October 1998
Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni Biesinger, Mark C.; Payne, Brad P.; Grosvenor, Andrew P. Applied Surface Science, Vol. 257, Issue 7, p. 2717-2730 https://doi.org/10.1016/j.apsusc.2010.10.051	journal	January 2011
Co-based catalysts from Co/Fe/Al layered double hydroxides for preparation of carbon nanotubes Xiang, X.; Zhang, L.; Hima, H. Applied Clay Science, Vol. 42, Issue 3-4 https://doi.org/10.1016/j.clay.2008.04.004	journal	January 2009
Non-platinum oxygen reduction electrocatalysts based on pyrolyzed transition metal macrocycles Pylypenko, Svitlana; Mukherjee, Sanjoy; Olson, Tim S. Electrochimica Acta, Vol. 53, Issue 27 https://doi.org/10.1016/j.electacta.2008.05.047	journal	November 2008
Morphology and chemical state of Co?Mo catalysts for growth ofBsingle-walled carbon nanotubes vertically aligned on quartz substrates Hu, M. Journal of Catalysis, Vol. 225, Issue 1 https://doi.org/10.1016/j.jcat.2004.04.013	journal	July 2004
Graphene/metal oxide composite electrode materials for energy storage Wu, Zhong-Shuai; Zhou, Guangmin; Yin, Li-Chang Nano Energy, Vol. 1, Issue 1 https://doi.org/10.1016/j.nanoen.2011.11.001	journal	January 2012
Ambient pressure photoelectron spectroscopy: A new tool for surface science and nanotechnology Salmeron, M.; Schlogl, R. Surface Science Reports, Vol. 63, Issue 4 https://doi.org/10.1016/j.surfrep.2008.01.001	journal	April 2008
Sol–gel cobalt oxide–silica nanocomposite thin films for gas sensing applications Musat, V.; Fortunato, E.; Botelho do Rego, A. M. Thin Solid Films, Vol. 516, Issue 7 https://doi.org/10.1016/j.tsf.2007.07.197	journal	February 2008
CVD-Enabled Graphene Manufacture and Technology Hofmann, Stephan; Braeuninger-Weimer, Philipp; Weatherup, Robert S. The Journal of Physical Chemistry Letters, Vol. 6, Issue 14 https://doi.org/10.1021/acs.jpclett.5b01052	journal	June 2015
Mechanistic Investigation on Self-redox Decompositions of Cobalt−Hydroxide−Nitrate Compounds with Different Nitrate Anion Configurations in Interlayer Space Xu, Rong; Zeng, Hua Chun Chemistry of Materials, Vol. 15, Issue 10 https://doi.org/10.1021/cm021732o	journal	May 2003
Solar Water Splitting Cells Walter, Michael G.; Warren, Emily L.; McKone, James R. Chemical Reviews, Vol. 110, Issue 11, p. 6446-6473 https://doi.org/10.1021/cr1002326	journal	November 2010
A Bifunctional Nonprecious Metal Catalyst for Oxygen Reduction and Water Oxidation Gorlin, Yelena; Jaramillo, Thomas F. Journal of the American Chemical Society, Vol. 132, Issue 39, p. 13612-13614 https://doi.org/10.1021/ja104587v	journal	October 2010
Oxygen Reduction Electrocatalyst Based on Strongly Coupled Cobalt Oxide Nanocrystals and Carbon Nanotubes Liang, Yongye; Wang, Hailiang; Diao, Peng Journal of the American Chemical Society, Vol. 134, Issue 38 https://doi.org/10.1021/ja305623m	journal	September 2012
Stable Cobalt Nanoparticles and Their Monolayer Array as an Efficient Electrocatalyst for Oxygen Evolution Reaction Wu, Liheng; Li, Qing; Wu, Cheng Hao Journal of the American Chemical Society, Vol. 137, Issue 22 https://doi.org/10.1021/jacs.5b04142	journal	June 2015
The Parameter Space of Graphene Chemical Vapor Deposition on Polycrystalline Cu Kidambi, Piran R.; Ducati, Caterina; Dlubak, Bruno The Journal of Physical Chemistry C, Vol. 116, Issue 42 https://doi.org/10.1021/jp303597m	journal	October 2012
High-Loading Cobalt Oxide Coupled with Nitrogen-Doped Graphene for Oxygen Reduction in Anion-Exchange-Membrane Alkaline Fuel Cells He, Qinggang; Li, Qing; Khene, Samson The Journal of Physical Chemistry C, Vol. 117, Issue 17 https://doi.org/10.1021/jp401814f	journal	April 2013
