Divanadium substituted keggin [PV2W10O40] on non-reducible supports-Al2O3 and SiO2: synthesis, characterization, and catalytic properties for oxidative dehydrogenation of propane

Orozco, José C.; Shuaib, Damola T.; Marshall, Christopher L.; Khan, M. Ishaque

doi:10.1007/s11144-020-01893-7

Divanadium substituted keggin [PV₂W₁₀O₄₀] on non-reducible supports-Al₂O₃ and SiO₂: synthesis, characterization, and catalytic properties for oxidative dehydrogenation of propane

Journal Article · Sat Oct 24 00:00:00 EDT 2020 · Reaction Kinetics, Mechanisms and Catalysis

DOI:https://doi.org/10.1007/s11144-020-01893-7· OSTI ID:1785349

Orozco, José C. ^[1]; Shuaib, Damola T. ^[1]; Marshall, Christopher L. ^[2]; ^[1]

Illinois Institute of Technology, Chicago, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

Molecular metal oxide cluster, K₅[α-1,2-PV₂W₁₀O₄₀] (PV₂W₁₀), was found to have intrinsic catalytic activity for the oxidative dehydrogenation of propane with high selectivity (> 80%) to propylene at low propane conversion (0.3%). Synthesis of dispersed PV₂W₁₀ in non-reducible supports, γ-Al₂O₃ and SiO₂, was done by incipient wetness impregnation. The supported catalysts were characterized by IR, Raman spectroscopy, nitrogen adsorption, x-ray powder diffraction (PXRD), elemental analysis, hydrogen temperature-programmed reduction (H₂–TPR), and ammonia temperature-programmed desorption (NH₃–TPD). Catalytic testing of the supported PV₂W₁₀ at equimolar cluster concentration revealed that when supported in γ-Al₂O₃ it is more active (sevenfold increase in propane conversion) but in SiO₂ it is more selective to propylene (94%). The observed performance was due to both an increase in reducibility and higher concentration of strong acid sites for PV₂W₁₀ supported in γ-Al₂O₃ versus SiO₂. Lastly, PV₂W10 was shown to remain intact under reaction conditions indicating its thermal and oxidative stability.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1785349

Journal Information:: Reaction Kinetics, Mechanisms and Catalysis, Journal Name: Reaction Kinetics, Mechanisms and Catalysis Journal Issue: 2 Vol. 131; ISSN 1878-5190

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

References (38)

