Nontraditional Catalyst Supports in Surface Organometallic Chemistry

Witzke, Ryan J.; Chapovetsky, Alon; Conley, Matthew P.; Kaphan, David M.; Delferro, Massimiliano

doi:10.1021/acscatal.0c03350

Nontraditional Catalyst Supports in Surface Organometallic Chemistry

Journal Article · Mon Sep 14 00:00:00 EDT 2020 · ACS Catalysis

DOI:https://doi.org/10.1021/acscatal.0c03350· OSTI ID:1785726

Witzke, Ryan J. ^[1]; Chapovetsky, Alon ^[1]; ^[2]; ^[1]; ^[1]

Argonne National Lab. (ANL), Argonne, IL (United States)
Univ. of California, Riverside, CA (United States)

The field of Surface Organometallic Chemistry (SOMC) aims to blend the positive attributes of homogeneous and heterogeneous catalysis. Significant insight into heterogeneous systems has been gained over the years through the synthesis, characterization, and application of well-defined surface organometallic catalysts, predominantly supported on silica and alumina. Considerable research efforts have focused on the application of homogeneous methods to the synthesis and characterization of these systems. Homogeneous catalysis has thrived on its ability to electronically and sterically tune ligands to yield desired reactivity and selectivity. Efforts in SOMC, however, have only recently turned to harnessing the stereoelectronic diversity of potential inorganic support materials beyond silica and alumina in order to exert similar control on the reactivity of the organometallic active site. The support material is intrinsically linked to electronic structure and reactivity of heterogeneous organometallic systems in the same way that ligands exert control over homogeneous catalyst systems. The ability to tune the reactivity of heterogeneous catalysts by changing the support is of great value, and it is anticipated that this will represent an area of significant growth in the field. In this Perspective, the use and future of nontraditional catalyst supports, such as sulfated metal oxides, modified silicas, and redox active supports are discussed.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1785726

Journal Information:: ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 20 Vol. 10; ISSN 2155-5435

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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