Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

An advanced low-cost cathode composed of graphene-coated Na2.4Fe1.8(SO4)3 nanograins in a 3D graphene network for ultra-stable sodium storage

Journal Article · · Journal of Energy Chemistry
 [1];  [2];  [3];  [3];  [1];  [2];  [4];  [4];  [4];  [1];  [1]
  1. Wuhan Univ. (China). Engineering Research Center of Organosilicon Compounds & Materials
  2. City Univ. of Hong Kong, Kowloon (Hong Kong)
  3. Zhengzhou Univ. (China)
  4. Argonne National Lab. (ANL), Lemont, IL (United States). Advanced Photon Source (APS)
+ Show Author Affiliations
Iron-based electrodes have attracted great attention for sodium storage because of the distinct cost effectiveness. However, exploring suitable iron-based electrodes with high power density and long duration remains a big challenge. Herein, a spray-drying strategy is adopted to construct graphene-coated Na2.4Fe1.8(SO4)3 nanograins in a 3D graphene microsphere network. The unique structural and compositional advantages endow these electrodes to exhibit outstanding electrochemical properties with remarkable rate performance and long cycle life. Additionally, mechanism analyses further explain the outstanding electrochemical properties from the structural aspect.
Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
National Key R&D Program of China; National Natural Science Foundation of China (NSFC); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1785724
Journal Information:
Journal of Energy Chemistry, Journal Name: Journal of Energy Chemistry Vol. 54; ISSN 2095-4956
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (54)