Polyoxovanadometalate-Catalyzed Selective Epoxidation of Alkenes with Hydrogen Peroxide Nakagawa, Yoshinao; Kamata, Keigo; Kotani, Miyuki Angewandte Chemie International Edition, Vol. 44, Issue 32 https://doi.org/10.1002/anie.200500491	journal	August 2005
Vanadium Oxide Based Nanostructured Materials: Novel Oxidative Dehydrogenation Catalysts Ishaque Khan, M.; Deb, Sangita; Marshall, Christopher L. Catalysis Letters, Vol. 128, Issue 3-4 https://doi.org/10.1007/s10562-008-9701-4	journal	October 2008
Vanadium Oxide Based Nanostructured Materials for Catalytic Oxidative Dehydrogenation of Propane: Effect of Heterometallic Centers on the Catalyst Performance Khan, M. Ishaque; Deb, Sangita; Aydemir, Kadir Catalysis Letters, Vol. 135, Issue 3-4 https://doi.org/10.1007/s10562-010-0275-6	journal	February 2010
Oxidative Dehydrogenation Properties of Novel Nanostructured Polyoxovanadate Based Materials Khan, M. Ishaque; Aydemir, Kadir; Siddiqui, M. Rafiq H. Catalysis Letters, Vol. 141, Issue 4 https://doi.org/10.1007/s10562-011-0547-9	journal	January 2011
Development of Dehydrogenation Catalysts and Processes Vora, Bipin V. Topics in Catalysis, Vol. 55, Issue 19-20 https://doi.org/10.1007/s11244-012-9917-9	journal	November 2012
Solid state NMR and IR studies of phosphomolybdenum and phosphotungsten heteropoly acids supported on SiO2, $gamma;-Al2O3, and SiO2$z.sbnd;Al2O3 Rao, K. Journal of Catalysis, Vol. 119, Issue 2 https://doi.org/10.1016/0021-9517(89)90179-6	journal	October 1989
Al-O infrared vibrational frequencies of γ-alumina Saniger, JoséM. Materials Letters, Vol. 22, Issue 1-2 https://doi.org/10.1016/0167-577X(94)00234-7	journal	January 1995
Factors controlling the selectivity of V2O5 supported catalysts in the oxidative dehydrogenation of propane Martra, Gianmario; Arena, Franco; Coluccia, Salvatore Catalysis Today, Vol. 63, Issue 2-4 https://doi.org/10.1016/S0920-5861(00)00460-0	journal	December 2000
Acid catalysts prepared by impregnation of tungstophosphoric acid solutions on different supports Pizzio, L. R.; Cáceres, C. V.; Blanco, M. N. Applied Catalysis A: General, Vol. 167, Issue 2 https://doi.org/10.1016/S0926-860X(97)00328-1	journal	February 1998
Hydroxylation of benzene catalyzed by selectively site-substituted vanadium(V) heteropolytungstates in the presence of hydrogen peroxide Nomiya, Kenji; Yanagibayashi, Hiroto; Nozaki, Chika Journal of Molecular Catalysis A: Chemical, Vol. 114, Issue 1-3 https://doi.org/10.1016/S1381-1169(96)00316-0	journal	December 1996
Multicenter active sites of vanadium-substituted polyoxometalate catalysts on benzene hydroxylation with hydrogen peroxide and two reaction types with and without an induction period Nomiya, Kenji; Nemoto, Yukihiro; Hasegawa, Takeshi Journal of Molecular Catalysis A: Chemical, Vol. 152, Issue 1-2 https://doi.org/10.1016/S1381-1169(99)00283-6	journal	March 2000
An experimental assessment of the ammonia temperature programmed desorption method for probing the surface acidic properties of heterogeneous catalysts Arena, Francesco; Chio, Roberto Di; Trunfio, Giuseppe Applied Catalysis A: General, Vol. 503 https://doi.org/10.1016/j.apcata.2015.05.035	journal	August 2015
Oxidative dehydrogenation of ethane and propane: How far from commercial implementation? Cavani, F.; Ballarini, N.; Cericola, A. Catalysis Today, Vol. 127, Issue 1-4, p. 113-131 https://doi.org/10.1016/j.cattod.2007.05.009	journal	September 2007
Catalytic oxidation of hydrocarbons with hydrogen peroxide by vanadium-based polyoxometalates Mizuno, Noritaka; Kamata, Keigo Coordination Chemistry Reviews, Vol. 255, Issue 19-20 https://doi.org/10.1016/j.ccr.2011.01.041	journal	October 2011
Vibrational study of interaction between 12-tungstophosphoric acid and microporous/mesoporous supports Bajuk-Bogdanović, Danica; Popa, Alexandru; Uskoković-Marković, Snezana Vibrational Spectroscopy, Vol. 92 https://doi.org/10.1016/j.vibspec.2017.06.007	journal	September 2017
Aerobic Oxidations of Light Alkanes over Solid Metal Oxide Catalysts Grant, Joseph T.; Venegas, Juan M.; McDermott, William P. Chemical Reviews, Vol. 118, Issue 5 https://doi.org/10.1021/acs.chemrev.7b00236	journal	November 2017
Catalytic Oxidation of Light Alkanes (C₁–C₄) by Heteropoly Compounds Sun, Miao; Zhang, Jizhe; Putaj, Piotr Chemical Reviews, Vol. 114, Issue 2, p. 981-1019 https://doi.org/10.1021/cr300302b	journal	November 2013
Catalytic Dehydrogenation of Light Alkanes on Metals and Metal Oxides Sattler, Jesper J. H. B.; Ruiz-Martinez, Javier; Santillan-Jimenez, Eduardo Chemical Reviews, Vol. 114, Issue 20 https://doi.org/10.1021/cr5002436	journal	August 2014
Recent Advances in Polyoxometalate-Catalyzed Reactions Wang, Sa-Sa; Yang, Guo-Yu Chemical Reviews, Vol. 115, Issue 11 https://doi.org/10.1021/cr500390v	journal	May 2015
Introduction: PolyoxometalatesMulticomponent Molecular Vehicles To Probe Fundamental Issues and Practical Problems Hill, C. L. Chemical Reviews, Vol. 98, Issue 1 https://doi.org/10.1021/cr960395y	journal	February 1998
