Giant Domain Wall Conductivity in Self‐Assembled BiFeO 3 Nanocrystals

Liu, Lisha; Xu, Kun; Li, Qian; Daniels, John; Zhou, Hua; Li, Jiangyu; Zhu, Jing; Seidel, Jan; Li, Jing‐Feng

doi:10.1002/adfm.202005876

Title: Giant Domain Wall Conductivity in Self‐Assembled BiFeO ₃ Nanocrystals

Journal Article · Thu Sep 24 00:00:00 EDT 2020 · Advanced Functional Materials

DOI:https://doi.org/10.1002/adfm.202005876· OSTI ID:1785758

Liu, Lisha ^[1]; Xu, Kun ^[2]; Li, Qian ^[1]; Daniels, John ^[3]; Zhou, Hua ^[4]; Li, Jiangyu ^[5]; Zhu, Jing ^[2]; Seidel, Jan ^[6];

^[1]

State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and Engineering Tsinghua University Beijing 100084 P. R. China
National Center for Electron Microscopy in Beijing The State Key Laboratory of New Ceramics and Fine Processing Key Laboratory of Advanced Materials (MOE) School of Materials Science and Engineering Tsinghua University Beijing 100084 P. R. China
School of Materials Science and Engineering UNSW Sydney Sydney NSW 2052 Australia
X‐ray Science Division Advanced Photon Source Argonne National Laboratory 9700 S. Cass Avenue Lemont IL 60439 USA
Shenzhen Key Laboratory of Nanobiomechanics Shenzhen Institutes of Advanced Technology Chinese Academy of Sciences Shenzhen Guangdong 518055 China, Department of Materials Science and Engineering Southern University of Science and Technology Shenzhen Guangdong 518055 China
School of Materials Science and Engineering UNSW Sydney Sydney NSW 2052 Australia, ARC Centre of Excellence in Future Low‐Energy Electronics Technologies UNSW Sydney Sydney NSW 2052 Australia

Abstract Ever‐increasing demand on electronic devices with ultrahigh‐density non‐volatile data storage has attracted great interest in novel ferroelectric memories based on conductive ferroelectric domain walls. Embedded in an insulating material, ferroelectric domain walls have the capability of being (re)created, displaced, erased, and altered in their spatial configurations and electronic characteristics. However, the domain wall conductivities are in most cases not yet sufficiently high to ensure the current density required to drive read‐out circuits operating at high speeds. In this work, a giant domain wall current (>10 µA) of a single charged domain wall is obtained through conductive atomic force microscopy with a bias field of 4 V. This is achieved in self‐assembled BiFeO ₃ nanocrystals grown by sol‐gel method on Nb‐doped SrTiO ₃ substrates. Local configurations of domains and domain wall types are studied using vector piezoresponse force microscopy and high‐resolution transmission electronic microscopy. The enhancement of the wall current is shown to be due to the formation of conducting pathways of charged defects accumulated along domain walls and traversing the nanocrystals. The diverse domain walls can be manipulated by electric field in a perpendicular architecture. The perpendicular array structure of BiFeO ₃ nanocrystals should have great potentials for developing perpendicular nanoelectronic prototypes.

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE

OSTI ID:: 1785758

Journal Information:: Advanced Functional Materials, Journal Name: Advanced Functional Materials Vol. 31 Journal Issue: 1; ISSN 1616-301X

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (61)