Polarized X-ray Absorption Spectroscopy Observation of Electronic and Structural Changes of Chemical Vapor Deposition Graphene in Contact with Water Velasco-Velez, J. J.; Wu, C. H.; Wang, B. Y. The Journal of Physical Chemistry C, Vol. 118, Issue 44 https://doi.org/10.1021/jp507405z	journal	October 2014
Anion-Exchange Membrane Fuel Cells: Dual-Site Mechanism of Oxygen Reduction Reaction in Alkaline Media on Cobalt−Polypyrrole Electrocatalysts Olson, Tim S.; Pylypenko, Svitlana; Atanassov, Plamen The Journal of Physical Chemistry C, Vol. 114, Issue 11 https://doi.org/10.1021/jp910572g	journal	March 2010
Synthesis and Activities of Rutile IrO ₂ and RuO ₂ Nanoparticles for Oxygen Evolution in Acid and Alkaline Solutions Lee, Youngmin; Suntivich, Jin; May, Kevin J. The Journal of Physical Chemistry Letters, Vol. 3, Issue 3 https://doi.org/10.1021/jz2016507	journal	January 2012
Graphene-Based Nanoarchitectures. Anchoring Semiconductor and Metal Nanoparticles on a Two-Dimensional Carbon Support Kamat, Prashant V. The Journal of Physical Chemistry Letters, Vol. 1, Issue 2 https://doi.org/10.1021/jz900265j	journal	December 2009
Predictive Modeling of Electrocatalyst Structure Based on Structure-to-Property Correlations of X-ray Photoelectron Spectroscopic and Electrochemical Measurements Artyushkova, Kateryna; Pylypenko, Svitlana; Olson, Tim S. Langmuir, Vol. 24, Issue 16 https://doi.org/10.1021/la801089m	journal	August 2008
Anchoring Semiconductor and Metal Nanoparticles on a Two-Dimensional Catalyst Mat. Storing and Shuttling Electrons with Reduced Graphene Oxide Lightcap, Ian V.; Kosel, Thomas H.; Kamat, Prashant V. Nano Letters, Vol. 10, Issue 2 https://doi.org/10.1021/nl9035109	journal	February 2010
Kinetic Control of Catalytic CVD for High-Quality Graphene at Low Temperatures Weatherup, Robert S.; Dlubak, Bruno; Hofmann, Stephan ACS Nano, Vol. 6, Issue 11 https://doi.org/10.1021/nn303674g	journal	October 2012
Direct observation of the oxygenated species during oxygen reduction on a platinum fuel cell cathode Casalongue, Hernan Sanchez; Kaya, Sarp; Viswanathan, Venkatasubramanian Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3817	journal	December 2013
Concentration and chemical-state profiles at heterogeneous interfaces with sub-nm accuracy from standing-wave ambient-pressure photoemission Nemšák, Slavomír; Shavorskiy, Andrey; Karslioglu, Osman Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6441	journal	November 2014
Co₃O₄ nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction Liang, Yongye; Li, Yanguang; Wang, Hailiang Nature Materials, Vol. 10, Issue 10, p. 780-786 https://doi.org/10.1038/nmat3087	journal	August 2011
A Janus cobalt-based catalytic material for electro-splitting of water Cobo, Saioa; Heidkamp, Jonathan; Jacques, Pierre-André Nature Materials, Vol. 11, Issue 9 https://doi.org/10.1038/nmat3385	journal	August 2012
Graphene oxide windows for in situ environmental cell photoelectron spectroscopy Kolmakov, Andrei; Dikin, Dmitriy A.; Cote, Laura J. Nature Nanotechnology, Vol. 6, Issue 10 https://doi.org/10.1038/nnano.2011.130	journal	August 2011
Graphene-based materials for catalysis Machado, Bruno F.; Serp, Philippe Catal. Sci. Technol., Vol. 2, Issue 1 https://doi.org/10.1039/C1CY00361E	journal	January 2012
Carbon-based nanostructured materials and their composites as supercapacitor electrodes Bose, Saswata; Kuila, Tapas; Mishra, Ananta Kumar J. Mater. Chem., Vol. 22, Issue 3 https://doi.org/10.1039/C1JM14468E	journal	January 2012