Catalysis by Heteropoly Acids and Multicomponent Polyoxometalates in Liquid-Phase Reactions Kozhevnikov, Ivan V. Chemical Reviews, Vol. 98, Issue 1 https://doi.org/10.1021/cr960400y	journal	February 1998
Heterogeneous Catalysis Mizuno, Noritaka; Misono, Makoto Chemical Reviews, Vol. 98, Issue 1 https://doi.org/10.1021/cr960401q	journal	February 1998
Electrochemical Properties of Polyoxometalates as Electrocatalysts Sadakane, Masahiro; Steckhan, Eberhard Chemical Reviews, Vol. 98, Issue 1 https://doi.org/10.1021/cr960403a	journal	February 1998
Critical Literature Review of the Kinetics for the Oxidative Dehydrogenation of Propane over Well-Defined Supported Vanadium Oxide Catalysts Carrero, C. A.; Schloegl, R.; Wachs, I. E. ACS Catalysis, Vol. 4, Issue 10 https://doi.org/10.1021/cs5003417	journal	September 2014
Highly Selective Oxidation of Alkylphenols to p -Benzoquinones with Aqueous Hydrogen Peroxide Catalyzed by Divanadium-Substituted Polyoxotungstates Ivanchikova, Irina D.; Maksimchuk, Nataliya V.; Maksimovskaya, Raisa I. ACS Catalysis, Vol. 4, Issue 8 https://doi.org/10.1021/cs500738e	journal	July 2014
New Evidence on the Structure of Potassium Salts of 12-Tungstophosphoric Acid, K _x H _3- _x PW ₁₂ O ₄₀ Haber, Jerzy; Matachowski, Leszek; Mucha, Dariusz Inorganic Chemistry, Vol. 44, Issue 19 https://doi.org/10.1021/ic050350s	journal	September 2005
The 1- and 2-dimensional tungsten-183 and vanadium-51 NMR characterization of isopolymetalates and heteropolymetalates Domaille, Peter J. Journal of the American Chemical Society, Vol. 106, Issue 25 https://doi.org/10.1021/ja00337a004	journal	December 1984
Adsorption of Gases in Multimolecular Layers Brunauer, Stephen; Emmett, P. H.; Teller, Edward Journal of the American Chemical Society, Vol. 60, Issue 2, p. 309-319 https://doi.org/10.1021/ja01269a023	journal	February 1938
⁵¹ V Magic Angle Spinning NMR Spectroscopy of Keggin Anions [PV _n W _12- _n O ₄₀ ] ⁽³⁺ ⁿ ^)- : Effect of Countercation and Vanadium Substitution on Fine Structure Constants Huang, Wenlin; Todaro, Louis; Yap, Glenn P. A. Journal of the American Chemical Society, Vol. 126, Issue 37 https://doi.org/10.1021/ja0475499	journal	August 2004
Surface and Bulk Aspects of Mixed Oxide Catalytic Nanoparticles: Oxidation and Dehydration of CH ₃ OH by Polyoxometallates Nakka, Lingaiah; Molinari, Julie E.; Wachs, Israel E. Journal of the American Chemical Society, Vol. 131, Issue 42 https://doi.org/10.1021/ja904957d	journal	October 2009
Infrared and Computational Investigation of Vanadium-Substituted Keggin [PV _n W _12- _n O ₄₀ ] ⁽ ⁿ ^+3)- Polyoxometallic Anions Watras, Michael J.; Teplyakov, Andrew V. The Journal of Physical Chemistry B, Vol. 109, Issue 18 https://doi.org/10.1021/jp044674y	journal	May 2005
Spectroscopic Enlightening of the Local Structure Of VO _X Active Sites in Catalysts for the Odh of Propane Rossetti, Ilenia; Mancini, Giulia Fulvia; Ghigna, Paolo The Journal of Physical Chemistry C, Vol. 116, Issue 42 https://doi.org/10.1021/jp307031b	journal	October 2012
Efficient stereo- and regioselective hydroxylation of alkanes catalysed by a bulky polyoxometalate Kamata, Keigo; Yonehara, Kazuhiro; Nakagawa, Yoshinao Nature Chemistry, Vol. 2, Issue 6 https://doi.org/10.1038/nchem.648	journal	May 2010
Monitoring surface metal oxide catalytic active sites with Raman spectroscopy Wachs, Israel E.; Roberts, Charles A. Chemical Society Reviews, Vol. 39, Issue 12 https://doi.org/10.1039/c0cs00145g	journal	January 2010
Structure, properties and reactivity of polyoxometalates: a theoretical perspective López, Xavier; Carbó, Jorge J.; Bo, Carles Chemical Society Reviews, Vol. 41, Issue 22 https://doi.org/10.1039/c2cs35168d	journal	January 2012
From serendipity to design of polyoxometalates at the nanoscale, aesthetic beauty and applications Cronin, Leroy; Müller, Achim Chemical Society Reviews, Vol. 41, Issue 22 https://doi.org/10.1039/c2cs90087d	journal	January 2012
Pushing the frontiers in polyoxometalate and metal oxide cluster science Long, De-Liang; Cronin, Leroy Dalton Transactions, Vol. 41, Issue 33 https://doi.org/10.1039/c2dt90121h	journal	January 2012
Selective oxidative dehydrogenation of propane to propene using boron nitride catalysts Grant, J. T.; Carrero, C. A.; Goeltl, F. Science, Vol. 354, Issue 6319 https://doi.org/10.1126/science.aaf7885	journal	December 2016

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Divanadium substituted keggin [PV2W10O40] on non-reducible supports-Al2O3 and SiO2: synthesis, characterization, and catalytic properties for oxidative dehydrogenation of propane

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Divanadium substituted keggin [PV₂W₁₀O₄₀] on non-reducible supports-Al₂O₃ and SiO₂: synthesis, characterization, and catalytic properties for oxidative dehydrogenation of propane