Next-generation ferroelectric domain-wall memories: principle and architecture Jiang, An Quan; Zhang, Yan NPG Asia Materials, Vol. 11, Issue 1 https://doi.org/10.1038/s41427-018-0102-x	journal	January 2019
A Strain-Driven Morphotropic Phase Boundary in BiFeO₃ Zeches, R. J.; Rossell, M. D.; Zhang, J. X. Science, Vol. 326, Issue 5955, p. 977-980 https://doi.org/10.1126/science.1177046	journal	November 2009
Oxide Interfaces--An Opportunity for Electronics Mannhart, J.; Schlom, D. G. Science, Vol. 327, Issue 5973, p. 1607-1611 https://doi.org/10.1126/science.1181862	journal	March 2010
Domain Wall Architecture in Tetragonal Ferroelectric Thin Films De Luca, Gabriele; Rossell, Marta D.; Schaab, Jakob Advanced Materials, Vol. 29, Issue 7 https://doi.org/10.1002/adma.201605145	journal	December 2016
Spin coating epitaxial films Kelso, Meagan V.; Mahenderkar, Naveen K.; Chen, Qingzhi Science, Vol. 364, Issue 6436 https://doi.org/10.1126/science.aaw6184	journal	April 2019
Potassium‐Sodium‐Niobate‐Based Thin Films: Lead Free for Micro‐Piezoelectrics Zhang, Su‐Wei; Zhou, Zhen; Luo, Jin Annalen der Physik, Vol. 531, Issue 7 https://doi.org/10.1002/andp.201800525	journal	March 2019
Electrical Tunability of Domain Wall Conductivity in LiNbO ₃ Thin Films Lu, Haidong; Tan, Yueze; McConville, James P. V. Advanced Materials, Vol. 31, Issue 48 https://doi.org/10.1002/adma.201902890	journal	October 2019
Magnetism at the interface between ferromagnetic and superconducting oxides Chakhalian, J.; Freeland, J. W.; Srajer, G. Nature Physics, Vol. 2, Issue 4 https://doi.org/10.1038/nphys272	journal	April 2006
Thickness Dependence of Switching Behavior in Ferroelectric BiFeO3 Thin Films: A Phase-Field Simulation Cao, Guoping; Huang, Houbing; Ma, Xingqiao Applied Sciences, Vol. 7, Issue 11 https://doi.org/10.3390/app7111162	journal	November 2017
High-temperature interface superconductivity between metallic and insulating copper oxides Gozar, A.; Logvenov, G.; Kourkoutis, L. Fitting Nature, Vol. 455, Issue 7214, p. 782-785 https://doi.org/10.1038/nature07293	journal	October 2008
Injection and controlled motion of conducting domain walls in improper ferroelectric Cu-Cl boracite McQuaid, Raymond G. P.; Campbell, Michael P.; Whatmore, Roger W. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15105	journal	May 2017
Hall effect in charged conducting ferroelectric domain walls Campbell, M. P.; McConville, J. P. V.; McQuaid, R. G. P. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13764	journal	December 2016
Conduction at domain walls in oxide multiferroics Seidel, J.; Martin, L. W.; He, Q. Nature Materials, Vol. 8, Issue 3 https://doi.org/10.1038/nmat2373	journal	January 2009
Anisotropic conductance at improper ferroelectric domain walls Meier, D.; Seidel, J.; Cano, A. Nature Materials, Vol. 11, Issue 4 https://doi.org/10.1038/nmat3249	journal	February 2012
Physics and Applications of Bismuth Ferrite Catalan, Gustau; Scott, James F. Advanced Materials, Vol. 21, Issue 24 https://doi.org/10.1002/adma.200802849	journal	June 2009
Real-time observation of filamentary conduction pathways in Ca-doped BiFeO ₃ Park, Heung-Sik; Lim, Ji Soo; Suh, Jeonghun Applied Physics Letters, Vol. 115, Issue 18 https://doi.org/10.1063/1.5124892	journal	October 2019
First-principles study of ferroelectric domain walls in multiferroic bismuth ferrite Lubk, Axel; Gemming, S.; Spaldin, N. A. Physical Review B, Vol. 80, Issue 10 https://doi.org/10.1103/PhysRevB.80.104110	journal	September 2009
Temporary formation of highly conducting domain walls for non-destructive read-out of ferroelectric domain-wall resistance switching memories Jiang, Jun; Bai, Zi Long; Chen, Zhi Hui Nature Materials, Vol. 17, Issue 1 https://doi.org/10.1038/nmat5028	journal	November 2017
Phase structure of epitaxial Pb(Zr,Ti)O3 thin films on Nb-doped SrTiO3 substrates Zhu, Zhi-Xiang; Li, Jing-Feng; Lai, Feng-Ping Applied Physics Letters, Vol. 91, Issue 22 https://doi.org/10.1063/1.2819613	journal	November 2007
Conduction at Domain Walls in Insulating Pb(Zr0.2Ti0.8)O3 Thin Films Guyonnet, Jill; Gaponenko, Iaroslav; Gariglio, Stefano Advanced Materials, Vol. 23, Issue 45 https://doi.org/10.1002/adma.201102254	journal	September 2011
Understanding the Nature of Ultrafast Polarization Dynamics of Ferroelectric Memory in the Multiferroic BiFeO ₃ Rana, Dhanvir Singh; Kawayama, Iwao; Mavani, Krushna Advanced Materials, Vol. 21, Issue 28 https://doi.org/10.1002/adma.200802094	journal	July 2009