Graphene–inorganic nanocomposites Bai, Song; Shen, Xiaoping RSC Adv., Vol. 2, Issue 1 https://doi.org/10.1039/C1RA00260K	journal	January 2012
High-performance bi-functional electrocatalysts of 3D crumpled graphene–cobalt oxide nanohybrids for oxygen reduction and evolution reactions Mao, Shun; Wen, Zhenhai; Huang, Taizhong Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/C3EE42696C	journal	January 2014
Aqueous solution/metal interfaces investigated in operando by photoelectron spectroscopy Karslıoğlu, O.; Nemšák, S.; Zegkinoglou, I. Faraday Discussions, Vol. 180 https://doi.org/10.1039/C5FD00003C	journal	January 2015
Electrocatalysis at Co–poly(difluoropyrrole) electrodeposited on Vulcan carbon supports: demonstration of halogenated polypyrrole as an electrocatalytic material Pietron, Jeremy J.; Biffinger, Justin C.; Qadri, Syed B. Journal of Materials Chemistry, Vol. 21, Issue 21 https://doi.org/10.1039/c1jm10393h	journal	January 2011
Chemical interaction and imaging of single Co3O4/graphene sheets studied by scanning transmission X-ray microscopy and X-ray absorption spectroscopy Wang, Jian; Zhou, Jigang; Hu, Yongfeng Energy & Environmental Science, Vol. 6, Issue 3 https://doi.org/10.1039/c2ee23844f	journal	January 2013
Investigation of solid/vapor interfaces using ambient pressure X-ray photoelectron spectroscopy Starr, D. E.; Liu, Z.; Hävecker, M. Chemical Society Reviews, Vol. 42, Issue 13 https://doi.org/10.1039/c3cs60057b	journal	January 2013
Incorporation of cobaltocene as an n-dopant in organic molecular films Chan, Calvin K.; Kahn, Antoine; Zhang, Qing Journal of Applied Physics, Vol. 102, Issue 1 https://doi.org/10.1063/1.2752145	journal	July 2007
Energy Resources and Global Development Chow, J. Science, Vol. 302, Issue 5650 https://doi.org/10.1126/science.1091939	journal	November 2003
Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction Gong, K.; Du, F.; Xia, Z. Science, Vol. 323, Issue 5915, p. 760-764 https://doi.org/10.1126/science.1168049	journal	February 2009
The structure of interfacial water on gold electrodes studied by x-ray absorption spectroscopy Velasco-Velez, J. -J.; Wu, C. H.; Pascal, T. A. Science, Vol. 346, Issue 6211 https://doi.org/10.1126/science.1259437	journal	October 2014
Hydrogen and Oxygen Evolutions on Ru-Ir Binary Oxides Wen, Ten-Chin Journal of The Electrochemical Society, Vol. 139, Issue 8 https://doi.org/10.1149/1.2221195	journal	January 1992
In-Situ XAS Investigation of the Effect of Electrochemical Reactions on the Structure of Graphene in Aqueous Electrolytes Velasco-Velez, Juan J.; Chuang, Cheng-Hao; Han, Hui-Ling Journal of The Electrochemical Society, Vol. 160, Issue 9 https://doi.org/10.1149/2.113309jes	journal	January 2013

Similar Records

Modifikation eines Cu‐Pd‐Schaufelrad‐Metall‐Organischen Gerüsts für die selektive CO ₂ ‐Elektroreduktion

Journal Article · Fri Nov 15 19:00:00 EST 2024 · Angewandte Chemie · OSTI ID:2480380

Druckeffekte auf organische Reaktionen in Fluiden – eine neue theoretische Perspektive

Journal Article · Sun Jul 23 20:00:00 EDT 2017 · Angewandte Chemie · OSTI ID:1377942

Produktion von Methanol und Ethanol aus Methan in einem einzigen Reaktor mit einem Nickeloxid auf Ceroxid‐Zirconiumoxid‐Katalysator

Journal Article · Mon Sep 25 20:00:00 EDT 2017 · Angewandte Chemie · OSTI ID:1394848

Photoelektronenspektroskopie an der Graphen‐Flüssigelektrolyt‐Grenzfläche zur Bestimmung der elektronischen Struktur eines elektrochemisch abgeschiedenen Cobalt/Graphen‐Elektrokatalysators (in German)

Citation Formats

References (50)

Similar Records

Related Subjects