Na 2 FeP 2 O 7 as a Promising Iron-Based Pyrophosphate Cathode for Sodium Rechargeable Batteries: A Combined Experimental and Theoretical Study journal October 2012
Reversible Sodium Ion Insertion in Single Crystalline Manganese Oxide Nanowires with Long Cycle Life journal June 2011
Hierarchical Carbon Framework Wrapped Na 3 V 2 (PO 4 ) 3 as a Superior High-Rate and Extended Lifespan Cathode for Sodium-Ion Batteries journal August 2015
Carbon Quantum Dots and Their Derivative 3D Porous Carbon Frameworks for Sodium-Ion Batteries with Ultralong Cycle Life journal October 2015
Phosphate Framework Electrode Materials for Sodium Ion Batteries journal January 2017
3D Graphene Decorated NaTi 2 (PO 4 ) 3 Microspheres as a Superior High-Rate and Ultracycle-Stable Anode Material for Sodium Ion Batteries journal June 2016
Layer-by-Layer Na 3 V 2 (PO 4 ) 3 Embedded in Reduced Graphene Oxide as Superior Rate and Ultralong-Life Sodium-Ion Battery Cathode journal May 2016
Recent Progress on Spray Pyrolysis for High Performance Electrode Materials in Lithium and Sodium Rechargeable Batteries journal December 2016
Sodium-Ion Batteries: From Academic Research to Practical Commercialization journal September 2017
Layered Oxide Cathodes for Sodium-Ion Batteries: Phase Transition, Air Stability, and Performance journal November 2017
Next Generation Batteries: Aim for the Future journal December 2017
A Novel Graphene Oxide Wrapped Na 2 Fe 2 (SO 4 ) 3 /C Cathode Composite for Long Life and High Energy Density Sodium-Ion Batteries journal August 2018
A Practical High-Energy Cathode for Sodium-Ion Batteries Based on Uniform P2-Na 0.7 CoO 2 Microspheres journal April 2017
Formation of Polypyrrole-Coated Sb 2 Se 3 Microclips with Enhanced Sodium-Storage Properties journal July 2018
Off-Stoichiometry in Alluaudite-Type Sodium Iron Sulfate Na 2+2 x Fe 2− x (SO 4 ) 3 as an Advanced Sodium Battery Cathode Material journal April 2015
3D Interconnected Carbon Fiber Network-Enabled Ultralong Life Na 3 V 2 (PO 4 ) 3 @Carbon Paper Cathode for Sodium-Ion Batteries journal December 2016
Recent Progress in Iron-Based Electrode Materials for Grid-Scale Sodium-Ion Batteries journal January 2018
High performance TiP2O7 nanoporous microsphere as anode material for aqueous lithium-ion batteries journal December 2018
Hierarchical sodium-rich Prussian blue hollow nanospheres as high-performance cathode for sodium-ion batteries journal January 2018
Recent Advances in Sodium-Ion Battery Materials journal June 2018
IR and polarized Raman spectra of K2Mg(SO4)2 · 6H2O journal February 1987
Ni3(BO3)2 as anode material with high capacity and excellent rate performance for sodium-ion batteries journal May 2019
Improved cycle and air stability of P3-Na0.65Mn0.75Ni0.25O2 electrode for sodium-ion batteries coated with metal phosphates journal September 2019
FeS2 nanoparticles embedded in N/S co-doped porous carbon fibers as anode for sodium-ion batteries journal January 2020
A Fully Sodiated NaVOPO4 with Layered Structure for High-Voltage and Long-Lifespan Sodium-Ion Batteries journal May 2018
Insights into the Improved High-Voltage Performance of Li-Incorporated Layered Oxide Cathodes for Sodium-Ion Batteries journal September 2018
Synthesis and electrode performance of carbon coated Na2FePO4F for rechargeable Na batteries journal November 2011
Reversible NaFePO4 electrode for sodium secondary batteries journal August 2012
Sodium iron pyrophosphate: A novel 3.0V iron-based cathode for sodium-ion batteries journal October 2012
An alluaudite Na2+2xFe2−x(SO4)3(x=0.2) derivative phase as insertion host for lithium battery journal February 2015
Reduced graphene oxide wrapped alluaudite Na2+2xFe2-x(SO4)3 with high rate sodium ion storage properties journal July 2018
Facile synthesis of hierarchical Na2Fe(SO4)2@rGO/C as high-voltage cathode for energy density-enhanced sodium-ion batteries journal November 2020
Carbon coated hollow Na2FePO4F spheres for Na-ion battery cathodes journal February 2013
Realizing a highly stable sodium battery with dendrite-free sodium metal composite anodes and O3-type cathodes journal June 2018
Na-Ion Battery Anodes: Materials and Electrochemistry journal January 2016
Sodium Intercalation Mechanism of 3.8 V Class Alluaudite Sodium Iron Sulfate journal July 2016
High-Performance Olivine NaFePO 4 Microsphere Cathode Synthesized by Aqueous Electrochemical Displacement Method for Sodium Ion Batteries journal August 2015
Ionothermal Synthesis of High-Voltage Alluaudite Na 2+2x Fe 2-x (SO 4 ) 3 Sodium Insertion Compound: Structural, Electronic, and Magnetic Insights journal March 2016
Double-Nanocarbon Synergistically Modified Na 3 V 2 (PO 4 ) 3 : An Advanced Cathode for High-Rate and Long-Life Sodium-Ion Batteries journal June 2016
3.0 V High Energy Density Symmetric Sodium-Ion Battery: Na 4 V 2 (PO 4 ) 3 ∥Na 3 V 2 (PO 4 ) 3 journal March 2018
Chalcopyrite-Derived Na x MO 2 (M = Cu, Fe, Mn) Cathode: Tuning Impurities for Self-Doping journal December 2019
Electrode Materials of Sodium-Ion Batteries toward Practical Application journal June 2018
Monoclinic Phase Na 3 Fe 2 (PO 4 ) 3 : Synthesis, Structure, and Electrochemical Performance as Cathode Material in Sodium-Ion Batteries journal December 2016
Insight into the Multirole of Graphene in Preparation of High Performance Na 2+2 x Fe 2– x (SO 4 ) 3 Cathodes journal October 2018
Low-Surface-Area Hard Carbon Anode for Na-Ion Batteries via Graphene Oxide as a Dehydration Agent journal January 2015
Porous Amorphous FePO 4 Nanoparticles Connected by Single-Wall Carbon Nanotubes for Sodium Ion Battery Cathodes journal October 2012
Carbon-Coated Na 3 V 2 (PO 4 ) 3 Embedded in Porous Carbon Matrix: An Ultrafast Na-Storage Cathode with the Potential of Outperforming Li Cathodes journal March 2014
Mesoporous Amorphous FePO 4 Nanospheres as High-Performance Cathode Material for Sodium-Ion Batteries journal May 2014
A 3.8-V earth-abundant sodium battery electrode journal July 2014
Eldfellite, NaFe(SO 4 ) 2 : an intercalation cathode host for low-cost Na-ion batteries journal January 2015
Top-down synthesis of muscle-inspired alluaudite Na 2+2x Fe 2−x (SO 4 ) 3 /SWNT spindle as a high-rate and high-potential cathode for sodium-ion batteries journal January 2016
Polypyrrole-promoted superior cyclability and rate capability of Na x Fe[Fe(CN) 6 ] cathodes for sodium-ion batteries journal January 2016
A high voltage cathode of Na 2+2x Fe 2−x (SO 4 ) 3 intensively protected by nitrogen-doped graphene with improved electrochemical performance of sodium storage journal January 2018
Recent Developments in Cathode Materials for Na Ion Batteries journal January 2017

Similar Records

Operando studies reveal active Cu nanograins for CO2 electroreduction
Journal Article · Wed Feb 08 00:00:00 UTC 2023 · Nature (London) · OSTI ID:2293522
Three-dimensional graphene/LiFePO{sub 4} nanostructures as cathode materials for flexible lithium-ion batteries
Journal Article · Tue Oct 15 04:00:00 UTC 2013 · Materials Research Bulletin · OSTI ID:22285098

Related Subjects

25 ENERGY STORAGE
Cathode
Na2.4Fe1.8(SO4)3
Polyanions
Sodium-ion batteries
Spray-drying