Analysis of multi-domain ferroelectric switching in BiFeO3 thin film using phase-field method Cao, Guoping; Cao, Ye; Huang, Houbing Computational Materials Science, Vol. 115 https://doi.org/10.1016/j.commatsci.2015.11.021	journal	April 2016
Electronic Properties of Isosymmetric Phase Boundaries in Highly Strained Ca-Doped BiFeO ₃ Seidel, Jan; Trassin, Morgan; Zhang, Yi Advanced Materials, Vol. 26, Issue 25 https://doi.org/10.1002/adma.201400557	journal	April 2014
Domain walls of ferroelectric ${BaTiO}_{3}$ within the Ginzburg-Landau-Devonshire phenomenological model Marton, P.; Rychetsky, I.; Hlinka, J. Physical Review B, Vol. 81, Issue 14 https://doi.org/10.1103/PhysRevB.81.144125	journal	April 2010
Polarization switching in epitaxial BiFeO3 films Zavaliche, F.; Shafer, P.; Ramesh, R. Applied Physics Letters, Vol. 87, Issue 25 https://doi.org/10.1063/1.2149180	journal	December 2005
Tunable Metallic Conductance in Ferroelectric Nanodomains Maksymovych, Peter; Morozovska, Anna N.; Yu, Pu Nano Letters, Vol. 12, Issue 1 https://doi.org/10.1021/nl203349b	journal	December 2011
Domain Dynamics During Ferroelectric Switching Nelson, C. T.; Gao, P.; Jokisaari, J. R. Science, Vol. 334, Issue 6058 https://doi.org/10.1126/science.1206980	journal	November 2011
Ferroelectric Domain Wall Memristor McConville, James P. V.; Lu, Haidong; Wang, Bo Advanced Functional Materials, Vol. 30, Issue 28 https://doi.org/10.1002/adfm.202000109	journal	May 2020
Experimental demonstration of hybrid improper ferroelectricity and the presence of abundant charged walls in (Ca,Sr)3Ti2O7 crystals Oh, Yoon Seok; Luo, Xuan; Huang, Fei-Ting Nature Materials, Vol. 14, Issue 4 https://doi.org/10.1038/nmat4168	journal	January 2015
Manipulation of Conductive Domain Walls in Confined Ferroelectric Nanoislands Tian, Guo; Yang, Wenda; Song, Xiao Advanced Functional Materials, Vol. 29, Issue 32 https://doi.org/10.1002/adfm.201807276	journal	May 2019
Conducting Domain Walls in Lithium Niobate Single Crystals Schröder, Mathias; Haußmann, Alexander; Thiessen, Andreas Advanced Functional Materials, Vol. 22, Issue 18 https://doi.org/10.1002/adfm.201201174	journal	May 2012
Vector Piezoresponse Force Microscopy Kalinin, Sergei V.; Rodriguez, Brian J.; Jesse, Stephen Microscopy and Microanalysis, Vol. 12, Issue 03 https://doi.org/10.1017/S1431927606060156	journal	May 2006
Polarization charge as a reconfigurable quasi-dopant in ferroelectric thin films Crassous, Arnaud; Sluka, Tomas; Tagantsev, Alexander K. Nature Nanotechnology, Vol. 10, Issue 7 https://doi.org/10.1038/nnano.2015.114	journal	June 2015
Ferroelastic switching for nanoscale non-volatile magnetoelectric devices Baek, S. H.; Jang, H. W.; Folkman, C. M. Nature Materials, Vol. 9, Issue 4 https://doi.org/10.1038/nmat2703	journal	February 2010
Thermal Agitation of Electric Charge in Conductors Nyquist, H. Physical Review, Vol. 32, Issue 1 https://doi.org/10.1103/PhysRev.32.110	journal	July 1928
Piezoresponse force microscopy (PFM) Soergel, Elisabeth Journal of Physics D: Applied Physics, Vol. 44, Issue 46, Article No. 464003 https://doi.org/10.1088/0022-3727/44/46/464003	journal	November 2011
Hierarchical Domain Structure and Extremely Large Wall Current in Epitaxial BiFeO ₃ Thin Films Bai, Zi Long; Cheng, Xiao Xing; Chen, Dong Fang Advanced Functional Materials, Vol. 28, Issue 31 https://doi.org/10.1002/adfm.201801725	journal	June 2018
Evidence of Sharp and Diffuse Domain Walls in ${BiFeO}_{3}$ by Means of Unit-Cell-Wise Strain and Polarization Maps Obtained with High Resolution Scanning Transmission Electron Microscopy Lubk, A.; Rossell, M. D.; Seidel, J. Physical Review Letters, Vol. 109, Issue 4 https://doi.org/10.1103/PhysRevLett.109.047601	journal	July 2012
Nanoelectronics based on topological structures Seidel, Jan Nature Materials, Vol. 18, Issue 3 https://doi.org/10.1038/s41563-019-0301-z	journal	February 2019
Interface Physics in Complex Oxide Heterostructures Zubko, Pavlo; Gariglio, Stefano; Gabay, Marc Annual Review of Condensed Matter Physics, Vol. 2, Issue 1 https://doi.org/10.1146/annurev-conmatphys-062910-140445	journal	March 2011
Conduction through 71° Domain Walls in ${BiFeO}_{3}$ Thin Films Farokhipoor, S.; Noheda, B. Physical Review Letters, Vol. 107, Issue 12 https://doi.org/10.1103/PhysRevLett.107.127601	journal	September 2011
Resonant electron tunnelling assisted by charged domain walls in multiferroic tunnel junctions Sanchez-Santolino, Gabriel; Tornos, Javier; Hernandez-Martin, David Nature Nanotechnology, Vol. 12, Issue 7 https://doi.org/10.1038/nnano.2017.51	journal	April 2017
Domain-wall conduction in ferroelectric BiFeO3 controlled by accumulation of charged defects Rojac, Tadej; Bencan, Andreja; Drazic, Goran Nature Materials, Vol. 16, Issue 3 https://doi.org/10.1038/nmat4799	journal	November 2016
Domain wall conductivity in oxygen deficient multiferroic YMnO ₃ single crystals Du, Y.; Wang, X. L.; Chen, D. P. Applied Physics Letters, Vol. 99, Issue 25 https://doi.org/10.1063/1.3671393	journal	December 2011
Domain wall conductivity in KTiOPO ₄ crystals Lindgren, G.; Canalias, C. APL Materials, Vol. 5, Issue 7 https://doi.org/10.1063/1.4995651	journal	July 2017
Domain Wall Conductivity in La-Doped ${BiFeO}_{3}$ Seidel, J.; Maksymovych, P.; Batra, Y. Physical Review Letters, Vol. 105, Issue 19, Article No. 197603 https://doi.org/10.1103/PhysRevLett.105.197603	journal	November 2010
Free-electron gas at charged domain walls in insulating BaTiO3 Sluka, Tomas; Tagantsev, Alexander K.; Bednyakov, Petr Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2839	journal	May 2013
Domain wall nanoelectronics Catalan, G.; Seidel, J.; Ramesh, R. Reviews of Modern Physics, Vol. 84, Issue 1 https://doi.org/10.1103/RevModPhys.84.119	journal	February 2012
Conductivity of twin-domain-wall/surface junctions in ferroelastics: Interplay of deformation potential, octahedral rotations, improper ferroelectricity, and flexoelectric coupling Eliseev, Eugene A.; Morozovska, Anna N.; Gu, Yijia Physical Review B, Vol. 86, Issue 8 https://doi.org/10.1103/PhysRevB.86.085416	journal	August 2012
Piezoresponse force microscopy and recent advances in nanoscale studies of ferroelectrics Gruverman, A.; Kalinin, S. V. Journal of Materials Science, Vol. 41, Issue 1 https://doi.org/10.1007/s10853-005-5946-0	journal	January 2006
A detailed understanding of the electronic bipolar resistance switching behavior in Pt/TiO ₂ /Pt structure Kim, Kyung Min; Choi, Byung Joon; Lee, Min Hwan Nanotechnology, Vol. 22, Issue 25 https://doi.org/10.1088/0957-4484/22/25/254010	journal	May 2011
Tunable Quasi-Two-Dimensional Electron Gases in Oxide Heterostructures Thiel, S. Science, Vol. 313, Issue 5795, p. 1942-1945 https://doi.org/10.1126/science.1131091	journal	September 2006
Nonvolatile ferroelectric domain wall memory Sharma, Pankaj; Zhang, Qi; Sando, Daniel Science Advances, Vol. 3, Issue 6 https://doi.org/10.1126/sciadv.1700512	journal	June 2017
Giant Resistive Switching via Control of Ferroelectric Charged Domain Walls Li, Linze; Britson, Jason; Jokisaari, Jacob R. Advanced Materials, Vol. 28, Issue 31 https://doi.org/10.1002/adma.201600160	journal	May 2016
Deterministic switching of ferromagnetism at room temperature using an electric field Heron, J. T.; Bosse, J. L.; He, Q. Nature, Vol. 516, Issue 7531 https://doi.org/10.1038/nature14004	journal	December 2014
Pressureless densification and properties of TiB ₂ –B ₄ C composite ceramics with Ni as additives Ma, Li; Yu, Jincheng; Guo, Xue Micro & Nano Letters, Vol. 13, Issue 7 https://doi.org/10.1049/mnl.2017.0709	journal	July 2018
A nanoscale shape memory oxide Zhang, Jinxing; Ke, Xiaoxing; Gou, Gaoyang Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3768	journal	November 2013
A Review on Conduction Mechanisms in Dielectric Films Chiu, Fu-Chien Advances in Materials Science and Engineering, Vol. 2014 https://doi.org/10.1155/2014/578168	journal	January 2014
Large and accessible conductivity of charged domain walls in lithium niobate Werner, Christoph S.; Herr, Simon J.; Buse, Karsten Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-09703-2	journal	August 2017
High-temperature carrier transport and thermoelectric properties of heavily La- or Nb-doped SrTiO3 single crystals Ohta, Shingo; Nomura, Takashi; Ohta, Hiromichi Journal of Applied Physics, Vol. 97, Issue 3 https://doi.org/10.1063/1.1847723	journal	February 2005
Critical thickness for ferroelectricity in perovskite ultrathin films Junquera, Javier; Ghosez, Philippe Nature, Vol. 422, Issue 6931, p. 506-509 https://doi.org/10.1038/nature01501	journal	April 2003

Similar Records

Hierarchical Domain Structure and Extremely Large Wall Current in Epitaxial BiFeO ₃ Thin Films

Journal Article · Wed Jun 06 00:00:00 EDT 2018 · Advanced Functional Materials · OSTI ID:1785758

Bai, Zi Long; Cheng, Xiao Xing; Chen, Dong Fang; +5 more

Unexpected Giant Microwave Conductivity in a Nominally Silent BiFeO₃ Domain Wall

Journal Article · Wed Jan 22 00:00:00 EST 2020 · Advanced Materials · OSTI ID:1785758

Huang, Yen‐Lin; Zheng, Lu; Chen, Peng; +10 more

Ferroelectric Domain Studies of Patterned (001) BiFeO₃ by Angle-Resolved Piezoresponse Force Microscopy

Journal Article · Tue Jan 09 00:00:00 EST 2018 · Scientific Reports · OSTI ID:1785758

Kim, Bumsoo; Barrows, Frank P.; Sharma, Yogesh; +5 more

Title: Giant Domain Wall Conductivity in Self‐Assembled BiFeO 3 Nanocrystals

Citation Formats

References (61)

Similar Records

Related Subjects

Title: Giant Domain Wall Conductivity in Self‐Assembled BiFeO ₃ Nanocrystals